NIT-Ph-p-BEN氮氧自由基的制备及催化降解性

以对醛基苯甲酸为原料，通过醛酸与2,3-二甲基-2,3-二羟胺基丁烷缩合，再经NaIO4氧化最终制得4-(4,4,5,5-四甲基-1,3-二氧化物)咪唑基-1-苯甲酸（NIT-Ph-p-BEN氮氧自由基）。采用FTIR、UV、ERP（电子顺磁共振波谱仪）和元素分析等对其结构进行表征；通过催化降解废水中有机染料甲基橙、甲基蓝和罗丹明B对其催化活性进行了评估。结果表明，当甲基橙、甲基蓝和罗丹明B浓度为15 mg/L，NIT-Ph-p-BEN质量浓度为0.15 g/L，H2O2浓度为30 mmol/L时，NIT-Ph-p-BEN对甲基橙有更好的催化降解性，仅在1 h内甲基橙的降解率达到94.26%。此外，反应机理表明，H2O2有助于实现NIT-Ph-p-BEN自由基的再生和循环利用。     

基于退化四元小波变换的纸币识别

针对如何提取纸币图像特征和提高识别率的问题,综合利用退化四元小波变换具有的相位特性,提出一种基于退化四元小波变换的纸币识别方法.该方法首先对采集的纸币图像进行倾斜校正和边缘检测,然后运用退化四元小波对纸币图像进行分解操作,并对分解系数进行统计分析,将每个分解子带系数的能量和标准差作为该纸币图像的特征向量,最后将支持向量机作为分类器对纸币图像进行识别.本文方法在资源约束的嵌入式清分系统上实现,实验结果表明采用本文提出的算法突破了传统纸币识别系统识别率很难再提高的瓶颈,同时能够满足清分系统的实时性要求.     

Model-based test generation using extended symbolic grammars

A novel, model-based test case generation approach for validating reactive systems, especially those supporting richly structured data inputs and/or interactions, is presented. Given an executable system model and an extended symbolic grammar specifying plausible system inputs, the approach performs a model-based simulation to (i) ensure the consistency of the model with respect to the specified inputs, and (ii) generate corresponding test cases for validating the system. The model-based simulation produces a state transition diagram (STD) automatically justifying the model runtime behaviors within the test case coverage. The STD can further be transformed to produce an evolved symbolic grammar, which can then be used to incrementally generate a refined set of test cases. As a case study, we present a live sequence chart (LSC) model-based test generator, named LCT in short, for LSC simulation and consistency testing. The evolved symbolic grammar produced by the simulator can either be used to generate practical test cases for software testing, or be further refined by applying our model-based test generation approach again with additional test coverage criteria. We further show that LSCs can also be used to specify and test certain temporal system properties during the model simulation. Their satisfaction, reflected in the STD, can either be served as a directive for selective test generation, or a basis for further temporal property model checking.     

乙烯装置急冷油系统减粘技术的研究

基于乙烯装置急冷油和急冷系统结垢物的组成分析，探讨了急冷油增粘和系统结垢的机理．研究了适用于急冷油系统的新型减粘剂RIPP-1420和减粘剂的注入技术。结果表明，RIPP-1420减粘剂和该注入技术能有效降低急冷油系统物料的粘度，减少结垢物的生成。     

Processing and characterization of particles reinforced SiOC composites via pyrolysis of polysiloxane with SiC or/and Al fillers

Polysiloxane loaded with SiC as inert filler, and Al as active filler, was pyrolyzed in nitrogen to fabricate SiOC composites, and the processing and properties of the filled SiOC composites were investigated. Adding SiC fillers could reduce the linear shrinkage of filler-free cured polysiloxane in order to obtain monolithic SiC/SiOC composites. The flexural strength of SiC/SiOC composites reached 201.3 MPa at a SiC filler content of 27.6 vol.%. However, SiC/SiOC composites exhibited poor oxidation resistance, thermal shock resistance and high temperature resistance. Al fillers could react with hydrocarbon generated during polysiloxane pyrolysis at 600 °C and N₂ at 800 °C to form Al₄C₃ and AlN, respectively. The volume expansions resulting from these two reactions were in favor of the reduction in linear shrinkage and the improvement in flexural strength of SiC/SiOC composites. The flexural strength of Al-containing SiC/SiOC composites was 1.36 times that of SiC/SiOC composites without Al at an Al filler content of 20 vol.%. The addition of Al fillers remarkably improved the high temperature resistance and oxidation resistance of SiC/SiOC composites, but not thermal shock resistance.     

Ultrahigh molecular weight polyethylene/polypropylene/organo‐montmorillonite nanocomposites: Phase morphology,rheological, and mechanical properties

Phase morphology, rheological, and mechanical properties of ultrahigh molecular weight polyethylene (UHMWPE)/PP/organo‐montmorillonite nanocomposites were investigated in this work. The results of TEM and XRD indicated that the organo‐montmorillonite PMM prepared with the complex intercalator [2‐methacryloyloxyethyldodecyldimethylammonium bromide/poly(ethylene glycol)] were exfoliated and dispersed into UHMWPE matrix, and the synergistic effect of the complex intercalator on the exfoliation and intercalation for montmorillonite occurred. Besides, the presence of PMM in UHMWPE matrix was found able to lead to a significant reduction of melt viscosity and enhancement in tensile strength and elongation at break of UHMWPE, except that izod‐notched impact strength was without much obvious change. The dispersed PMM particles exhibited a comparatively large two‐dimensional aspect ratio (L_clay/d_clay = 35.5), which played an important role in determining the enhancement of mechanical properties of UHMWPE nanocomposites. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

加压条件下电梯活塞效应及疏散可行性分析

通过对电梯井加压和不加压条件下电梯运行活塞效应引起的电梯井内、建筑空间及外界之间的气体流动规律分析,确定火灾条件下烟气是否会卷入前室的临界质量流率。研究结果表明,只对电梯井的一个开口集中加压时,加压质量流率达到临界质量流率以上,活塞效应就不会引起加压损失;对电梯井上下部都加压时,上下加压质量流率各在临界质量流率的一半以上,活塞效应才不会引起加压损失。对于现状条件下的大多数电梯,特别是多梯井,通过设计来防止活塞效应引起烟气卷入前室是可行的。     

鲁棒的单类协同排序算法

单类协同过滤(One-class collaborative filtering, OCCF)问题是当前的一大研究热点.之前的研究所提出的算法对噪声数据很敏感,因为训练数据中的噪声数据将给训练过程带来巨大影响,从而导致算法的不准确性.文中引入了Sigmoid成对损失函数和Fidelity成对损失函数,这两个函数具有很好的灵活性,能够和当前最流行的基于矩阵分解(Matrix factorization, MF)的协同过滤算法和基于最近邻(K-nearest neighbor, KNN)的协同过滤算法很好地融合在一起,进而提出了两个鲁棒的单类协同排序算法,解决了之前此类算法对噪声数据的敏感性问题.基于Bootstrap抽样的随机梯度下降法用于优化学习过程.在包含有大量噪声数据点的实际数据集上实验验证,本文提出的算法在各个评价指标下均优于当前最新的单类协同排序算法.     

铰支柔性梁主参数共振的时滞反馈控制

研究了时滞反馈控制作用下铰支柔性梁主参数共振问题.采用多尺度法,从理论上推导了时滞位移反馈控制作用下铰支柔性梁非线性主参数共振,分析了时滞、反馈控制增益,非线性系数等系统参数对系统非线性主参数振动的影响,分析了主参数动力响应随参数变化的规律.结果表明:随着反馈增益的增大,系统响应幅值得到明显抑制,合理地控制系统参数选取可提高振动控制的效率.     

On Constrained MMVC of Discrete‐Time First‐Order Linear Stochastic Systems with PSI I: The Critically Stable Case

This paper is devoted to the study of the modified minimal variance control (MMVC) of discrete‐time first‐order linear critically stable stochastic systems with prospective strong intervention (PSI) and control input constraints. Due to different evolutionary characteristics of systems with PSI, that is, the two modes of tending to infinity and having bounded oscillations, the discrete‐time first‐order linear critically stable systems can be partitioned into two types regarding the signs of a key system parameter a. A necessary and sufficient condition for the state mean convergence of a system with a = 1 is derived and the corresponding design of MMVC is formulated. For the critical stable system with a =? 1, its oscillation amplitudes of state means can be effectively suppressed or the means can converge under control. Finally, the effectiveness and advantages of the proposed control strategies comparing with MVC are confirmed by numerical simulations.