热电型太赫兹探测器响应度校准技术

为保证太赫兹辐射强度测量的准确可靠,对热电型太赫兹探测器的响应度进行了校准。首先,基于替代法构建了太赫兹探测器响应度校准装置,该装置的合成标准不确定度为2.4%。然后,在1.63 THz频率点处,利用校准装置对12D-3S-VP型太赫兹探测器进行了校准,得到的响应度校准结果为197.6 mV/W,与厂家标称值一致。对自主研制的热电型太赫兹探测器进行了校准,得到的响应度和合成标准测量不确定度分别为362.2 mV/W和2.7%。最后,将校准结果的标准偏差值与合成标准不确定度进行了比较,发现标准偏差值在合理范围内,这进一步证明了校准方法、校准结果以及不确定度分析的合理性。     

Highly enantioselective regiodivergent allylic alkylations of MBH carbonates with phthalides

Phthalides were used for the first time in the allylic alkylation reactions with MBH carbonates for the creation of chiral 3,3-disubstituted phthalides. Highly enantioselective regiodivergent synthesis of γ-selective or β-selective allylic alkylation products was achieved by employing bifunctional chiral phosphines or multifunctional tertiary amine-thioureas as the catalyst, respectively. It was demonstrated that proper selection of catalysts and reaction conditions would differentiate an S(N)2'-S(N)2' pathway and an addition-elimination process, yielding different regioisomers of the allylic alkylation products in a highly enantiomerically pure form.     

多圆盘Hardy空间的不变子空间(英文)

设M是多圆盘Hardy空间H²（Tⁿ）的不变子空间.R_zi是以坐标函数z_i（i=1,2,…,n）为符号的乘法算子在M上的限制.本文作者证明了,存在一个内函数q,使得M=qH²（Tⁿ）当且仅当对i≠j,R_ziR_zj^*=R_zj^*R_zi.     

Theoretical study on instantaneous linewidth of Fourier-domain mode-locked fiber lasers

We have numerically simulated the operation of the Fourier-domain mode-locked (FDML) fiber laser based on the wavelength reconstruction method instead of numerical solving the nonlinear Schrödinger equation. We studied the influences of the filter bandwidth and the relative time delay caused by the fiber chromatic dispersion on the instantaneous linewidth of the FDML fiber laser. The results show that the instantaneous linewidth broadens as the filter bandwidth and the relative time delay increase. When the filter has the bandwidth of 0.02 nm, the narrowest and broadest instantaneous linewidths are 0.024 and 0.042 nm, respectively. We give an understanding for the oscillation of the instantaneous linewidth of FDML. The presented result can be used to evaluate the performance achievable in the FDML fiber lasers.     

Polarization fluctuations of Gaussian Schell-model type photon beams in a slant channel with non-Kolmogorov turbulence

Polarization properties of Gaussian Schell-mode type photon beams propagating through the non-Kolmogorov turbulence in a slant channel are studied which are based on the model of quantum field and the effective photon annihilation/creation operator. Our numerical results show that the degree of polarization increases with the increasing of the transverse coherent width of source ρ_s0, the source's transverse size ω₀ and the power law of the turbulent spectrum, but the degree of polarization P decreases as the zenith angle θ increases. The effect of the wavelength of light beam on the degree of polarization of Gaussian Schell-model beams is small.     

Long period grating cascaded to photonic crystal fiber modal interferometer for simultaneous measurement of temperature and refractive index

We propose and demonstrate a novel and simple dual-parameter measurement scheme based on a cascaded optical fiber device of long-period grating (LPG) and photonic crystal fiber (PCF) modal interferometer. The temperature and refractive index (RI) can be measured simultaneously by monitoring the spectral characteristics of the device. The implemented sensor shows distinctive spectral sensitivities of -30.82 nm/RIU (refractive index unit) and 47.4 pm/°C by the LPG, and 171.96 nm/RIU and 10.4 pm/°C by the PCF modal interferometer. The simultaneous measurement of the temperature and external RI is experimentally demonstrated by the sensor. The temperature shift and RI shift calculated by the sensor matrix agree well with the actual temperature and RI change in the experiment.     

大尺度三维几何尺寸立体视觉测量系统实现

基于立体视觉的大尺度三维几何尺寸测量技术是对外形不规则的大型物体进行几何量测量的有效方法。与传统的视觉测量技术不同,大尺度视觉测量的精度随测量距离的增加而迅速下降,同时大尺度空间下照明条件难以控制,也使得测量变得不稳定。因此如何在大测量尺度的前提下提高测量精度成为这一领域的研究难点。从立体视觉测量系统的原理出发,分析了影响系统精度的各种因素,将相位一致性变换与极线约束条件引入结构光光条中心提取之中,显著提高了图像分析的精度。研制了测量系统的样机并给出了实验结果,现场测试表明该系统可以有效地保证大尺度条件下的测量精度。     

Direct asymmetric Mannich reaction of phthalides: facile access to chiral substituted isoquinolines and isoquinolinones

The first Mannich reaction employing phthalides using a quinidine-based multifunctional catalyst has been developed. The reported method led to the synthesis of 3,3-disubstituted phthalide derivatives in excellent yields, with good diastereo- and enantioselectivities. Convenient synthesis of chiral isoquinolinones and isoquinolines has also been demonstrated.     

稀土氧化物上SO2和NO的催化还原Ⅱ.用CO作还原剂的脱硫及反应机理

采用连续流动固定床石英反应器,在反应气体为1%SO2和2%CO, 流量为180 ml/min, 以及催化剂用量为0.5 g的条件下,考察了经活化处理的稀土系列氧化物对CO还原SO2的催化活性,探讨了空速、温度和水蒸气等因素对反应的影响.所研究的样品依据对SO2的转化能力可分为三组: 高活性的镧、镨、钕、钐、铕和钆氧化物; 低活性的铈、钬和铒氧化物; 无活性的铽和镝氧化物.在活性最高的钕和钐氧化物样品上, 450 ℃时SO2的转化率＞98%.反应过程中,活性相为稀土氧硫化物,反应遵从COS中间物机理.     

稀土氧化物上SO2和NO的催化还原 Ⅱ.用CO作还原剂的脱硫及反应机理

采用连续流动固定床石英反应器,在反应气体为１％ＳＯ２和２％ＣＯ,流量为１８０ｍｌ／ｍｉｎ,以及催化剂用量为０．５ｇ的条件下,考察了经活化处理的稀土系列氧化物对ＣＯ还原ＳＯ２的催化活性,探讨了空速、温度和水蒸气等因素对反应的影响,所研究的样品依据对ＳＯ２的转化能力可分为三组：高活性的镧、镨、钕、钐、铕和钆氧化物;低活性的铈、狄和铒氧化物;无活性的铽和氧化物,在活性最高的钕和钐氧化物样品上,４５０℃时ＳＯ２的转化率〉９８％,反应过程中,活性相为稀土氧硫化物,反应遵从ＣＯＳ中间物机理。