Structure of the thermal lithosphere and asthenosphere beneath oceans and continents

The lithosphere and asthenosphere make up a common geodynamic system but are characterized by different physical parameters. The former has a temperature of 1200–1300°C, a density of 3.3 g/cm³, and a viscosity of 10²² poise, while the latter has a density of 3.23 g/cm³, a viscosity in the range 10²¹-10^18–19 poise, and a temperature from 1200–1300°C to 1600–1700°C. The asthenosphere is distinguished by a great variability of its physical state in the lateral and vertical directions. This circumstance necessitates the recognition of the different types of the asthenosphere: seismic (LVZ zone), electrical, thermal, and seismological. The structure and the physical state of the thermal asthenosphere is considered in this paper on the basis of P-T parameters. Its state normally fits viscous Newtonian liquid beneath the continents and provides partial (5–20%) melting in spreading zones and along continental margins. No partial melting is detected beneath the main portion of the continents. The interaction between the asthenosphere and lithosphere is characterized by spatiotemporal migration of partial melting zones and asthenosphere upwelling, and such interaction determines the entire range of geodynamic processes from spreading and rifting to collision and vertical motions of different senses.     

The dissolution of calcite in CO2-saturated solutions at 25°C and 1 atmosphere total pressure

The dissolution of Iceland spar in CO₂-saturated solutions at 25°C and 1 atm total pressure has been followed by measurement of pH as a function of time. Surface concentrations of reactant and product species have been calculated from bulk fluid data using mass transport theory and a model that accounts for homogeneous reactions in the bulk fluid. The surface concentrations are found to be close to bulk solution values. This indicates that calcite dissolution under the experimental conditions is controlled by the kinetics of surface reaction. The rate of calcite dissolution follows an empirical second order relation with respect to calcium and hydrogen ion from near the initial condition (pH 3.91) to approximately pH 5.9. Beyond pH 5.9 the rate of surface reaction is greatly reduced and higher reaction orders are observed. Calculations show that the rate of calcite dissolution in natural environments may be influenced by both transport and surface-reaction processes. In the absence of inhibition, relatively short times should be sufficient to establish equilibrium.     

Li/Ca in multiple species of benthic and planktonic foraminifera: thermocline, latitudinal, and glacial-interglacial variation

Li/Ca ratios were measured in planktonic and benthic foraminifera from a variety of hydrographic settings to investigate the factors influencing lithium incorporation into foraminiferal tests including temperature, dissolution, pressure, and interspecies differences. Down-core measurements of planktonic (Orbulina universa, Globigerinoides ruber, and Globigerinoides sacculifer) and benthic foraminifera (calcitic Cibicides wuellerstorfi and aragonitic Hoeglandina elegans) show a systematic variation in Li/Ca with δ¹⁸O through the last glacial-interglacial transition. All species examined exhibit an increase in Li/Ca between 14 to 50% from the Holocene to the last glacial maximum. Li/Ca generally increases with decreasing temperature as seen in a latitudinal transect of planktonic O. universa and down-slope benthic species along the Bahama Bank margins. Postdepositional dissolution possibly causes a decrease in planktonic foraminiferal Li/Ca along the Sierra Leone Rise, and increased water depth causes a decrease in benthic foraminiferal Li/Ca in the deep Caribbean. However, none of these effects are sufficient to account for the observed glacial-interglacial changes. Physiological factors such as calcification rate may affect the Li/Ca content of foraminiferal calcite. The calcification rate in turn may be a function of carbonate ion concentration of ambient ocean water. This work shows that incorporation of lithium by foraminifera appears to be influenced by factors other than seawater composition and does not appear to be dominated by changes in temperature, dissolution, or pressure. We hypothesize that the consistent increase in foraminiferal Li/Ca during the last glacial maximum may be linked to changes in seawater carbonate ion concentration. Important parameters to be tested include calcification rate and foraminiferal test size and weight. If foraminiferal Li/Ca is dominantly controlled by calcification rate as a function of seawater carbonate ion concentration, then Li/Ca may act as a proxy of past atmospheric CO₂.