Aspects of rhodium marine chemistry

Rhodium, one of the least abundant of the Pt-group elements in the earth's crust, has the second highest concentration in seawater. This may be a consequence of strong complexing, perhaps kinetically restrained with time constants of the order of centuries to millenia. The element shows a nutrient-like distribution in waters of the Pacific Ocean. Pelagic and coastal sediments have Rh concentrations close to crustal values. There is a remarkable enrichment of Rh in ferromanganese minerals that cannot be explained by oxidative capture. Unlike the other Pt-group elements, Rh is enriched in the high temperature hydrothermal sulfide deposits as well as phosphorites.     

Matching Martian crustal magnetization and magnetic properties of Martian meteorites

Abstract— Magnetic properties of 26 (of 32) unpaired Martian meteorites (SNCs) are synthesized to further constrain the lithology carrying Martian magnetic crustal sources. Magnetic properties of ultramafic cumulates (i.e., Chassigny, Allan Hills [ALH] 84001) and lherzolitic shergottites (ALH 77005, Lewis Cliff [LEW] 88516) are one or two orders of magnitude too weak to account for the crustal magnetizations, assuming magnetization in an Earth‐like field. Nakhlites and some basaltic shergottites, which are the most magnetic SNCs, show the right intensity. Titanomagnetite is the magnetic carrier in the nakhlites (7 meteorites), whereas in most basaltic shergottites (11 meteorites) it is pyrrhotite. Dhofar (Dho) 378, Los Angeles, and NWA 480/1460 and 2046 are anomalous basaltic shergottites, as their magnetism is mainly due to titanomagnetite. Pyrrhotite should be among the candidate minerals for the magnetized Noachian crust.     

Origin of near-surface high-salinity water observed in the Kuroshio Extension region

Hydrographic data in the Kuroshio Extension (KE) region from 2008 to 2010 show large year-to-year variability in near-surface salinity, including a very large anomalous event in February 2010. During this event, the deep winter mixed layer in the southern KE region had higher salinity than had existed during the previous summer in September 2009. Our analysis shows that advection from the Philippine Sea along the western branch of the North Pacific subtropical gyre, taking approximately 9 months, resulted in this large salinity anomaly in February 2010 and contributes to the interannual salinity variability in the southern KE region.     

Deep-sea coral geochemistry: Implication for the vital effect

Deep-sea corals hold a great potential as a key to important aspects of paleoceanography for at least two reasons, 1) they offer temporal high resolution records of deep-sea environment, because they have growth banding structures, 2) and they are well suited for studying vital effects, because the deep-sea environment does not change over short time scales. However, the relationship between the chemical composition of deep-sea coral skeletons and environmental factors is not well understood. In this study, the chemical composition of deep-sea corals was measured in bulk individuals and along skeletal micro-structures. Among the bulk individuals, δ¹⁸O value and Sr / Ca ratio show a negative but weak correlation with ambient temperature. On the other hand, the Mg / Ca ratio has a positive, weak correlation with the temperature. Large variations were found among samples collected from similar temperature. The variation is up to 3.8‰ for δ¹⁸O, 0.9 mmol/mol for Sr / Ca ratios, and 0.78 mmol/mol for Mg / Ca ratios among samples with ambient average temperature within 1 °C. This variation may be due to a large vital effect. The centers of calcification (COCs), which were formed at high calcification rate, have lower Sr / Ca, U / Ca and higher Mg / Ca ratios than surrounding fasciculi. This chemical distribution supports the model that elemental incorporation depends on calcification rate. This suggests that calcification rate is a very important factor for the chemical composition in deep-sea corals and is one of the most significant mechanisms of the vital effect. Because of this large vital effect, further investigations are essential to use the deep-sea coral as a temperature proxy.     

Studies on critical Reynolds number indices for wind-tunnel experiments on flow within urban areas

Reynolds-number dependence of flow fields within a modelled urban area was studied in a wind tunnel. We measured flow around a single model building and around model city blocks at various wind speeds, and studied Reynolds number indices more appropriate than the building Reynolds number. Our results led to the following conclusions. Firstly, the flow around the models in the wind tunnel was roughly divided into three parts according to the intensities of viscous stress and Reynolds stress as follows: (1) the flow in the vicinity of the ground or the surfaces of the model, where viscous stress became dominant under certain conditions; (2) the flow detached from the surfaces of the model, where Reynolds stress was always dominant; and (3) the flow around the separation bubble at the leading edge of the building model, where the influences of both viscous stress near the wall and the Reynolds stress in the separated boundary layer were mixed.Secondly, the critical Reynolds number of the flow in the modelled urban area could be defined by using both the roughness Reynolds number Re_z0 (= z₀u_*/) and the dimensionless height z₊ (= zu_*/). Reynolds-number independence could be expected for whole flow fields in the modelled urban areas as long as the critical values of Re_z0 and z₊ were satisfied.     

241Pu/239+240Pu ratios in polar glaciers

The analyses of plutonium isotopes in dated strata of polar ice sheets indicate that the²⁴¹Pu/^239+240Pu activity ratio produced in the U.S.-dominated nuclear tests during the 1950s was about 26, while that in the U.S.S.R.-dominated weapons tests in the early 1960s was between 12 and 14. This difference provides time horizons for sedimentary deposits. Further, the²³⁹Pu/²⁴⁰Pu ratio may show a similar difference in fallout values from these two periods of weapons testing and may provide an additional, and perhaps more sensitive, chronology for sediments.     

P-wave velocity structure of the margin of the southeastern Tsushima Basin in the Japan Sea using ocean bottom seismometers and airguns

The Tsushima Basin is located in the southwestern Japan Sea, which is a back-arc basin in the northwestern Pacific. Although some geophysical surveys had been conducted to investigate the formation process of the Tsushima Basin, it remains unclear. In 2000, to clarify the formation process of the Tsushima Basin, the seismic velocity structure survey with ocean bottom seismometers and airguns was carried out at the southeastern Tsushima Basin and its margin, which are presumed to be the transition zone of the crustal structure of the southwestern Japan Island Arc. The crustal thickness under the southeastern Tsushima Basin is about 17 km including a 5 km thick sedimentary layer, and 20 km including a 1.5 km thick sedimentary layer under its margin. The whole crustal thickness and thickness of the upper part of the crust increase towards the southwestern Japan Island Arc. On the other hand, thickness of the lower part of the crust seems more uniform than that of the upper part. The crust in the southeastern Tsushima Basin has about 6 km/s layer with the large velocity gradient. Shallow structures of the continental bank show that the accumulation of the sediments started from lower Miocene in the southeastern Tsushima Basin. The crustal structure in southeastern Tsushima Basin is not the oceanic crust, which is formed ocean floor spreading or affected by mantle plume, but the rifted/extended island arc crust because magnitudes of the whole crustal and the upper part of the crustal thickening are larger than that of the lower part of the crustal thickening towards the southwestern Japan Island Arc. In the margin of the southeastern Tsushima Basin, high velocity material does not exist in the lowermost crust. For that reason, the margin is inferred to be a non-volcanic rifted margin. The asymmetric structure in the both margins of the southeastern and Korean Peninsula of the Tsushima Basin indicates that the formation process of the Tsushima Basin may be simple shear style rather than pure shear style.     

Strontium, oxygen, and hydrogen isotope geochemistry of hydrothermally altered and weathered rocks in DSDP Hole 504B, Costa Rica Rift

DSDP Hole 504B was drilled into 6 Ma crust, about 200 km south of the Costa Rica Rift, Galapagos Spreading Center, penetrating 1.35 km into a section that can be divided into four zones—Zone I: oxic submarine weathering; Zone II: anoxic alteration; Zones III and IV: hydrothermal alteration to greenschist facies. In Zone III there is intense veining of pillow basalts. Zone IV consists of altered sheeted dikes. Isotopic geochemical signatures in relation to the alteration zones are recorded in Hole 504B, as follows:

Zone	Depth(m)	Average87Sr/86Sr	Average δ18O (%o)	Average δD (%o)
I	275–550	0.7032	7.3	−63
II	550–890	0.7029	6.5	−45
III	890–1050	0.7035	5.6	−31
IV	1050–1350	0.7032	5.5	−36

Full-size table

Alteration temperatures are as low as 10°C in Zones I and II based on oxygen isotope fractionation. Strontium isotopic data indicate that a circulation of seawater is much more restricted in Zone II than in Zone I. Fluid inclusion measurements of vein quartz indicate the alteration temperature was mainly 300 ± 20°C in Zones III and IV, which is consistent with secondary mineral assemblages.The strontium, oxygen, and hydrogen isotopic compositions of hydrothermal fluids which were responsible for the greenschist facies alteration in Zones III and IV are estimated to be 0.7037, 2‰, and 3‰, respectively. Strontium and oxygen isotope data indicate that completely altered portions of greenstones and vein minerals were in equilibrium with modified seawater under low water/rock ratios (in weight) of about 1.6. This value is close to that of the end-member hydrothermal fluids issuing at 21°N EPR.Basement rocks are not completely hydrothermally altered. About 32% of the greenstones in Zones III and IV have escaped alteration. Thus 1 g of fresh basalt including the 32% unaltered portion are required in order to make 1 g of end-member solution from fresh seawater in water-rock reactions.     

Decomposition of Phytoplankton in Seawater. Part I: Kinetic Analysis of the Effect of Organic Matter Concentration

Decomposition experiments were conducted on cultured phytoplankton (Skeletonema costatum) in seawater containing decomposer and consumer of size less than 500 μm. We determined the decomposition rates of bulk particulate organic matter (POM), the ratio of labile to semi-refractory fractions in the POM, and the POM carbon/ nitrogen (C/N) ratio during decomposition. To identify the kinetic mechanisms involved in the reactions of different order (e.g., first- and second-order), we studied the sensitivity of reaction rates to the initial concentration of POM, ranging from 2.4 to 71 mg-C L⁻¹. The results showed that decomposition consists of two first-order reactions: decomposition of labile and of semi-refractory particulate organic carbon (POC). The decomposition rate constants found for labile (0.13 day⁻¹ at 20°C), and semi-refractory POC (0.008 day⁻¹ at 20°C), and the carbon weight ratio of semi-refractory POC (13% at 20°C), were insensitive to the initial organic matter concentration. The time-dependence of the C/N ratio was also independent of this initial concentration. The decomposition rate constants and the content of semi-refractory POC did not change, regardless of the absence or presence of 25–500 μm organisms in natural seawater. This revised version was published online in July 2006 with corrections to the Cover Date.