用偏振荧光光谱表征乙醇-水团簇分子的取向行为

采用波长为236nm紫外光激励乙醇水溶液获得荧光光谱并对其偏振特性进行了研究.实验中分别改变入射光的偏振度，在300—400nm波段内进行荧光光谱、水平和垂直偏振荧光光谱检测.实验结果表明，当采用线偏振光照射乙醇水溶液时，其发射的荧光具有一定的偏振性，并计算了其偏振度.经理论分析得到了描述荧光偏振态的四个斯托克斯矢量，进而对该荧光的偏振状态进行了描述，通过对乙醇-水溶液的米勒矩阵的计算，对溶液中分子的取向特性进行了分析.本结果能对乙醇-水团簇分子的结构提供理论参考. 关键词： 荧光光谱 偏振光谱 斯托克斯矢量 米勒矩阵     

Influence of air pressure on mechanical effect of laser plasma shock wave

The influence of air pressure on mechanical effect of laser plasma shock wave in a vacuum chamber produced by a Nd:YAG laser has been studied. The laser pulses with pulse width of 10ns and pulse energy of about 320mJ at 1.06$\mu $m wavelength is focused on the aluminium target mounted on a ballistic pendulum, and the air pressure in the chamber changes from $2.8\times 10^{3}$ to 1.01$\times $10$^{5 }$Pa. The experimental results show that the impulse coupling coefficient changes as the air pressure and the distance of the target from focus change. The mechanical effects of the plasma shock wave on the target are analysed at different distances from focus and the air pressure.     

Experimental investigation of the impact on nearby solid boundary during laser-generated bubble collapse

Cavitation damage has been considered as being responsible for many effects in hydraulic machinery and biological medicine. In order to better understand the cavity interaction with nearby solid surfaces, the impact loading induced by the high-speed liquid-jet and subsequent jet flow during the final stage of the bubble collapse in a static fluid is investigated by focusing a Q-switched pulsed laser into water. By means of a new method based on a fibre-coupling optical beam deflection technique, a detailed experimental study has been made to clarify the relationship of the impact pressure against a solid boundary as a function of the dimensionless γ that is generally used to describe the bubble dynamics with its definition γ= s/R_{max}(R_{max} being the maximum bubble radius and s denoting the distance of the cavity inception from the boundary). The experimental results are shown that for γ in the range of about 0.67 to 0.95 with a pulsed laser energy 230mJ, the transient pressure applied on the solid surface is maximum; while for γ>1 or γ<0.67, it is gradually decreased. By combination of our experimental results with the other work that detected the acoustic emission during the bubble collapse at different γ, it is concluded that in this range of 0.67－0.95, the destructive effect due to a liquid-jet and the following jet flow impact actually outweighs the well-known effect of shock wave emission and plays a vital role during the cavitation bubble collapse.     

非均匀等离子体对平面电磁波的衰减

利用荧光灯排列形成非均匀等离子体层(面积约60cm×52cm,消耗功率约400W),研究了其对1～8GHzE波(电矢量方向平行于灯轴方向的入射波)的反射和透射的影响。结果表明,该等离子体对1～4GHz的E波具有强吸收和弱反射的特性,单程衰减最高可达8dB。利用2维分段线性电流密度递归卷积时域有限差分计算式,模拟了E波传播及其在非均匀等离子体内推进的瞬态过程,计算了等离子体对电磁波的反射和透射衰减,并与实验结果拟合,得到等离子体电子数密度峰值约9.72×1016m-3,电子与中性粒子碰撞频率约4GHz。     

Thermal stress cleaving of silicon wafer by pulsed Nd：YAG laser

The applied laser energy absorbed in a local area in laser thermal stress cleaving of brittle materials using a controlled fracture technique produces tensile thermal stress that causes the material to separate along the moving direction of the laser beam. The material separation is similar to crack extension, but the fracture growth is controllable. Using heat transfer theory, we establish a three-dimensional （3D） mathematical thermoelastic calculational model containing a pre-existing crack for a two-point pulsed Nd：YAG laser cleaving silicon wafer. The temperature field and thermal stress field in the silicon wafer are obtained by using the finite element method （FEM）. The distribution of the tensile stress and changes in stress intensity factor around the crack tip are analyzed during the pulse duration. Meanwhile, the mechanism of crack propagation is investigated by analyzing the development of the thermal stress field during the cleaving process.     

Numerical Simulations on the Formation of Speckles in Nanofluids Illuminated by a TEM00 Laser Beam

On the basis of a Rayleigh scattering model for a single nanoparticle illuminated by a TEMoo laser beam, we theoretically and numerically study the speckle formation when nanofluids are illuminated by a TEMoo laser beam. The results show that the laser speckles possess a Gaussian distribution, which are in agreement with the experimental results. The results may be useful for using a laser speckle velocimetry to determine the velocitiies of nanoparticles in nanofluids.     

干涉法诊断由纳秒激光诱导产生的大气等离子体的电子密度

通过改进的马赫-曾德尔干涉仪获得了高质量的Nd:YAG激光诱导大气等离子体干涉条纹图.利用快速傅里叶变换（FFT）分析法恢复了干涉图波面,通过Abel逆变换进行密度反演,重建了不同时刻激光等离子体电子密度的三维分布,并得到了激光等离子体膨胀速度与延迟时间的关系.结果显示,纳秒激光诱导大气击穿形成的等离子体具有等离子体通道结构,等离子体膨胀速度的迅速衰减,对等离子体通道的塌陷起到了促进作用,等离子体形状的离心率在大约48 ns时达到最大值,然后开始向圆形演变. 关键词： 激光等离子体电子密度 干涉测量 Abel逆变换     

乙醇-水团簇分子形成激基缔合物及荧光发射机理研究

紫外光照射具有特殊结构的长链式乙醇-水团簇分子时,处于激发态和基态的分子形成了分子间激基缔合物,并发射荧光.根据实验结果分析和能量转移理论可知,激发态单分子和激基缔合物间形成了电子迁移洛合物并发生了能量转移.根据Mulliken理论对电子迁移洛合物进行量子力学处理,得出了团簇分子在基态和激发态能量E^b_N和E^b_E以及由于电子迁移而引起的静电相互作用能E^s;根 关键词： 荧光光谱 激基缔合物 电子迁移 乙醇-水团簇     

含气量对黏性液体中空泡脉动特性的影响

采用自行研制的高灵敏度光偏转测试系统,研究黏性液体中激光空泡脉动特性.判定了空泡两次脉动对应的最大和最小泡半径,进而计算了激光空泡在前两次脉动过程中泡内的含气量.研究表明：泡内含气量对泡脉动特性有较大影响.随着脉动次数的增加,空泡泡内含气量增大.空泡最大泡半径随含气量的增加而增大.此外,受液体黏性影响,空泡膨胀和收缩过程明显变缓. 关键词： 含气量 黏性 激光空泡 脉动特性     

Derivative fluorimetry analysis of new cluster structures formed by ethanol and Water molecules

The ultraviolet （UV） light excited fluorescence spectra of ethanol-water mixture with different concentrations are investigated by derivative fluorimetry. It is found that there are 8 types of luminescent cluster molecules, formed by ethanol and water molecules in different ways, existing in the solution. The peak wavelengths of all these clusters＇ fluorescence spectra are measured and their contents are obtained by measuring the peak values in the second derivative fluorescence spectra. The spectra corresponding to the 8 types of clusters are obtained by Gaussian decomposition. It is found that two kinds of cluster molecules whose peak wavelengths are 330 and 345 nm have an optimal excitation wavelength located at （236 4- 3） nm. This research contributes to the study of ethanol-water cluster structures and their physical and chemical characteristics.