库仑滴定法测定烟叶提取物中茄尼醇

本文提出用库仑滴定法测定茄尼醇。以含有1mol·L－1KBr的78％（V／V）醋酸溶液为介质，以5mA恒电流为电解电流，对布尼醇进行库仑滴定，用双铂电极电流法指示滴定终点，得到满意结果．方法简便、准确，不需要标准溶液，不需要昂贵仪器。     

水溶液中碳纳米管的表面增强拉曼光谱研究

合成了碳纳米管和金纳米颗粒的复合物, 测量了水溶液相中复合物的表面增强拉曼光谱, 结果表明, 碳纳米管的巯基化修饰可以提高碳纳米管与金纳米颗粒复合的效率, 随着金纳米颗粒负载量的增加, 碳纳米管的拉曼信号逐渐增强. 加入己二胺分子可以减小金纳米颗粒之间的距离使表面增强效应更显著, 碳纳米管的拉曼光谱得到进一步的增强. 还可进一步在复合体系中加入对巯基苯胺和罗丹明B等小分子拉曼探针, 利用金纳米颗粒的表面增强效应, 这种多元复合体系有望作为多通道拉曼成像探针材料.     

牛磺酸缩邻香草醛席夫碱铜配合物[Cu(C_(12)H_8N_2)(C_(10)H_(11)NO_5S)]·3.5H_2O的合成及晶体结构

含硫席夫碱及其金属配合物具有抑菌、抗癌和抗病毒的生物活性[1-3],有些含O、N席夫碱金属配合物具有仿酶催化活性[4].而氨基酸席夫碱配合物具有良好的生理活性,近年来得到人们的普遍重视[5,6].2-氨基乙磺酸(牛磺酸)作为生物     

Gaussian solitons in nonlocal media: variational analysis

Exact solutions of Gaussian solitons in nonlinear media with a Gaussian nonlocal response are obtained. Using the variational approach, we obtain the approximate solutions of such solitons when the degree of the nonlocality is arbitrary. Specifically, we study the conditions for Gaussian solitons that propagate in weakly and highly nonlocal media. We also compare the variational result with the known exact solutions for weakly and highly nonlocal media.     

光脉冲编码对基于拉曼放大的布里渊光时域分析系统的影响

报道了光脉冲编码对基于拉曼放大的布里渊光时域分析系统(BOTDA)的影响. 实验表明,光脉冲编码能够在保证较高空间分辨率的同时减小布里渊频移的不确定性. 实验实现了49.6 km传感距离, 在整段传感光纤上温度分辨率1 ℃,空间分辨率2.5 m. 本文实验测量并分析了系统的信噪比和光功率分布特性. 关键词： 分布式光纤传感 受激拉曼散射 布里渊增益 布里渊光时域分析系统(BOTDA)     

(Mg,Cr)共掺LaFeO3基复合粉体的能带结构及其热辐射性能

采用高温固相烧结法在1 300℃反应2 h成功制备出钙钛矿型LaFe_(0.75)Cr_(0.25)O_3和La_(0.75)Mg_(0.25)Fe_(0.75)-Cr_(0.25)O_3粉体材料。通过XRD、FT-IR、SEM、XPS和Upward IntegratIRTM等对材料的物相结构和近中红外波段的发射性能进行分析表征,并应用第一性原理计算分析了其电子结构,研究影响发射率的理论机制。研究表明,粉体在1～5μm波段的发射率都出现上升,但Cr单掺试样的吸收率增幅不大,而Mg-Cr共掺粉体增幅较大,在近红外波区的吸收率在0.9以上。究其原因在于,Cr单掺后晶体发生畸变,但不增加自由载流子的浓度,Mg-Cr共掺后畸变加剧且生成较多氧空位和小极化子,强化了自由载流子的吸收。Cr 3d轨道与O 2p所形成的杂化能级和在近费米能级导带区的Cr 3d轨道造成了粉体禁带宽度变窄,Mg虽然未直接作用于带隙值,但间接改变了B位元素的形态,产生了更多的小极化子,因此与LaFeO_3禁带宽度值(3.817 eV)相比,Mg-Cr共掺(0.109 eV)减小幅度最大,Cr单掺(2.406 eV)次之。     

Effects of WC-Co reinforced Ni-based alloy by laser melting deposition: Wear resistance and corrosion resistance

WC-Co reinforced C276 alloy composite coatings are fabricated on Q235 steel by laser melting deposition.The microstructure,hardness,wear performance,and electrochemical corrosion behavior of composite coating are studied.The results show that WC-Co particles are mostly uniformly distributed in the coating and provide favorable conditions for heterogeneous nucleation.The microstructure of C276/WC-Co composite coatings is composed of γ-Ni solid solution dendrites and MoNi solid solution eutectics.The WC-Co particles can effectively improve the hardness and wear resistance of C276 alloy.The average hardness of the composite coating containing 10-wt% WC-Co(447 HV_0.2) are 1.26 times higher than that of the C276 alloy(356 HV_0.2).The wear rate of composite coating containing 10-wt% WC-Co(6.95 ×10^-3 mg/m) is just 3.5% of that of C276 coating(196.23 × 10^-3 mg/m).However,comparing with Hastelloy C276,the corrosion resistance of C276/WC-Co composite coating decreases.     

DDAB修饰纳米氧化锌的合成及XANES研究

用改进的反胶束法合成了半导体纳米级氧化锌,表面由DDAB(双十二烷基二甲基溴化铵)修饰.改进的方法与传统方法的区别是反胶束法中所需要的水是由含水的锌盐直接提供,在有机溶剂中直接形成了微反应池.TEM(透射电子显微镜)照片证实了氧化锌的尺寸为纳米级,其粒径可由锌盐和DDAB的使用量之比来控制.并用基于北京同步辐射的X射线吸收近边结构谱来研究纳米材料的表面结构重组和畸变性质等.     

关于f~((k))-af~n的零点

设 f (z) 为平面内超越亚纯函数 ,a≠ 0 为常数 ,证明了当 n≥ k+3 时 ,f( k) -afn有无穷多个零点 .     

Luminescent Characteristics of Near Ultraviolet InGaN/GaN MQWs Grown on Grooved Sapphire Substrates Fabricated by Wet Chemical Etching

InGaN/GaN multiple quantum wells （MQWs） are grown on planar and maskless periodically grooved sapphires by metal organic vapour phase epitaxy （MOCVD）. High-resolution x-ray rocking curves and transmission electron microscopy （TEM） are adopted to characterize the film quality. Compared with the MQWs grown on planar sapphire, the sample grown on grooved sapphire shows better crystalline quality： a remarkable reduction of dislocation densities is achieved. Meanwhile, the MQWs grown on grooved sapphire show two times larger PL intensity at room temperature. Temperature-dependent PL measurements are adopted to investigate the luminescence properties. The luminescence thermal quenching based on a fit to the Arrhenius plot of the normalized integrated PL intensity over the measured temperature range suggests that the nonradiative recombination centres （NRCs） are greatly reduced for the sample grown on grooved sapphire. We assume that the reduction of dislocations which act as NRCs is the main reason for the sample grown on pattern sapphire having higher PL intensity.