定点处全微分和相关计算问题的解法探究

根据偏导函数的定义,抓住问题的本质,能够给出有关定点处全微分计算及相关计算问题更为简洁、有效的求解方法.     

SrSnO3纳米粒子的制备及其光催化性能

以硝酸锶[Sr（NO₃）₂]和结晶四氯化锡（SnCI₄·5H₂O）为原料,有机碱四甲基氢氧化铵[N（CH₃）₄OH]为矿化剂,采用共沉淀法制备SrSnO₃纳米粒子。用XRD和IR对样品的物相和结构进行表征,并研究了对亚甲基蓝废水的光催化降解性能。结果表明:用该法在500℃煅烧1h时制备的纯立方相SrSnO₃纳米晶粒在可见光照下具有良好的光催化性能。催化剂浓度为60mg/L,反应时间为100min时,降解率可达94%。     

含中心功能基Schif碱大环配合物和氮杂大环自由配体的合成

使用Ｂａ２＋作为模板离子，将１，５－二（邻氨基苯氧基）－３－氧杂戊烷（３）分别与４－取代的２，６－二甲酰基苯酚（１ａ～１ｃ）反应，获得高收率的Ｓｃｈｉｆ碱大环配合物（４ａ～４ｃ），再经ＮａＢＨ４还原解络，得到氮杂大环自由配体（Ｌ１～Ｌ３）．本文研究和改进了４－取代的２，６－二甲酰基苯酚（１ａ～１ｃ）的合成方法，由４－取代的２，６－二羟甲基苯酚经活性ＭｎＯ２一步氧化，即可获得较好收率的产物（１ａ～１ｃ）．所有Ｓｃｈｉｆ碱大环配合物和氮杂大环自由配体均经元素分析、ＩＲ、１ＨＮＭＲ和ＭＳ等证实了它们的结构和组成．     

用于抗肿瘤药物评价的三维肿瘤细胞体系的构建及性能

以聚己内酯和明胶为原料,通过静电纺丝制得孔隙率高、细胞分散性好、机械性能佳的三维细胞支架;扫描电镜及共聚焦显微镜表征U87细胞在该三维支架内培养14天后的生长情况,结果表明U87细胞不仅能够在支架表面黏附增殖,而且能迁移进入静电纺丝膜内部生长,形成良好的三维细胞体系.游离阿霉素(DOX)对二维表面和三维静电纺丝膜中U87细胞的细胞毒性结果表明,相对于二维细胞体系而言,三维细胞体系对药物的敏感性能降低.进一步比较了二维与三维细胞对负载于聚乙二醇-b-聚己内酯(PEG-b-PCL)胶束中DOX的响应,三维细胞体系的药物敏感性低于二维体系.     

分光光度法研究PbSnO3纳米粒子对甲基橙溶液的光降解性

采用共沉淀法制备出完整的立方相锡酸铅纳米粒子,并研究了其对甲基橙溶液的光催化降解性能.结果表明：PbSnO3催化剂对甲基橙溶液有良好的光催化降解效果.当催化剂用量为60mg/L,反应时间为80min时,降解率可达90％以上.     

石墨型C3N4的固态合成及嵌锂性能研究

采用固态反应方法制备了石墨型C3N4. 采用XRD, FTIR, XPS对产物的组成和结构进行了表征. 研究了石墨型C3N4的电化学行为, 并将其用作负极材料组装成锂离子电池进行测试, 发现该材料具有一定的嵌锂能力, 但比容量低, 循环寿命短. 采用少量嵌入Mg2＋, Al3＋的方法对石墨型C3N4进行改性, 结果发现石墨型C3N4的充放电性能得到一定改善.     

Electron Transport Behavior of Multiferroic Perovskite BiMnO_3 Prepared by Co-Precipitation Method

Perovskite BiMnO_3 samples are successfully synthesized by the co-precipitation method at relatively low pressure and moderate temperature.The temperature dependences of resistivity are measured and systematically investigated.It is shown that the electrical resistivity increases sharply with the decrease of temperature above 210 K and the fitted results demonstrate that the thermally activated conduction model is the dominant conduction mechanism for the electron transport behaviors in this temperature region.A dual conducting mechanism,i.e.,the variable range hopping and thermal activated conduction,is suggested to be responsible for the transport behaviors of BiMnO_3 in the region of 180–200 K.Moreover,the resistivity increases slightly with the decrease of temperature below 180 K and the transport is governed by the variable range hopping mechanism.     

大型球轴承摩擦力矩试验台的研制及其实用性能的试验研究

为了研究大型轴承的摩擦性能，研制了一种可以测量外径２００～１５００ｍｍ球轴承的启动力矩、运转平均力矩、最大力矩和力矩变化幅值的大型轴承摩擦力矩试验台．这种试验台可以模拟轴承的启动角加速度、转动速度、预负荷和轴向工作负荷等．在此试验台上，对大型角接触球轴承成对预紧时的摩擦力矩与预紧量之间的关系进行了试验研究，并且根据试验结果，提出了一种适用于轴承外径２００～５００ｍｍ，转动速度低于３０ｒ／ｍｉｎ时计算摩擦力矩的经验公式．     

Large-aperture collimated wavefront evaluation based on sparse subaperture北大核心CSCD

A wavefront evaluation method based on sparse subaperture was proposed for the collimated wavefront of 300 mm aperture wavelength-tuned interferometer. The method used the wavefront data of sparse aperture to construct a uniform and equally spaced subaperture arrangement model and utilized the simultaneous fitting algorithm to realize the reconstruction of the full-aperture collimated wavefront. The change rules of subaperture spacing and subaperture size on the reconstruction accuracy were analyzed by the numerical calculation, and the optimized subaperture arrangement way was obtained. Finally, an optimized subaperture arrangement with a subaperture size of 10.8 mm and an adjacent subaperture center spacing of 9.72 mm was used for the sparse subaperture evaluation of 300 mm aperture collimated wavefront. The simulation results show that the optimized sparse subaperture evaluation wavefront residual peak valley (PV) value is 0.001 6λ and the residual root mean square (RMS) value is 1.689 3e−4 λ. Copyright ©2022 Journal of Applied Optics. All rights reserved.