Geoarchaeological and chronostratigraphical investigations of open‐air sites in the Geelbek Dunes,South Africa

The Geelbek Dunes located north of Cape Town, South Africa, are an active, northward migrating dune field. Interdunal deflation hollows temporarily expose former land surfaces that are associated with archaeological sites. These open‐air sites shed light on large‐scale patterns of Middle and Later Stone Age settlement and augment the information gained from well‐stratified, but spatially limited caves, rock shelters, and coastal shell middens. Based on paleopedological and sedimentological parameters, three former land surfaces were identified and associated with different assemblages. A chronostratigraphy of the various land surfaces was established by applying optically stimulated luminescence (OSL) dating. The youngest former land surface is represented by a dune generation (AD2) which stabilized at a maximum of 5 ka. An older dune generation (AD1) shows a more heterogeneous age pattern where deposition started at ca. 27 ka with a maximum estimated age of stabilization at ca. 10 ka. Both of these dune generations overlie a weathered calcrete complex of Middle to Late Pleistocene age. While the third dune generation (AD0) was observed between underlying calcrete layers, samples taken from this unit could not be dated. © 2008 Wiley Periodicals, Inc.     

A new peculiar muensterellid coleoid (Cephalopoda) from the Kimmeridge Clay Formation of Dorset (England)

A concretion from the lower Tithonian Kimmeridge Clay Formation (Pectinatus Zone) found by Steve Etches yielded a gladius of a coleoid cephalopod. It is peculiar in shape and has an unusual ornamentation of radiating ribs and tubercles. The new form is named Etchesia martilli n. gen. n. sp. and preliminarily placed within the octobrachian family Muensterellidae based on its limpet-like gladius. Through the presence of radiating ribs as well as the absence of a narrow anterior rachis E. martilli n. gen. n. sp. is similar to Pearceiteuthis buyi from the Oxford Clay Formation (Callovian). The new muensterellid is unique in having an enrolled patella apex, which is located close to the posterior gladius rim. E. martilli n. gen. n. sp. represents the first muensterellid coleoid from the Kimmeridge Clay Formation. A phylogenetic relationship of E. martilli n. gen. n. sp. (and Pearceiteuthis) with cirrate and incirrate octopods is discussed, although further information on soft parts such as the muscular mantle is necessary.     

Climate Change driven evolution of hazards to Europe’s transport infrastructure throughout the twenty-first century

Air circulation due to the urban heat island (UHI) effect can influence the dispersion of air pollutants in a metropolis. This study focusses on the influence of the UHI effect on particulate matter (PM; including PM_2.5 and PM_2.5–10) between May and September 2010–2012 in the Taipei basin. Meteorological and PM data were obtained from the sites, owned by the governmental authorities. The analysis was carried out using t test, relative indices (RIs), Pearson product–moment correlation and stepwise regression. The results show that the RI values for PM were the highest at moderate UHI intensity (MUI; 2 °C ≤ UHI < 4 °C) rather than at strong UHI intensity (SUI; 4 °C ≤ UHI) during the peak time for anthropogenic emissions (20:00 LST). Neither the accumulation of PM nor the surface convergence occurred in the hot centre, as shown by the case study. At MUI, more than 89 % of the synoptic weather patterns showed that the weather was clear and hot or that the atmosphere was stable. The variation in PM was associated with horizontal and vertical air dispersion. Poor horizontal air dispersion, with subsidence, caused an increase in PM at MUI. However, the updraft motion diluted the PM at SUI. The stepwise regression models show that the cloud index and surface air pressure determined the variation in PM_2.5–10, while cloud index, wind speed and mixing height influenced the variation in PM_2.5. In conclusion, a direct relationship between UHI effect and PM was not obvious.     

A quantitative vulnerability function for fluvial sediment transport

In quantitative risk assessment, risk is expressed as a function of hazard, elements at risk exposed, and vulnerability. Vulnerability is defined as the expected degree of loss for an element at risk as a consequence of a certain event, following a natural-scientific approach combined with economic methods of loss appraisal. The resulting value ranges from 0 (no damage) to 1 (complete destruction). With respect to torrent processes, i.e., fluvial sediment transport, this concept of vulnerability—though widely acknowledged—did not result in sound quantitative relationships between process intensities and associated degrees of loss so far, even if considerable loss occurred during recent years. To close this gap and establish this relationship, data from three well-documented torrent events in the Austrian Alps were used to derive a quantitative vulnerability function applicable to residential buildings located on torrent fans. The method applied followed a spatially explicit empirical approach within a GIS environment and was based on process intensities, the spatial characteristics of elements at risk, and average reconstruction values on a local scale. Additionally, loss data were collected from responsible administrative bodies and analysed on an object level. The results suggest a modified Weibull distribution to fit best to the observed damage pattern if intensity is quantified in absolute values, and a modified Frechet distribution if intensity is quantified relatively in relation to the individual building height. Additionally, uncertainties resulting from such an empirical approach were studied; in relation to the data quality a 90% confidence band was found to represent the data range appropriately. The vulnerability relationship obtained allows for an enhanced quantification of torrent risk, but also for an inclusion in comprehensive vulnerability models including physical, social, economic, and institutional vulnerability. As a result, vulnerability to mountain hazards might decrease in the future.     

Towards a Higher Comparability of Geothermometric Data obtained by Raman Spectroscopy of Carbonaceous Material. Part I: Evaluation of Biasing Factors

Raman spectroscopy of carbonaceous material (RSCM) is frequently used to determine metamorphic peak temperatures from the structural order of carbonaceous material enclosed in metasediments. This method provides a quick, robust and relatively cheap geothermometer. However, the comparability of the RSCM parameter is low as there are at least three major sources of biasing factors. These sources are the spectral curve‐fitting procedure, the sample characteristics itself and the experimental design including the used Raman system. To assess the impacts of the biasing factors on RSCM, a series of experiments was performed. The experiments showed that curve‐fitting is strongly influenced by individual operator‐bias and the degrees of freedom in the model, implying the need for a standardised curve‐fitting procedure. Due to the diversity of components (optics, light detection device, gratings, etc.) and their combinations within the Raman systems, different Raman instruments generally give differing results. Consequently, to estimate comparable metamorphic temperatures from RSCM data, every Raman instrument needs its own calibration. This demands a reference material series that covers the entire temperature calibration range. Although sample heterogeneity will still induce some variation, a reference material series combined with standardised curve‐fitting procedures will significantly increase the overall comparability of RSCM data from different laboratories.     

Dynamic tracking of mica breakdown reactions with electrochemical measurements

The breakdown of hydrous minerals involves multiple reactions of dehydration and often oxidation of ferric iron. Such reactions are important in mantle metasomatism, metamorphic petrology and material sciences. Here we track these reactions dynamically over the temperature range from 400° to 1100° C using Y-doped ZrO₂ sensors in a novel manner, comparable to differential thermal analyses. This contrasts to the conventional use of ZrO₂ cells in equilibrium electrochemical measurements for oxygen fugacity.     

Influence of the Po River runoff on the bacterioplankton community along trophic and salinity gradients in the Northern Adriatic Sea

The Po River runoff strongly affects the oceanographic and ecological characteristics of the Northern Adriatic Sea. Catalysed reported deposition ‐ fluorescence in situ hybridization (CARD‐FISH) analysis was employed to assess how the composition of the coastal bacterioplankton community is influenced by the river runoff in two different seasons (spring and autumn). Samples were collected from the water column along a coastal–offshore transect in the Northern Adriatic Sea at different depths. Four clone libraries were then constructed from coastal (0 m) and offshore waters (?65 m). Higher abundances of bacteria were recorded in coastal waters as compared with the offshore samples. This result was mainly due to the trophic state of the water column, and it was related to salinity. Particularly, Actinobacteria and Gammaproteobacteria were affected by the riverine inputs, whereas Bacteroidetes and Alphaproteobacteria showed only minor responses. This was particularly clear in the autumn sample, in which a clear difference between the coastal and the offshore samples was found due to a strong influence of the less saline river water with high nutrient concentrations. Analysis of 205 partial length 16S rRNA gene sequences indicated a high diversity with the dominance of Alphaproteobacteria, Bacteroidetes and Gammaproteobacteria mainly affiliated to coastal and marine bacterioplankton clades. Actinobacteria were also detected and, together with Gammaproteobacteria, strongly follow the freshwater intrusion. Overall, our results indicate that the seasonal difference in the Po River discharge greatly affects the bacterioplankton community. In spring we observed a smooth transition from coastal to open‐sea conditions owing to the more superficial freshwater plume. In autumn the deeper freshwater intrusion in the coastal site and thermal stratification offshore resulted in a marked difference between the coastal and offshore microbial communities.     

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Intercomparison of Two Hydroxyl Radical Measurement Techniques at the Atmosphere Simulation Chamber SAPHIR

At the atmosphere simulation chamber SAPHIR in Jülich both Laser-Induced Fluorescence Spectroscopy (LIF) and Long-Path Differential Optical Laser Absorption Spectroscopy (DOAS) are operational for the detection of OH radicals at tropospheric levels. The two different spectroscopic techniques were compared within the controlled environment of SAPHIR based on all simultaneous measurements acquired in 2003 (13 days). Hydroxyl radicals were scavenged by added CO during four of these days in order to experimentally check the calculated precisions at the detection limit. LIF measurements have a higher precision (σ= 0.88×10⁶ cm^–3) and better time resolution (Δt = 60 s), but the DOAS method (σ= 1.24×10⁶ cm^–3, Δt = 135 s) is regarded as primary standard for comparisons because of its good accuracy. A high correlation coefficient of r = 0.95 was found for the whole data set highlighting the advantage of using a simulation chamber. The data set consists of two groups. The first one includes 3 days, where the LIF measurements yield (1 – 2) ×10⁶ cm^–3 higher OH concentrations than observed by the DOAS instrument. The experimental conditions during these days are characterized by increased NO_x concentration and a small dynamic range in OH. Excellent agreement is found within the other group of 6 days. The regression to the combined data of this large group yields unity slope without a significant offset.