全文获取类型
收费全文 | 533篇 |
免费 | 12篇 |
国内免费 | 2篇 |
学科分类
数理化 | 547篇 |
出版年
2022年 | 9篇 |
2021年 | 6篇 |
2020年 | 11篇 |
2019年 | 11篇 |
2018年 | 15篇 |
2017年 | 10篇 |
2016年 | 14篇 |
2015年 | 11篇 |
2014年 | 19篇 |
2013年 | 44篇 |
2012年 | 30篇 |
2011年 | 23篇 |
2010年 | 19篇 |
2009年 | 23篇 |
2008年 | 16篇 |
2007年 | 19篇 |
2006年 | 16篇 |
2005年 | 17篇 |
2004年 | 13篇 |
2003年 | 6篇 |
2002年 | 12篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 6篇 |
1998年 | 5篇 |
1997年 | 4篇 |
1996年 | 7篇 |
1994年 | 14篇 |
1993年 | 5篇 |
1992年 | 9篇 |
1989年 | 4篇 |
1988年 | 9篇 |
1987年 | 8篇 |
1985年 | 6篇 |
1984年 | 10篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 6篇 |
1978年 | 4篇 |
1977年 | 11篇 |
1976年 | 7篇 |
1975年 | 7篇 |
1974年 | 4篇 |
1973年 | 6篇 |
1969年 | 7篇 |
1968年 | 3篇 |
1967年 | 4篇 |
1966年 | 3篇 |
排序方式: 共有547条查询结果,搜索用时 15 毫秒
31.
32.
We have synthesized a new series of azo‐bis antipyrine derivatives from a one‐pot multicomponent Knoevenagel/Michael addition reaction of antipyrine, with a diversity of azo aldehydes in ethanol and L‐Proline as a catalyst under reflux condition. The anti‐inflammatory activity of the final products was assessed using the inhibition of albumin denaturation technique. Compound 3f showed an inhibitory effect with IC50 values of 3.6 μM with respect to the standard anti‐inflammatory drug Aspirin, with IC50 values of 2 μM. In addition, molecular docking was performed to confirm the in vitro results against the enzymatic inhibition activity of COX‐2 enzymes in which compound 3f showed good binding affinity with an inhibition constant (Ki) of 1.79 nM. 相似文献
33.
Yantao Pang Anoop Thomas Kalaivanan Nagarajan Robrecht M. A. Vergauwe Kripa Joseph Bianca Patrahau Kuidong Wang Cyriaque Genet Thomas W. Ebbesen 《Angewandte Chemie (International ed. in English)》2020,59(26):10436-10440
It is well known that symmetry plays a key role in chemical reactivity. Here we explore its role in vibrational strong coupling (VSC) for a charge‐transfer (CT) complexation reaction. By studying the trimethylated‐benzene–I2 CT complex, we find that VSC induces large changes in the equilibrium constant KDA of the CT complex, reflecting modifications in the ΔG° value of the reaction. Furthermore, by tuning the microfluidic cavity modes to the different IR vibrations of the trimethylated benzene, ΔG° either increases or decreases depending only on the symmetry of the normal mode that is coupled. This result reveals the critical role of symmetry in VSC and, in turn, provides an explanation for why the magnitude of chemical changes induced by VSC are much greater than the Rabi splitting, that is, the energy perturbation caused by VSC. These findings further confirm that VSC is powerful and versatile tool for the molecular sciences. 相似文献
34.
R. Nagarajan A. K. Grover S. K. Dhar P. L. Paulose V. Nagarajan E. V. Sampathkumaran 《Hyperfine Interactions》1988,42(1-4):1227-1230
151Eu Mössbauer studies have been made across the respective superconductive transition temperatures in two compounds, La1.7Eu0.1Sr0.2CuO4?y and EuBa2Cu3O7, having zero resistance state at 25K and 85K respectively. The151Eu isomer shift data establish that Eu ions are in trivalent state at all temperatures. The Mössbauer f-factor does not show any significant anomaly across the TC. 相似文献
35.
36.
In recent days, humans are easily exposed to many work-related health issues. N-nitrosodiethylamine (NDE), which is considered to be a harmful carcinogenic agent released from rubber-based industries imparts a long-lasting effect on human health and immunity system. The current research investigates the ability of the two-dimensional nanomaterial, blue phosphorene nanosheet (BPNS) to detect the presence of NDE in the environment. Besides, the electronic and structural characteristics of BPNS are initially explored and NDE target vapour is permitted to interact with the chief component, BPNS. We have also designed blue phosphorene device to study the adsorption properties of NDE vapours based on current–voltage characteristics. The adsorption attributes are accounted for the target vapour adsorbed chief component, the results suggest that BPNS can be employed in detecting NDE vapours. 相似文献
37.
Jeyakumar Nagarajan Narayanasamy Bose 《Journal of Thermal Analysis and Calorimetry》2020,139(1):475-487
Journal of Thermal Analysis and Calorimetry - The solid–liquid equilibria (SLE) of two binary mixtures of organic stabilizers for energetic materials, viz.... 相似文献
38.
NH4H2PO4 (ADP) has been investigated by infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis and d.c. conductivity in the temperature range of 25–180° C. Sharp reversible changes were observed in the region from 400 to 500 cm?1 of the infrared spectra in the temperature range of 138–174° C. Similar and supportive data were obtained with DSC, TGA and DC conductivity measurements. The results clearly suggest a high temperature phase transition for ADP before its melting point. 相似文献
39.
Sankaran Viswanath 《代数通讯》2013,41(11):3903-3933
We continue the study of stabilization phenomena for Dynkin diagram sequences initiated in the earlier work of Kleber and the present author. We consider a more general class of sequences than that of this earlier work, and isolate a condition on the weights that gives stabilization of tensor product and branching multiplicities. We show that all the results of the previous article can be naturally generalized to this setting. We also prove some properties of the partially ordered set of dominant weights of indefinite Kac–Moody algebras, and use this to give a more concrete definition of a stable representation ring. Finally, we consider the classical sequences B n , C n , D n that fall outside the purview of the earlier work, and work out some easy-to-describe conditions on the weights which imply stabilization. 相似文献
40.
Komal Kurlekar Anshika Anjali Dr. Predhanekar Mohamed Imran Prof. Samuthira Nagarajan 《Chemphyschem》2023,24(2):e202200375
A series of new zinc porphyrins were synthesized, and their charge transport property was tuned by introducing various groups. Triarylamine was introduced to the porphyrin moiety at the meso-position as an electron donor, enhancing the charge carrier mobility. All the synthesized zinc porphyrins are thermally stable with a decomposition temperature over 178 °C. High frontier molecular orbitals levels of these compounds make them stable donor materials. SEM analysis of zinc porphyrins fabricated by spin-coating resulted in diversely self-assembled films. Field-effect transistors were fabricated using bottom-gate/top-contact architecture (BGTC) by solution-processable technique. The higher charge carrier mobility of 5.17 cm2/Vs with on/off of 106 was obtained for trifluoromethyl substituted compound due to better molecular packing. In addition, GIXRD analysis revealed zinc porphyrins films crystalline nature, which supports its better charge carrier mobility. The present investigation has validated that zinc porphyrin building blocks are an attractive candidate for p-channel OFET devices. 相似文献