We revisit the second-order nonlinear least square estimator proposed in Wang and Leblanc (Anne Inst Stat Math 60:883–900, 2008) and show that the estimator reaches the asymptotic optimality concerning the estimation variability. Using a fully semiparametric approach, we further modify and extend the method to the heteroscedastic error models and propose a semiparametric efficient estimator in this more general setting. Numerical results are provided to support the results and illustrate the finite sample performance of the proposed estimator. 相似文献
The crystal structures and magnetic properties of two novel polyclusters {[Cu(3)(tci)(2)(H(2)O)(2)]·12H(2)O}(n) (1) and {[Cu(3)(tci)(2)(H(2)O)(2)]·6H(2)O}(n) (2) (tci = tris(2-carboxyethyl) isocyanurate) are investigated. The X-ray crystallographic analysis reveals that they contain interesting infinite alternating chains of dinuclear paddle-wheel copper and mononuclear copper units arranged in ABBA magnetism exchange mode. Variable-temperature magnetic susceptibility measurements on the two polyclusters show strong antiferromagnetism couplings between copper ions with exchange interactions J = -181.4 cm(-1), zj' = -0.31 cm(-1) for 1, J = -170 cm(-1), zj' = -0.42 cm(-1) for 2. With the aim of studying magneto-structural correlation, we synthesized a three-dimensional polymer [Cu(3)(tci)(2)(py)(4)(H(2)O)(2)](n) (3) based on isolated dinuclear cluster and mononuclear copper units. Fitting the susceptibility data yielded J = -176.1 cm(-1), zj' = -0.084 cm(-1) for 3. 相似文献
Novel vanadium dioxide nanorods were fabricated via a surfactant-assisted hydrothermal method at 180 °C for 48 h in the presence of cetyltrimethylammonium bromide (CTAB). The self-assembled samples were characterized by XRD, SEM, TEM, HRTEM and FT-IR. The results show that the products are nanorods, which are pure B phase vanadium dioxide with high crystallinity. The obtained nanorods have diameters of 40-60 nm with lengths up to 1-2 um. The probable formation mechanism of vanadium dioxide is also discussed. 相似文献
A microporous luminescent metal-organic framework [Zn_4L_2(H_2O)_2].(H_2O)_m(DMA)_n(1)(H_4L=5,5'-((1H-pyrazole-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid, DMA=N,N-dimethylacetamide) was synthesized and characterized by infrared radiation(IR), thermogravimetric analyses(TGA), powder X-ray diffraction spectra(PXRD) and X-ray diffraction. Complex 1has a three dimensional(3D) framework, which can be simplified as 5,5,5,5-c net with the Schlfi symbol of {43.64.83}{44.65.8}{45.65}2. This luminescent metal-organic framework(MOF) shows selectively sensitive to nitrobenzene and series of nitroaromatic explosives such as 4-nitrotoluene, 1,4-dinitrobenzene, 1,3-dinitrobenzene and 2,4-dinitrotoluene, and exhibits well recyclability. So complex 1 could be used to detect nitroaromatic explosives as a selective sensing material. 相似文献
In the mean regression context, this study considers several frequently encountered heteroscedastic error models where the regression mean and variance functions are specified up to certain parameters. An important point we note through a series of analyses is that different assumptions on standardized regression errors yield quite different efficiency bounds for the corresponding estimators. Consequently, all aspects of the assumptions need to be specifically taken into account in constructing their corresponding efficient estimators. This study clarifies the relation between the regression error assumptions and their, respectively, efficiency bounds under the general regression framework with heteroscedastic errors. Our simulation results support our findings; we carry out a real data analysis using the proposed methods where the Cobb–Douglas cost model is the regression mean.