Preparation,characterization and salt-resistance of a coal based super absorbent composite

Potassium humate was extracted from brown coal.A novel super absorbent composite,poly (acrylic acid-co-acrylamide)/potassium humate (PAA-AM/KHA),was prepared by graft polymerization of acrylic acid,acrylamide and coal based potassium humate using N,N'-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator.The effects of reaction temperature,degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker,initiator and potassium humate were investigated.Salt resistance tests were also carried out.The composite prepared under optimal conditions had a potassium humate content of 10% and exhibited a water absorption of 770 g/g in distilled water,and 349,286 and 41 g/g in 0.5 mol/L KC1,MgCl2 and AlCl3 solutions respectively.The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly (acrylic acid-co-acrylamide) because of the collaborative effect of functional groups of the coal based potassium humate.The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy.Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments.The salt resisting property of the composite is improved,production costs are reduced and the growth stimulant effect is still present.     

汽车磁流变减振器多项式模型的研究

将优化后的磁流变减振器放在MTS849减振器试验台上进行试验,在不同的减振器活塞运动速度下,改变通电电流,测试磁流变减振器的示功图和速度特性。利用试验数据,进行多项式拟合,精确的建立了该减振器的阻尼力模型,便于对其半主动悬架实施实时控制。     

Numerical simulation on bolted rock joint shearing performance

A Double Shear Model(DSM)was used in a numerical simulation on bolted rock joint shearing performance.An entire bolt deformed as the letter"U"under a shear load between two joints.Near the bolt-joint intersection,the bolt partly deformed as the letter"Z".There were two critical points along the bolt: one was at the bolt-joint intersection with zero bending moment and the other at the maximum bending moment(plastic hinge)with zero shear stress.The blocks on two sides slid along the bolt as it deformed.A separation area was found between the two joint contact surfaces of the middle rock block and sided block.This area of separation was related to bolt diameter and external forces.We assume that this area is related to the work of external forces.Further research is needed.     

电弧喷涂马氏体不锈钢涂层耐磨性

为了系统地研究电弧喷涂马氏体不锈钢涂层的耐磨粒磨损性能,选用几种不同含碳量的马氏体不锈钢作为喷涂材料,制备了不同喷涂工艺参数的试件;采用喷砂吹蚀和湿砂橡胶轮磨损试验研究了涂层试件的耐磨粒磨损性能.试验结果表明,随着喷涂材料w（C）的增加,获得的涂层硬度增加,涂层耐磨粒磨损性能也随之增强.涂层制备的工艺参数对涂层的耐磨性影响很大,增加喷涂电流,涂层耐磨粒磨损性能提高;增加喷涂电压或加大喷涂距离,涂层耐磨粒磨损性能下降.     

四叔丁基萘酞菁氧钒非线性及光限幅特性

为提高酞菁化合物的非线性光学性能,以1,8-二氮杂双环[5.4.0]十一碳烯-7(DBU)为催化剂,采用液相法合成了四叔丁基萘酞菁氧钒((t-Bu)4NcVO)化合物.利用元素分析、红外光谱、核磁共振氢谱方法,验证了化合物的分子结构.应用调Q倍频ns/ps Nd∶YAG脉冲激光系统,在波长为532nm下,研究了化合物的非线性和光限幅特性.测得化合物的非线性折射率n2和三阶非线性极化率χ(3)分别为2.51×10-11esu和8.54×10-12esu,通过计算得到分子极化率γ’为3.7×10-29esu.在透过率69%时限幅阈值为1608mJ/cm2,箝位值为585mJ/cm2,有效激发态与基态吸收截面比为3.66.     

Simulation and optimization of SOFC-BCHP system

As the prime motor of dispersed energy system, the high-temperature solid oxide fuel cells (SOFC) are high efficient with large heat recovery. This study presents a simulation of SOFC building-based cooling, heat and power (BCHP) system, which can meet basic requirements in power and heating (cooling) of the designated customers. The peak power load can be met by power grid, while the peak heating (cooling) load requirement can be met by backup equipments. In order to solve the economic dispatch problem of the energy system, a restricted nonlinear optimization model has been developed. The production costs can be minimized via both the equality constraints of customer’s heat and power demands, and other inequality constrains of equipments’ capacities. The sequential quadratic programming method has been used to search the solution. The study indicates that the model can be used to optimize the system’s capacities and run strategy. An office building case has been computed, and it is indicated that the model can be served in design and optimization of SOFC-BCHP system.     

Influence of nitrogen hetero-substitution on the electrochemical performance of coal-based activated carbons measured in non-aqueous electrolyte

Nitrogen-containing carbons were prepared by modification of activated carbons. The modified carbons were used as electrode materials with improved electrochemical performance. Precursor anthracite was activated by KOH (KOH: anthracite= 1:1), modified by melamine or urea and then treated at 1173 K to obtain the modified carbons. The porous structure, the chemical composition and the electrochemical characteristics of the carbons were investigated by nitrogen sorption, XPS and electrochemical methods respectively. Electrochemical experiments were performed in an organic electrolytic solution of 1 M (C2H5)4NBF4/PC.The samples modified by the different methods showed differences in chemical composition that introduced varying degrees of electrochemical performance enhancement. The presence of nitrogen enhanced the electron donor properties and the surface wettability of the activated carbons: this ensured a sufficient utilization of the exposed surface for charge storage.     

基于网络的多卡加密系统调度模型

在分析L inux系统单卡加密系统的基础上,详细分析了影响单卡加密系统并行处理数据报文效率的原因,提出了一种能够改善报文处理效率的基于网络的多卡加密系统调度模型,讨论了多卡加密系统调度模型的特点,分析了该模型中各模块的功能.通过实例,比较了单卡和多卡加密系统在并行处理数据报文时的差异.结果表明,多卡加密系统调度模型是网络平台下的信息安全传输的一种优化方法.     

基于蓝牙技术的移动设备实现无线上网的研究及系统的实现

蓝牙技术是移动通信技术和计算机网络技术结合的产物,它的出现使蓝牙无线个人区域网成为当前发展最迅速的领域之一.在众多无线技术中,蓝牙以其功耗低、成本低廉、组网灵活等优点而成为新的研究热点,是个人局域网（PAN）的理想实现技术.在对蓝牙技术和无线个人局域网进行分析和研究的基础上,并针对一个开发实例——实现多个移动终端设备接入互联网的蓝牙局域网接入应用,分别详细地介绍了移动终端设备软件和蓝牙局域网无线接入在Windows系统上的实现过程.     

基于AHP法的中低收入群体住房改善方案分析

通过对中低收入群体住房现状分析,构建了以相对最佳的住房改善方案为目标层;以住户对住房产品的满意、社会人均住房水平提高的效率高、参与建设各方获得良好经济效益3方面组成准则层;以经济适用房、廉租房、双限房、普通商品住房构成方案层的AHP模型。进行赋值计算后,得出当前发展经济适用房是相对最佳方案,发展廉租房次之,发展双限房第三,发展普通商品住房排名最后的结论。