梨小食心虫信息素的合成

以环辛酮,醇混合物为原料,经八步反应,合成了梨小食心虫性信素.总得率为16%,纯度98%,Z-式与E-式之比为95:5,这是生物活性最佳的组成.     

Si调制掺杂AlGaN/GaN异质结磁阻拍频现象

在低温（15K—25K）和强磁场（0—10T）条件下，对二维电子气占据两个子带的Si调制掺杂AlGaN/GaN异质结构进行磁输运测量.在一定温度范围内观察到磁阻拍频现象.根据Sander等人和Raikh等人给出的磁阻振荡的具体表达式，拟合实验结果表明磁阻拍频是由第一子带S dH振荡和磁致子带间散射引起的磁阻振荡导致的. 关键词： AlGaN/GaN异质结构 SdH振荡 磁致子带间散射 磁阻拍频     

Scattering behaviours to the two-dimensional electron gasinduced by the Al composition fluctuation in AlxGa1-xNbarrier in AlxGa1-xN/GaN heterostructures

<正>This paper reports that cathodoluminescence（CL） measurements have been done to study the alloy fluctuation of the Al_0.3Ga_0.7N layer in Al_0.3Ga_0.7N/GaN heterostructures.The CL images and linescanning results demonstrate the existence of compositional fluctuation of Al in the Al_0.3Ga_0.7N barrier.A model using aδ-shape perturbation Hamilton function has been proposed to simulate the scattering probability of the two dimensional electron gases （2DEG） induced by Al composition fluctuation.Two factors,including conduction band fluctuation and polarization electric field variation,induced by the Al composition fluctuation have been taken into account.The scattering relaxation time induced by both factors has been estimated to be 0.31 ns and 0.0078 ns,respectively,indicating that the variation of the piezoelectric field is dominant in the scattering of the 2DEG induced by Al fluctuation.     

Thermal stability of tungsten and tungsten nitride Schottky contacts to AlGaN/GaN

Thin tungsten nitride (WNx) films were produced by reactive DC magnetron sputtering of tungsten in an Ar-N2 gas mixture. The films were used as Schottky contacts on AlGaN/GaN heterostructures. The Schottky behaviours of WNx contact was investigated under various annealing conditions by current-voltage (I-V ) measurements. The results show that the gate leakage current was reduced to 10-6 A/cm2 when the N2 flow is 400 mL/min. The results also show that the WNx contact improved the thermal stability of Schottky contacts. Finally, the current transport mechanism in WNx/AlGaN/GaN Schottky diodes has been investigated by means of I-V characterisation technique at various temperatures between 300 K and 523 K. A TE model with a Gaussian distribution of Schottky barrier heights (SBHs) is thought to be responsible for the electrical behaviour at temperatures lower than 523 K.     

Optimization of a solar-blind and middle infrared two-colour photodetector using GaN-based bulk material and quantum wells

This paper calculates the wavelengths of the interband transitions as a function of the Al mole fraction of Al_xGa_1-xN bulk material. It is finds that when the Al mole fraction is between 0.456 and 0.639, the wavelengths correspond to the solar-blind (250~nm to 280~nm). The influence of the structure parameters of Al_yGa_1-yN/GaN quantum wells on the wavelength and absorption coefficient of intersubband transitions has been investigated by solving the Schr?dinger and Poisson equations self-consistently. The Al mole fraction of the Al_yGa_1-yN barrier changes from 0.30 to 0.46, meanwhile the width of the well changes from 2.9~nm to 2.2~nm, for maximal intersubband absorption in the window of the air (3~μm <λ <5~μm). The absorption coefficient of the intersubband transition between the ground state and the first excited state decreases with the increase of the wavelength. The results are finally used to discuss the prospects of GaN-based bulk material and quantum wells for a solar-blind and middle infrared two-colour photodetector.     

氮化蓝宝石衬底上GaN薄膜的微结构与光学性质

用透射电子显微镜(TEM),X射线衍射(XRD)和光荧光谱(PL)等测量手段研究了GaN薄膜的微结构和光学性质。样品是用光辐射加热MOCVD在蓝宝石衬底上制备的。随着衬底氮化时间的增加,扩展缺陷的密度显著增加。在位错密度增加一个数量级时,XRD摇摆曲线半宽度(FWHM)由11″增加到15″,PL谱的黄光发射从几乎可忽略增加到带边发射强度的100倍。结合生长条件,我们对黄光与微结构的关系作了讨论。     

Phase transition in evolution of traffic flow with scale-free property

This paper investigates the behaviour of traffic flow in traffic systems with a new model based on the NaSch model and cluster approximation of mean-field theory. The proposed model aims at constructing a mapping relationship between the microcosmic behaviour and the macroscopic property of traffic flow. Results demonstrate that scale-free phenomenon of the evolution network becomes obvious when the density value of traffic flow reaches at the critical point of phase transition from free flow to traffic congestion, and jamming is limited in this scale-free structure.     

Effects of Dislocation on High Temperature Transport Characteristics of Unintentionally Doped GaN

High temperature transport characteristics of unintentionally doped GaN have been investigated by means of high temperature Hall measurements from room temperature to 500^o C. The increment of electron concentration from room temperature to 500^o C is found to vary largely for different samples. The dispersion of temperature dependence of electron concentration is found to be directly proportional to the density of dislocations in GaN layers calculated by fitting the FWHM of the rocking curves in x-ray diffraction measurements （XRD）. The buildup levels in persistent photoconductivity （PPC） are also shown to be directly proportionM to the density of dislocations. The correlation of XRD, Hall and PPC results indicate that the high temperature dependence of electron density in unintentional doped GaN is directly dislocation related.     

HPLC法同时测定果汁饮料中曙红、荧光桃红、荧光素钠

建立了同时检测果汁饮料中曙红、荧光桃红、荧光素钠的高效液相色谱分析方法.果汁饮料样品经甲醇超声提取后,补足重量,静置15 min,过0.45 μm的微孔滤膜.采用Agilent Zorbax Plus SB-Aq柱(250mm×4.6mm,5μm)分离,以乙腈-NH4 H2 PO4溶液(0.05 mol/L,用H3PO...     

单层MoS2薄膜的NaCl双辅助生长方法

以单层二硫化钼(MoS₂)为代表的过渡金属硫族化合物半导体材料具有良好的光学、电学性质,近十年来引起了人们广泛的研究兴趣.合成高质量单层MoS₂薄膜是科学研究及工业应用的基础.最近科研人员提出了盐辅助化学气相沉积生长单层薄膜的方法,大大提高了单层MoS₂薄膜的生长速度及晶体质量.本文基于此方法,提出利用氯化钠(NaCl)的双辅助方法,成功制备了高质量的单层MoS₂薄膜.光致发光(PL)谱显示其发光强度比无NaCl辅助生长的样品有了明显的提高.本文提出的NaCl双辅助生长方法为二维材料的大规模生长提供了思路.