全文获取类型
收费全文 | 380篇 |
免费 | 57篇 |
国内免费 | 159篇 |
学科分类
数理化 | 596篇 |
出版年
2023年 | 4篇 |
2022年 | 6篇 |
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 4篇 |
2018年 | 5篇 |
2017年 | 5篇 |
2016年 | 6篇 |
2015年 | 8篇 |
2014年 | 11篇 |
2013年 | 15篇 |
2012年 | 17篇 |
2011年 | 12篇 |
2010年 | 21篇 |
2009年 | 18篇 |
2008年 | 22篇 |
2007年 | 11篇 |
2006年 | 16篇 |
2005年 | 21篇 |
2004年 | 16篇 |
2003年 | 18篇 |
2002年 | 21篇 |
2001年 | 13篇 |
2000年 | 23篇 |
1999年 | 33篇 |
1998年 | 26篇 |
1997年 | 29篇 |
1996年 | 20篇 |
1995年 | 22篇 |
1994年 | 26篇 |
1993年 | 17篇 |
1992年 | 19篇 |
1991年 | 20篇 |
1990年 | 9篇 |
1989年 | 13篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 8篇 |
1981年 | 3篇 |
1966年 | 3篇 |
1965年 | 8篇 |
1963年 | 3篇 |
1962年 | 4篇 |
1961年 | 3篇 |
1957年 | 6篇 |
1955年 | 1篇 |
排序方式: 共有596条查询结果,搜索用时 218 毫秒
82.
We investigate the third-order optical nonlinearities in four novel porphyrin dimers (dimers A to D) and a monomeric porphyrin H2 CPTPP measured by using the single-beam z-scan technique with a pulsed Q-switched Nd:YAG nanosecond laser at 532nm. All the samples show strong excited state absorption (ESA) and high value of Х^(3) in the ns domain at this wavelength. We perform a comparison between dimer A and its monomer H2 CPTPP in their third-order optical nonlinearity, and discuss the relationships between the values of Х^(3) and the different bridging groups for all the dimers. 相似文献
83.
为建立快速测定感冒药物中2种有效成分对乙酰氨基酚(AAP)和盐酸伪麻黄碱(PEPD)的数学模型,分别采集上述2种化合物的多波长紫外光谱,从而获得两者的标准光谱库(v1和v2)。同时取市售感冒药4种,各取1片,分别配成溶液后,各自采集其光谱-色谱联用数据并转化成各时刻全波长下的吸光度A。从中扣除与被测组分具有相同保留时间的数据阵列,得到不含有被测组分的数据矩阵,然后分别采用主成分分析和奇异值分解降维处理后,得到不含有AAP的本底数据库N1和不含有PEPD的本底数据库N2。分析样品时,取上述4种感冒药各1片,分别配制成溶液后,每一样品取2份,一份采集多波长紫外光谱数据,另一份进行高效液相色谱(HPLC)分析。从而建立样品的光谱库a,并运用向量扣减方法计算得到样品中2种有效成分的含量。AAP测定值的相对标准偏差(n=5)均小于2.0%,PEPD测定值的相对标准偏差(n=5)均小于4.0%;加标回收试验测得回收率分别为94.5%~106%和92.1%~108%。此方法的测定结果与HPLC的测定结果之间的相对误差分别在±4.0%和±3.0%以内。 相似文献
84.
85.
Al2O3/SnO2 co-nanoparticles were prepared with a modified sol-gel technique followed by a thermal treatment process. With these co-nanoparticles the grafted collagen-Al2O3/SnO2 nanocomposites were obtained using a supersonic dispersion method. X-ray diffraction, FT-IR analysis, transmission electron microscopy, TGA/DTA and infrared emissivity test were performed to characterize the resulting nanoparticles and nanocomposites, respectively. The Al2O3/SnO2 co-nanoparticles showed a narrow distribution of size between 20-40 nm and could be uniformly absorbed on the tri-helix scaffolds of the grafted collagen without any aggregation. The nanocomposites possessed better thermal stability and substantially lower infrared emissivity than the grafted collagen and Al2O3/SnO2 co-nanoparticles with an increase of degradation temperature from 39 to 210 ℃ and a decrease of infrared emissivity from 0.850 of the grafted collagen and 0.708 of the Al2O3/SnO2 co-nanoparticles to 0.424, which provided a potential application of the nanocomposites to areas such as photoelectronics. 相似文献
86.
工业CT技术及其NDT应用 总被引:1,自引:0,他引:1
CT(Computed Tomography),即计算机层析成像技术或计算机断层扫描技术,是一种高新技术.它是物理学和计算机科学的发展产物,或者说,它是核物理学与现代图像理论相结合而产生的一门边缘学科.CT技术最引人注目的应用是在医学临床诊断领域,被人们称作医用CT(MCT),用于对人体的病灶作断层扫描,尔后以图像方式分析和确定病状.对此,医用CT已是家喻户晓,成为临床医学诊断不可或缺最为有效的手段.如今,医用CT已发展到了第五代,即超高速动态三维CT.因此,CT技术被公认为是20世纪后期最伟大… 相似文献
87.
本文采用溶胶 凝胶法合成了紫外波段有机染料DMT掺杂SiO2 薄膜和块体材料 薄膜中掺杂浓度高达 1 2 4× 1 0 - 2 mol/L ,块体材料浓度掺至 1 5× 1 0 - 3mol/L 由于SiO2“笼”的束缚作用 ,在荧光光谱中未观察到荧光猝灭现象 ;由于SiO2 “笼”的极化作用 ,370nm的发射峰较其在环己烷中发生了 34~ 44nm左右的红移 ;580~ 590nm的发射峰的量子效率比 370nm的发射峰略高 相似文献
88.
In order to make the numerical calculation of viscous flows more convenient for the flows in channel with complicated profile governing equations expressed in the arbitrary curvilinear coordinates were derived by means of Favre density- weighted averaged method, and a turbulent model with effect of curvature modification was also derived. The numerical calculation of laminar and turbulent flows in divergent curved channels was carried out by means of parabolized computation method. The calculating results were used to analyze and investigate the aerodynamic performance of stator cascades in compressors preliminarily. 相似文献
89.
90.
The detailed analysis of the dynamical process of coin tossing is made. Through calculations, it is illustrated how and why the result is extremely sensitive to the initial conditions. It is also shown that, as the initial height of the mass center of the coin increases, the final configuration, i.e. head or tail, becomes more and more sensitive to the initial parameters (the initial velocity angular velocity, and the initial orientation), the coefficient of the air drag, and the energy absorption factor of the surface on which the coin bounces. If we keep the head upward initially but allow a small range for the change of some other initial parameters, the frequency that the final configuration is head, would be 1 if the initial height h of the mass center is sufficiently small, and would be clo to 1/2 if h is sufficiently large. An interesting question is how this frequency changes continuously from 1 to 1/2 as h increases. Detailed calculations show that such a transition is very similar to the transition from laminar to turbulent flows. A basic difference between the transition stage and the completely random stage is indicated: In the completely random stage, the deterministic process of the individual case is extremely sensitive to the initial conditions and the dynamical parameters, out the statistical properties of the ensemble are insensitive to the small changes of the initial conditions and the dynamical parameters. On the contrary, in the transition stage, both the deterministic process of the individual case and the statistical properties of the ensemble are sensitive to the initial conditions and the dynamical parameters. The mechanism for this feature of the transition stage is the existence of the long-train structure in the parameter space. The illuminations of this analysis on some other random phenomena are discussed. 相似文献