The nature of crystalline silica from the TAG submarine hydrothermal mound, 26°N Mid Atlantic Ridge

Silica occurs in abundance in a variety of hydrothermal samples from the Trans-Atlantic Geotraverse (TAG) hydrothermal mound, 26°N Mid-Atlantic Ridge. The water content, trace element chemistry, and mineralogy of crystalline silica from 15 different samples have been examined by vibrational spectroscopy and probe microanalysis. The samples are from: shallow subsurface ferric iron oxyhydroxide silica deposits (n=4), a fragment of an active white smoker chimney (n=1), anhydrite bearing hydrothermal breccias (n=2), pyrite silica breccias (n=3), and silicified wall rock breccias (n=5). Length-fast chalcedony occurs in association with variable quantities of ferric iron oxyhydroxides in hydrothermal breccias from the mound flanks, within shallower subsurface chert samples, and within white smoker chimney walls. Samples from the anhydrite zone contain textures which are suggestive of an origin involving replacement of anhydrite. Samples taken from TAG 1 and 5 from below the anhydrite zone contain no chalcedony. Instead they contain subhedral quartz crystals which show oscillatory zoning in aluminium. Two types of crystalline silica namely, type A and type B quartz, are defined on the basis of the infrared spectra in the OH region from 3200 cm⁻¹ to 3600 cm⁻¹. The type A quartz occurs beneath the anhydrite zone at TAG 1 and 5. We propose a model that relates specific varieties of crystalline silica to different thermal and chemical environments within the mound interior. Length-fast chalcedony occurs in an outer low temperature envelope across the top and sides of the mound. The common association between length-fast chalcedony and ferric iron oxyhydroxides suggests that chalcedony crystallization is favoured where catalysis by ferric iron can occur. The apparent suppression of fibrous silica at the expense of single quartz crystals with increasing depth is attributed to differing growth rates and degrees of supersaturation of silica-bearing solutions with increasing temperature within the mound. The transition from type A to type B single crystal growth is interpreted to occur at temperatures approaching ˜360 °C due to decreasing solubility of aluminium in quartz, so that aluminium is rendered unavailable for type A valence compensation. Received: 10 September 1998 / Accepted: 6 July 1999     

Fourcade: the Centenary of a Stereoscopic Method of Photographic Surveying

In the Preface to his book, The Four Faces of Fourcade, Clare Storrar (1990) wrote: "It is di.cult to appreciate the breadth and depth of Henry Georges Fourcade's intelligence and creative power. He was an intellectual giant, a phenomenon, whose theoretical and practical achievements have never received proper recognition. These were all the more remarkable because he began his original work on photogrammetry when science in South Africa was in its infancy, and he laboured alone far from libraries and other research facilities. His only higher academic training was in land surveying. He was adept in each of four sciences at various stages in his life, but, mainly because of his natural reserve, his reputation was highly compartmentalised. To foresters he was 'the most brilliant forestry officer of his time' to surveyors, he was exceptionally learned in theory and skilled in practice. Photogrammetry was a new subject, unheard of, except by a handful of scientists. In botany, which he took up seriously at the age of fifty-five, his work was highly regarded by leading botanists in South Africa and in Europe. All stood in awe of his extraordinary talent and ability. Some were frightened of him. But few were able—in fact, not even the best brains were wholly qualified—to grasp fully the tremendous intellectual stature and potential of this protean man."
This paper briefly describes the historic achievements of Henry Georges Fourcade, with the emphasis on his land surveying and, in particular, his photogrammetric contributions to science. The centenary of one of these, his proposal of a stereoscopic method of photographic surveying, occurs in October 2001.     

On Invisible Trade Relations between Mesopotamian Cities during the Third Millennium B.C.

The idea that the emergence of writing was necessity due to the increase in both the number of economic transactions and political complexity has been recently emphasized by Matthews, who also underlines that writing acted as a feedback in enabling and encouraging the growth of ever more complex modes of exchange. The intertwinement of trade and writing suggests that clay tablets left by the civilizations from the third millennium B.C. in Mesopotamia, where writing was invented, may be considered as traces of trade links and transactions between cities. We estimate a gravity model based on clay tablets, as if they represented trade flows. The parameters lead us to conclude that Mesopotamia formed a strongly integrated market.     

Two classes of volcanic plumes on Io

Comparison of Voyager 1 and Voyager 2 images of the south polar region of Io has revealed that a major volcanic eruption occured there during the period between the two spacecraft encounters. An annular deposit ～1400 km in diameter formed around the Aten Patera caldera (311°W, 48°S), the floor of which changed from orange to red-black. The characteristics of this eruption are remarkably similar to those described earlier for an eruption centered on Surt caldera (338°W, 45°N) that occured during the same period, also at high latitude, but in the north. Both volcanic centers were evidently inactive during the Voyager 1 and 2 encounters but were active sometime between the two. The geometric and colorimetric characteristics, as well as scale of the two annular deposits, are virtually identical; both resemble the surface features formed by the eruption of Pele (255°W, 18°S). These three very large plume eruptions suggest a class of eruption distinct from that of six smaller plumes observed to be continously active by both Voyagers 1 and 2. The smaller plumes, of which Prometheus is the type example, are longer-lived, deposit bright, whitish material, erupt at velocities of ～0.5 km sec^?1, and are concentrated at low latitudes in an equatorial belt around the satellite. The very large Pele-type plumes, on the other hand, are relatively short-lived, deposit darker red materials, erupt at ～1.0 km sec^?1, and (rather than restricted to a latitudinal band) are restricted in longitude from 240° to 360°W. Both direct thermal infrared temperature measurements and the implied color temperatures for quenched liquid sulfur suggest that hot spot temperatures of ～650°K are associated with the large plumes and temperatures <400°K with the small plumes. The typical eruption duration of the small plumes is at least several years; that of the large plumes appears to be of the order of days to weeks. The two classes therefore differ by more than two orders of magnitude in duration of eruption. Based on uv, visible, and infrared spectra, the small plumes seem to contain and deposit SO₂ in their annuli whereas the large plumes apparently do not. Two other plumes that occur at either end of the linear feature Loki may be intermediate or hybrid between the two classes, exhibiting attributes of both. Additionally, Loki occurs in the area of overlap in the regional distributions of the two plume classes. Two distinct volcanic systems involving different volatiles may be responsible for the two classes. We propose that the discrete temperatures associated with the two classes are a direct reflection of sulfur's peculiar variation in viscosity with temperature. Over two temperature ranges (～400 to 430°K and >650°K), sulfur is a low-viscosity fluid (orange and black, respectively); at other temperatures it is either solid or has a high viscosity. As a result, there will be two zones in Io's crust in which liquid sulfur will flow freely: a shallow zone of orange sulfur and a deeper zone of black sulfur. A low-temperature system driven by SO₂ heated to 400 to 400°K by the orange sulfur zone seems the best model for the small plumes; a system driven by sulfur heated to >650°K by hot or even molten silicates in the black sulfur zone seems the best explanation for the large plume class. The large Pele-type plumes are apparently concentrated in a region of the satellite in which a thinner sulfur-rich crust overlies the tidally heated silicate lithosphere, so the black sulfur zone may be fairly shallow in this region. The Prometheus-type plumes are possibly confined to the equatorial belt by some process that concentrates SO₂ fluid in the equatorial crust.     

North-south transfer zones and paleo-morphological reconstruction of the Xylokastro area (Corinth Gulf, Greece)

A large number of studies have documented the structural and sedimentary architecture of the Corinth Gulf, especially the major E–W trending normal faults important in accommodating the main extensional strain and associated growth of the Gilbert fan deltas. However, the role of several N–S oriented structures that crop out at the surface and are detectable at depth by seismic reflection and gravity surveys are not clearly understood. Based on new geological data, collected near Xylokastro, we describe the N–S oriented tectonic activity of this area. The mapped inland faults correspond to off-shore structures identified in re-interpreted seismic lines and appear to have acted as a major transfer zone during the opening of the Corinth Gulf. Reconstruction of the paleo-topography based on sedimentary facies and the environment of clay mineral formation suggest these transfer zones played an important role in controlling both local structural relief and depositional conditions of the Gilbert fan deltas.     

Multi-scale slope instabilities along the Nile deep-sea fan,Egyptian margin: A general overview

The Nile deep-sea fan (NDSF), turbiditic system reaching a size of about 90,000 km², has been investigated since 1998 by several geophysical methods (multibeam bathymetry, backscatter imagery, seismic data, 3–5 kHz echo-sounding). The analysis of this important data set evidenced that the NDSF is the locus of numerous multi-scale slope instabilities. Three main types of instabilities have been defined, mainly on the basis of their size or origin. (1) First type of instabilities related to the generalized gravity spreading of the Plio-Quaternary deep-sea fan on Messinian salt layers. This global spreading is accommodated by numerous localized slides. (2) Second type of instabilities correspond to giant mass movements probably triggered either by earthquakes, fluids, or climate and eustatic oscillations. Finally, (3) third type of instabilities correspond either to localized levee liquefactions or to thin-skinned slides on the steep slopes of the Eratosthenes seamount. The deposits generated by these slope movements greatly participate in the building of the NDSF. The characterization of these different instabilities, in a petroleum province as the NDSF, has important implications in terms of risk assessments when considering drilling operations.     

Helium resonance lines in the flare of 15 June, 1973

Time sequences of He i and He ii resonance line intensities at several sites within the flare of 15 June, 1973 are derived from observations obtained with the Naval Research Laboratory's Slitless Spectroheliograph on Skylab. The data are compared with predictions in six model flare atmospheres based on two values for the heating rate and three for the flux of photoionizing coronal X-rays and EUV. A peak ionizing flux more than 10³ times that in the quiet Sun is indicated. For most conditions in flare kernels the He ii L and L lines are found to be formed by collisional excitation, thereby contributing to the local cooling of the plasma at temperatures above 6 × 10⁴ K. Emission in the higher Lyman lines is generally the result of a mixture of collisional excitation at these temperatures and photoionization and recombination at temperatures near 2.5 × 10⁴ K. We discuss implications for the common practice of deriving stellar coronal fluxes from He ii 1640 Å fluxes assuming dominance of the recombination mechanism.Chief, Quantum Physics Division, National Institute of Standards and Technology.Operated jointly by the National Institute of Standards and Technology and the University of Colorado.Operated by the National Optical Astronomy Observatories of the Association of Universities for Research in Astronomy, Inc. under contract with the National Science Foundation.     

Sutter's Mill dicarboxylic acids as possible tracers of parent‐body alteration processes

Dicarboxylic acids were searched for in three Sutter's Mill (SM) fragments (SM2 collected prerain, SM12, and SM41) and found to occur almost exclusively as linear species of 3‐ to 14‐carbon long. Between these, concentrations were low, with measured quantities typically less than 10 nmole g^?1 of meteorite and a maximum of 6.8 nmole g^?1 of meteorite for suberic acid in SM12. The SM acids' molecular distribution is consistent with a nonbiological origin and differs from those of CMs, such as Murchison or Murray, and of some stones of the C2‐ungrouped Tagish Lake meteorite, where they are abundant and varied. Powder X‐ray diffraction of SM12 and SM41 show them to be dominated by clays/amorphous material, with lesser amounts of Fe‐sulfides, magnetite, and calcite. Thermal gravimetric (TG) analysis shows mass losses up to 1000 °C of 11.4% (SM12) and 9.4% (SM41). These losses are low compared with other clay‐rich carbonaceous chondrites, such as Murchison (14.5%) and Orgueil (21.1%). The TG data are indicative of partially dehydrated clays, in accordance with published work on SM2, for which mineralogical studies suggest asteroidal heating to around 500 °C. In view of these compositional traits and mineralogical features, it is suggested that the dicarboxylic acids observed in the SM fragments we analyzed likely represent a combination of molecular species original to the meteorite as well as secondary products formed during parent‐body alteration processes, such as asteroidal heating.