Gradient and weather resistant hybrid super‐hydrophobic coating based on fluorinated epoxy resin

A weather resistant super‐hydrophobic coating that can offer good substrate adhesion and yet to be easily processed at large scale can be of practical use in emerging fields of self‐cleaning and anti‐icing paint, combing all these properties together remains challenging task. Here we describe a composite coating composed of a fluorinated epoxy resin emulsion with embedded in situ surface‐modified dual‐scale nano‐silica, which displayed durable super‐hydrophobicity and excellent adhesive strength. The as‐prepared coating possesses water contact angle of 158.6 ± 1°, sliding angle around 3.8 ± 0.2° which remain stable even under acidic/alkaline, heat/cool, and accelerated aging treatment. The results demonstrate that surface roughness had a micron‐ and nanometer scale distribution with increased particle loading beyond 40 wt %. Through quantitative comparison of surface Attenuated Total Reflection (ATR) with bulk FT‐IR transmission spectra, a gradient coating with surface enrichment of hydrophobic groups was determined. The air‐side fluorinated polysiloxane‐rich layer endows coating with weather‐resistance and ultra‐hydrophobicity while bottom epoxy resin layer enhances substrate adhesion. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40955.     

Pullulan‐based films and coatings for food packaging: Present applications,emerging opportunities,and future challenges

Societal and industrial demands for lower environmental impact, cost effectiveness, and high‐performance goods and services are increasingly impacting the choice of technologies which are developed and deployed in consumer products. Like many other sectors, food packaging is moving to new technologies; the use of biopolymers is one of the most promising strategies toward an optimized use of traditional packaging materials (e.g., oil‐based plastics) without impairing the goal of extending shelf life. Among other food packaging materials, pullulan is attracting much attention due to its unique features. The goal of this review is to provide an overview of current and emerging applications of pullulan within the food packaging sector. In particular, the functional properties of interest for the food packaging industry will be discussed in light of the physicochemical attributes of this exopolysaccharide. Future challenges that may dictate the successful penetration of pullulan in the food packaging market are also outlined. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40539.     

变压吸附制氮性能主要影响参数的研究

介绍了变压吸附制氮技术的优点、原理方法及工艺流程,实验研究了吸附压力、吸附解吸时间、产品流量等主要工艺参数对变压吸附制氮装置性能的影响,最后得出实验装置的最佳工艺条件为:吸附压力0.8 MPa,吸附解吸时间54 s,均压时间4 s,产品气出气流量7 m3/h。此时,实验装置制得的产品氮气体积分数最稳定,平均体积分数98%以上,回收率在40%左右。     

不同形式补强圈对吊装强度影响

针对大型萃取精馏塔,利用有限元方法分析了3种形式的补强圈对其吊装强度的影响,为大型塔设备吊装提供合理方案。     

核-壳型脂质体基因载体的研究进展

脂质体作为一种重要的非病毒基因载体,在核酸和药物转运方面有着巨大的优势和潜力。近年来脂质体基因载体的研究基础上,主要介绍了脂质体-聚阳离子-DNA复合载体(LPD)和脂质体-磷酸钙纳米粒子复合载体(LCP)两种核-壳型脂质体基因载体,展望了核-壳型脂质体基因载体的发展方向及其在基因治疗领域的应用前景。     

GLP与矿用材料实验室建设和管理

介绍了GLP(Good Laboratory practice)和SOP(Standard Operating Procedures)的发展过程与实际意义,并将SOP作为管理理念引入材料实验室建设与管理。探讨了材料实验室SOP建设的意义、特点、范围和内容。指出SOP建设与实施可以保障实验室安全、高效运行,保证研究工作质量和研究资料可比性、完整性与准确性。     

脱水污泥吸附去除废水中钼污染物的研究

运用脱水污泥研究了吸附去除含钼废水中钼染污物。研究结果表明：pH 3~4,吸附时间为3 0 min,投加量为1 g,温度为30℃时为最佳吸附条件,去除率可达88.5%以上。吸附机理研究结论表明,吸附机制为表面络合反应。     

用于氮氧化物处理的填料塔的设计

选用填料塔对草酸生产过程中产生的氮氧化物进行吸收处理。对填料塔本体进行了设计计算,结合已有的工程设计经验给出了确定填料塔本体尺寸的具体步骤,并讨论了设计应考虑的主要问题。所采用的工艺有效地降低了生产过程中氮氧化物的排放,降低了生产成本,减少了环境污染。     

“高聚物加工工程”重点课程的建设与实践

高聚物加工工程是高分子材料与工程专业的核心课程,是将高分子材料变成实用制品的关键环节,也是东北林业大学重点建设课程之一。通过重点课程的建设,提升课程的教学质量,为创新型人才培养奠定课程基础。针对高聚物加工工程建设,从教学理念、教师队伍建设、教学内容整合与优化、课堂教学与实践教学相结合的角度对课程建设的探索与实践进行了总结。     

电感耦合发射光谱测煤灰中的元素

本文用三标准试样法来做校正曲线,用电感耦合离子发射光谱来测煤灰中Si、Al、Fe、Ca、Mg、Ti、S、P,这种方法方便快捷,准确度高,能同时测多种元素,每种元素的线性相关系数都大于0.999。