扬州江都区邵伯农田土壤环境质量及生态风险评价

选取扬州邵伯地区作为研究区,根据评价标准（GB 15618—2018）对其农田土壤环境质量及生态风险进行评价。研究区农田土壤中8种重金属元素平均含量均低于农用地污染风险筛选值,除Ni外其余7种重金属元素的平均含量均超过江苏土壤平均背景值,其中Hg含量均值为江苏土壤平均背景值的2.16倍;通过对比内梅罗指数法和综合指数法评价结果,认为综合指数法能更客观准确地反映研究区农田土壤环境质量状况,结果显示研究区农田土壤轻度污染以上样本占总样本的2.35%;研究区农田土壤属中度生态风险,综合潜在风险指数平均值为200.56,主要贡献因子是Hg。     

生物标志化合物与相关的全球变化

在各种地质体中广泛分布的生物标志化合物在全球变化研究中有着广泛应用,特别是在海洋和湖泊沉积物中,研究工作已涉及到古植被、古温度、古降水量、古大气CO2浓度和古季风等的恢复.文章介绍利用气相色谱仪、气相色谱-质谱联用仪、气相色谱-热转换-同位素比质谱仪分析了一个长40cm泥炭岩芯(约222年)的生物标志化合物的分布及其单体氢同位素.结果显示,不管是生物标志化合物的分布,还是其单体稳定同位素特征都记载了气候(温度)的变化.正构脂肪酸的碳优势指数(CPI值)、正构烷烃C23/C31比值、正构烷烃C23的δD值与温度有很好的对应关系.     

Erratum to: Geochemical and environmental magnetic characteristics of high arsenic aquifer sediments from Datong Basin,northern China

Geochemical and environmental magnetic studies were carried out to identify the effect of iron oxyhydroxides on arsenic mobilization in high arsenic aquifer system. Using high arsenic sediment samples from two boreholes, specifically drilled for this study, chemical composition and magnetic properties including magnetic susceptibility, saturation remnant magnetization, and isothermal remnant magnetization were measured. Results of correlation analysis of element contents show that arsenic and iron are closely associated with each other (r ² = 0.40, α = 0.05, n = 21). In contrast, the correlation of phosphorus with iron (r = 0.11, α = 0.05, n = 21) and arsenic (r ² = 0.18, α = 0.05, n = 21) was poor, which might result from competitive adsorption of phosphorus and arsenic on the surface of Fe-oxyhydroxides. The high correlation coefficients between arsenic contents and magnetic parameters suggest that the ferrimagnetic minerals including maghemite and hematite are the dominant carrier of arsenic in aquifer sediments. The results of sequential extraction experiments also revealed the association of arsenic with reducible iron oxides, such as maghemite and hematite in aquifer sediments. Therefore, under reducing conditions, reductive dissolution and desorption of arsenic from Fe-oxyhydroxides into the aqueous phase should be the dominant geochemical processes for its enrichment in groundwater at Datong. An erratum to this article can be found at     

山东金青顶金矿床和七宝山金矿床的流体包裹体REE组成

文章运用电感耦合等离子体质谱（ICP-MS）方法，研究了金青顶金矿床和七宝山金矿床的脉石英中流体包裹体REE组成特征，结果表明流体包裹体的REE均为LREE富集型，并显示Eu正异常。成矿流体REE配分模式和REE参数特征表明它们具有相当的来源。与金矿有关的成矿母岩，即昆嵛山花岗岩和七宝山次火山岩的REE特征也极为相似，反映成矿流体的REE组成都有从成岩向成矿过程演化继承的关系。矿床流体包裹体REE组成的相似特征及矿床碳氧同位素等特点表明，金青顶金矿床和七宝山金矿床是华北东部中生代同一构造热事件的产物。     

峨眉山玄武岩的地幔热柱成因

根据峨眉山玄武岩的岩石组合、岩相学特征将峨眉火成岩省分为盐源-丽江岩区、攀西岩区、贵州高原岩区和松潘-甘孜岩区。通过对研究区二叠世的区域地质背景和古地理环境的分析，对峨眉山玄武岩喷发与地幔热柱的关系及其火山喷发的大地构造背景进行了进一步系统归纳和总结。根据地层学关系大致确定峨眉山玄武岩的主喷发期是阳新世（中二叠）晚期-乐平世（晚二叠）早期，时限大致为259Ma-257Ma。峨眉山玄武岩微量元素地幔标准化曲线特征与OIB基本一致，反映出其成因与地幔热柱活动有密不可分的关系。     

Lipid distribution in a subtropical southern China stalagmite as a record of soil ecosystem response to paleoclimate change

Lipid extracts from a 61.7-cm-long subtropical stalagmite in southern China, spanning the period of ca. 10,000–21,000 yr ago as constrained by U–Th dating, were analyzed using gas chromatography–mass spectrometry. The higher plants and microorganisms in the overlying soils contribute a proportion of n-alkanes identified in the stalagmite. The occurrence of LMW (lower molecular weight) n-alkanols and n-alkan-2-ones in the stalagmite was mainly related to the soil microorganisms. We suggest that HMW (higher molecular weight) n-alkanols and n-alkan-2-ones identified in the stalagmite originate from soil organics and reflect input from contemporary vegetation. Shifts in the ratio of LMW to HMW n-alkanols or n-alkan-2-ones indicative of the variation of soil ecosystems (e.g., microbial degradation of organic matter and/or the relative abundance of soil microorganisms to higher plants) are comparable with the subtropical alkenone-SST (sea surface temperature) record of the same period. The similar trends seen in the δ¹³C data and the lipid parameters in this stalagmite imply that the overlying soil ecosystem response to climate might be responsible for the variation of δ¹³C values.     

高位钻场长钻孔在淮南刘庄煤矿瓦斯抽采中的应用

刘庄煤矿东二采区121102工作面所开采的11-2煤层为非突出煤层,但在工作面回采期间,存在瓦斯突出的可能。为防止工作回风巷尤其是上隅角瓦斯超限,确保工作面的正常生产,同时兼顾瓦斯资源的抽采利用,施工了最大长度496m,钻孔直径133mm的瓦斯抽采孔。实际应用表明,该孔投入使用后,整个工作面回采过程中均未发生过瓦斯超限现象,说明利用大口径长距离钻孔取代巷道抽放瓦斯是完全可行的。本文介绍的高位钻场长钻孔的设计、施工和瓦斯抽采情况,可以为今后同类工作面中长钻孔的施工提供借鉴。     

Mode of a spherical cavity’s thermo-elastodynamic response in a saturated porous medium for non-torsional loads

The thermo-hydro-elastodynamic model (THED), in which the thermo-osmosis and thermal-filtration phenomenon in a two-phase porous thermoelastic medium can be considered, was previously presented by the authors [Ganbin Liu, Kanghe Xie, Rongyue Zheng. Model of nonlinear coupled thermo-hydro-elastodynamics response for a saturated poroelastic medium. Sci China (Ser E) 2009;52(8):2373–83] and is used in this paper to investigate the thermo-elastodynamic response of a spherical cavity in a saturated poroelastic medium when subjected to a time-dependent non-torsional thermal/mechanical source. The Separated Variable Method is introduced, and the non-zero displacement potentials are expanded in terms of the Legendre polynomial. Solutions for the displacement, temperature increment, pore pressure and stress are obtained in the domain of the Laplace transform. Numerical results are also performed for different modes and are compared with the results of the thermoelastic model (TED) to ascertain the validity and the difference between these two models.     

黄铁矿表面及其与Au（HS）2^—溶液作用的STM研究

本文用ＳＴＭ研究了黄铁矿和方铅矿表面的原子结构、纳米级微形貌、电子态分布及其吸附态的特点。ＳＴＭ电流图象揭示了表面缺陷与表面电子态之间的对应关系，硫化和的表面的化学反应活性可能是表现缺陷引起的局域导电性增强有关。ＳＴＭ观察进一步表明黄铁矿和方铅矿对金的硫氢配合物的吸附作用优先发生于扭折位和台阶边缘等高能部位，反映出吸附态的分布也是与表面电子态分布相对应的。这样就从微观领域考证了硫化物表面对化学活性