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101.
Silicon - This paper aims to evaluate and upgrade the quality of quartz mining by-products through acid leaching process. The quartz samples were collected as gold mine by-products from El Sid-... 相似文献
102.
A novel manganese phosphomolybdate exchanger was synthesized, dried at different temperatures, and evaluated for the elimination of lead, iron, and manganese ions from aqueous solutions. The chemical structure of the cation exchanger was established using Fourier-transform infrared, scanning electron microscopy, Thermo gravimetric analysis/ Differential thermal analysis, and X-ray diffraction. The adsorption performance of the heavy metals Pb2+, Fe3+, and Mn2+ toward the synthesized material has been studied. The obtained outcomes show that the selectivity of the cationic exchanger was descending in this order, Pb2+ > Fe3+ > Mn2+. The highest adsorption capacity was shown to be decreased as drying temperature of the exchanger increases from 50°C to 800°C. 相似文献
103.
Merat Hodaie Mirabdullah Seyed Sadjadi Mostafa M. Amini Ezzatollah Najafi Seik Weng Ng 《Journal of Inorganic and Organometallic Polymers and Materials》2016,26(3):500-511
In order systematically investigate the effect of ligand with a large conjugated π-system on the structure and optical properties of tin complex, anthracene-9-carboxylic acid (L1) is selected as a primary ligand, and quinoline-2-carboxylic acid (L2) used as second ligand to incorporate with anthracene-9-carboxylic acid to construct a new tin(IV)-carboxylate coordination complex under thermal gradient condition. Prepared complex was fully characterized based on its 1H and 13C NMR, IR and UV spectra and elemental analysis. The molecular structure of complex was determined by single-crystal X-ray analysis. The nanocrystalline complexes of the prepared complex were successfully obtained at 30, 50 and 60 °C by a facile sonochemical route. The new nanocrystalline complexes were characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analysis. The photoluminescence properties of the nanocrystalline complexes and crystalline bulk complex in the solid-state indicated that the size of the complex particles has a remarkable effect on the optical properties of it. Absorption and emission peaks of the nanocrystalline complexes blue shifted significantly in comparison with those of in the single-crystal form. Application of the prepared complex in fabrication of an organic light-emitting diode has been demonstrated. The current–voltage (I–V) characteristics and the electroluminescence (EL) properties of the complex have been investigated. The EL of the compound exhibits green emission at 552 nm. 相似文献
104.
Annealed ZnO thin film at 400 °C for two hours was deposited on a glass substrate by using pulsed laser deposition (PLD). The structural properties of the annealed ZnO thin film were studied by XRD, TEM and SEM. Gas sensing properties for different gases such as H2 and LPG were investigated. Applying XRD the size of the nanocrystals is found to be 10.61 nm. SEM of the thin film consisted of many grains distributed uniformly throughout the surface. An annealed ZnO thin film sensor showed the typical n-type semiconducting behavior in the case of H2 and LGP gases at low and high operating temperature range, respectively. When working at 50 and 140 °C the sensor exhibits very good dynamic response–recovery characteristics to H2 and LGP, respectively. These results along with a simple fabrication process demonstrate that the annealed ZnO thin film at 400 °C for two hours is promising for developing low cost and high performance H2 and LPG sensors. The low cost of the sensor element fabrication, high H2 and LPG sensitivity, fast response and quick recovery make the entire fabrication process a front-runner and cost-effective for the production of annealed ZnO thin film H2 and LPG sensors. 相似文献
105.
Mostafa Khajeh Yadollah Yamini Shahab Shariati 《Food and Bioproducts Processing》2010,88(2-3):227-232
Essential oil of Nepeta persica cultivated in Iran was obtained by steam distillation and supercritical (carbon dioxide) extraction methods. The oils were analysed by capillary gas chromatography using flame ionization and mass spectrometric detections. The compounds were identified according to their retention indices and mass spectra (EI, 70 eV). The effects of different parameters such as pressure, temperature, modifier volume and extraction times (dynamic and static) on the supercritical fluid extraction (SFE) of N. persica oil were investigated. The results showed that under the pressure of 20.3 MPa, temperature of 45 °C, methanol of 1.5% v/v), dynamic extraction time of 50 min and static extraction time of 25 min extraction was more selective for the 4αβ,7α,7aα-nepetalactone. Twelve compounds were identified in the steam-distilled oil. The major components of N. persica were 4αβ,7α,7aα-nepetalactone (26.5%), cis-β-farnesene (4.4%) and 3,4α-dihydro-4aα,7α,7aα-nepetalactone (3.5%). However, by using supercritical carbon dioxide under optimum conditions, only two components have more than 90.0% of the oil. The extraction yield based on steam distillation was 0.08% (v/w). On the other hand, using SFE extraction yield in the range of 0.22–8.90% (w/w) were obtained at different conditions. The results show that, in Iranian N. persica oil, 4αβ,7α,7aα-nepetalactone is a major component. 相似文献
106.
S Mohammad M Mortazavi Hassan Arabi Gholamhossein Zohuri Saeid Ahmadjo Mehdi Nekoomanesh Mostafa Ahmadi 《Polymer International》2010,59(9):1258-1265
Catalysts have a major role in the polymerization of olefins and exert their influence in three ways: (1) polymerization behaviour, including polymerization activity and kinetics; (2) polymer particle morphology, including bulk density, particle size, particle size distribution and particle shape; and (3) polymer microstructure, including molecular weight regulation, chemical composition distribution and short‐ and long‐chain branching. By tailoring the catalyst structure, such as the creation of a bridge or introducing a substituent on the ligand, metallocene catalysts can play a major role in the achievement of desirable properties. Kinetic profiles of the metallocene catalyst used in this study showed decay‐type behaviour for copolymerization of ethylene/α‐olefins. It was observed that increasing the comonomer ratio in the feedstock affected physical properties such as reducing the melting temperature, crystallinity, density and molecular weight of the copolymers. It was also observed that the heterogeneity of the chemical composition distribution and the physical properties were enhanced as the comonomer molecular weight was increased. In particular, 2‐phenyl substitution on the indenyl ring reduced somewhat the melting point of the copolymers. In addition, the copolymer produced using bis(2‐phenylindenyl)zirconium dichloride (bis(2‐PhInd)ZrCl2) catalyst exhibited a narrower distribution of lamellae (0.3–0.9 nm) than the polymer produced using bisindenylzirconium dichloride catalyst (0.5–3.6 nm). The results obtained indicate that the bis(2‐PhInd)ZrCl2 catalyst showed a good comonomer incorporation ability. The heterogeneity of the chemical composition distribution and the physical properties were influenced by the type of comonomer and type of substituent in the catalyst. Copyright © 2010 Society of Chemical Industry 相似文献
107.
Mostafa Kahani Afshin Tatar Milad Sadeghzadeh 《Numerical Heat Transfer, Part A: Applications》2013,63(4):1190-1206
AbstractIn this study, Multilayer Perceptron Artificial Neural Network (MLP-ANN) model and Least Square Support Vector Machine (LSSVM), were developed to predict the thermal performance and pressure loss of nanofluid flow through coils as non-straight pathways. There different coils with various curvature ratios and coil pitches were constructed and used. Stable TiO2 (50?nm)/water nanofluid in different concentrations from 0.0 to 2.0% were prepared using appropriate method. As it is expected, considerable enhancement of heat transfer was achieved by application of nanofluids instead of water in system. Volume concentration of nanofluid, Prandtl number (ranging from 4.82 to 9.11) and Helical number (106.80 to 1282.87) were introduced to the developed models to obtain Nusselt number (9.89 to 53.30) and pressure drop (291.35 to 18784?kPa) as the output data of the models. According to the output results of developed models, MLP-ANN model was able to predict both Nusselt number and pressure drop of nanofluid flow more precisely in comparison to LSSVM model. The developed MLP model of this study exceeded LSSVM model to high correlation coefficient value of 0.97. 相似文献
108.
Salha?Boulila Hassane?Oudadesse Rim?Kallel Bertrand?Lefeuvre Mostafa?Mabrouk Khansa?Chaabouni Fatma?Makni-Ayedi Tahia?Boudawara Abdelfattah?Elfeki Hafed?ElfekiEmail author 《Polymer Bulletin》2017,74(10):4153-4173
The present study aimed to evaluate the effect of bioactive glass as well as the presence of Ciprofloxacin drug (%Cip) into bioactive glass–chitosan composite on the in vivo behavior of these scaffolds. These scaffolds were implanted in the femoral condyl of an ovariectomized rat. The serum and organs (liver and kidney) of the under investigated rats were analyzed. Also the physicochemical properties of the prepared implants were assessed using Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) before and after implantation (at different periods of implantation). Biochemical and histological analyses of the under investigated rats proved the biocompatibility of the prepared scaffolds. The hydroxyapatite like layer was significantly precipitated on the surface of BG–CH scaffold than BG–CH–20Cip. In this same period, FT-IR of BG–CH shows complete disappearance of Si–O–Si. Their characteristics bands were replaced by P–O group arisen form bone apatite bands. Physicochemical results show progressive degradation of BG–CH and BG–CH–20Cip that occurred at the same time as replacement of the implant by an apatite layer. However, the bioresorbability and bioactivity of BG–CH are faster than those of BG–CH–20Cip. Therefore, the incorporation of the Ciprofloxacin in the BG–CH induces a retarding effect on the formation of the hydroxyapatite, and consequently on the ossification, without any side effects on the liver–kidney. 相似文献
109.
Mostafa Safdari Shadloo Amir Zainali Samir H. Sadek Mehmet Yildiz 《Computer Methods in Applied Mechanics and Engineering》2011,200(9-12):1008-1020
In this article, we present numerical solutions for flow over an airfoil and a square obstacle using Incompressible Smoothed Particle Hydrodynamics (ISPH) method with an improved solid boundary treatment approach, referred to as the Multiple Boundary Tangents (MBT) method. It was shown that the MBT boundary treatment technique is very effective for tackling boundaries of complex shapes. Also, we have proposed the usage of the repulsive component of the Lennard-Jones Potential (LJP) in the advection equation to repair particle fractures occurring in the SPH method due to the tendency of SPH particles to follow the stream line trajectory. This approach is named as the artificial particle displacement method. Numerical results suggest that the improved ISPH method which is consisting of the MBT method, artificial particle displacement and the corrective SPH discretization scheme enables one to obtain very stable and robust SPH simulations. The square obstacle and NACA airfoil geometry with the angle of attacks between 0° and 15° were simulated in a laminar flow field with relatively high Reynolds numbers. We illustrated that the improved ISPH method is able to capture the complex physics of bluff-body flows naturally such as the flow separation, wake formation at the trailing edge, and the vortex shedding. The SPH results are validated with a mesh-dependent Finite Element Method (FEM) and excellent agreements among the results were observed. 相似文献
110.