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41.
High‐resolution 3D‐printed stainless steel metal microreactors (3D‐PMRs) with different cross‐sectional geometry are fabricated to control ultrafast intramolecular rearrangement reactions in a comparative manner. The 3D‐PMR with circular channel demonstrates the improved controllability in rapid Fries‐type rearrangement reactions, because of the superior mixing efficiency to rectangular cross‐section channels (250 µm × 125 µm) which is confirmed based on the computational flow dynamics simulation. Even in case of very rapid intramolecular rearrangement of sterically small acetyl group occurring in 333 µs of reaction time, the desired intermolecular reaction can outpace to the undesired intramolecular rearrangement using 3D‐PMR to result in high conversion and yield.  相似文献   
42.
The demand for defect diagnoses is gradually gaining ground owing to the growing necessity to implement safe inspection methods to ensure the durability and quality of structures. However, conventional manpower-based inspection methods not only incur considerable cost and time, but also cause frequent disputes regarding defects owing to poor inspections. Therefore, the demand for an effective and efficient defect-diagnosis model for concrete structures is imminent, as the reduction in maintenance costs is significant from a long-term perspective. Thus, this paper proposes a deep learning-based image object-identification method to detect the defects of paint peeling, leakage peeling, and leakage traces that mostly occur in underground parking lots made of concrete structures. The deep learning-based object-detection method can replace conventional visual inspection methods. A faster region-based convolutional neural network (R-CNN) model was used with a training dataset of 6,281 images that utilized a region proposal network to objectively localize the regions of interest and detect the surface defects. The defects were classified according to their type, and the learning of each exclusive model was ensured through test sets obtained from real underground parking lots. As a result, average precision scores of 37.76%, 36.42%, and 61.29% were obtained for paint peeling, leakage peeling, and leakage trace defects, respectively. Thus, this study verified the performance of the faster RCNN-based defect-detection algorithm along with its applicability to underground parking lots.  相似文献   
43.
Measurements of non-methane hydrocarbons (NMHC) were performed at the entrance and exit of the Sangdo tunnel to estimate emission factors (EF) of NMHC from vehicles in May 2000. About 50 species were analyzed by a combined GC/FID and GC/MS system. Ethylene was the most abundant compound, followed by n-butane and acetylene, respectively. Based on the measurement data, the real world vehicular EF in Seoul was estimated. The highest EF value was 89.8 mg (veh-mile)-1 for n-butane, followed by ethylene and toluene.  相似文献   
44.
The present study is concerned with γ-(Ti52Al48)100−x B x (x=0, 0.5, 2, 5) alloys produced by mechanical milling/vacuum hot pressing (VHPing) using melt-extracted powders. Microstructure of the as-vacuum hot pressed (VHPed) alloys exhibits a duplex equiaxed microstructure of α2 and γ with a mean grain size of 200 nm. Besides α2 and γ phases, binary and 0.5 pct B alloys contain Ti2AlN and Al2O3 phases located along the grain boundaries and show appreciable coarsening in grain and dispersoid sizes during annealing treatment at 1300 °C for 5 hours. On the other hand, 2 pct B and 5 pct B alloys contain fine boride particles within the γ grains and show minimal coarsening during annealing. Room-temperature compressing tests of the as-VHPed alloys show low ductility, but very high yield strength >2100 MPa. After annealing treatment, mechanically milled alloys show much higher yield strength than conventional powder metallurgy and ingot metallurgy processed alloys, with equivalent ductility to ingot metallurgy processed alloys. The 5 pct B alloy with the smallest grain size shows higher yield strength than binary alloy up to the test temperature of 700 °C. At 850 °C, 5 pct B alloy shows much lower strength than the binary alloy, indicating that the deformation of fine 5 pct B alloy is dominated by the grain boundary sliding mechanism. This article is based on a presentation made in the symposium “Mechanical Behavior of Bulk Nanocrystalline Solids,” presented at the 1997 Fall TMS Meeting and Materials Week, September 14–18, 1997, in Indianapolis, Indiana, under the auspices of the Mechanical Metallurgy (SMD), Powder Materials (MDMD), and Chemistry and Physics of Materials (EMPMD/SMD) Committees.  相似文献   
45.
In this paper, a new analytical method for solving stable crack propagation problems in a ductile panel with a row of cracks, is presented. The main purpose of the present study is to estimate the maximum load carrying capacity of such panels accurately. The so called Elastic Plastic Finite Element Alternating Method (Pyo et al. (1994) was extended to account for the propagating cracks. The crack propagation algorithm utilizes the analytic crack solution to release the stresses ahead the crack tip. The T inf sup* integral is employed as the crack extension criterion. This integral parameter accounts for the near tip stress-strain singularity and its critical values for crack propagation can be extracted from the P-a curve of single cracked specimen case. The present method can be applied to the problems of the fuselage skin of aging airplanes, in which a row of cracks develop (MSD; Multiple Site Damage) from rivet holes. The load carrying capacity of such damaged structure reduces by a considerable amount. In order to predict the behavior near the critical load, one must account for plastic deformation, if the material is ductile. Furthermore, the maximum load carried by the structure is often reached after some amount of crack propagation. In this paper, a series of analyses have been conducted and their results compare with the available experimental data.  相似文献   
46.
This paper describes some simplified stable crack growth analyses of two kinds of inhomogeneous CT specimens. The one is machined from a submerged are welded plate of a nuclear pressure vessel A533B Class 1 steel, while the other is machined from an electron-beam welded plate of the A533B Class 1 steel and a high strength HT80 steel. In both specimens, initial cracks are placed to be normal to the fusion line. The ratio of yield stresses of the weld metal and the base metal of the A533B Class 1 steel is about 1·15, while that of the HT80 and the A533B Class 1 steels is about 1·4.

The generation phase crack growth analyses using the GE/EPRI and the reference stress methods are performed, calculating an applied load (P) and the J-value, while the application phase analyses of analyses using the R6 method are performed to calculate the maximum value of the applied load (Pmax). Finally, some modification procedures of the three simplified estimation schemes are discussed in order to apply them to inhomogeneous material regimes.  相似文献   

47.
Crystalline water-free β-phase Ca0.14V2O5 is reported for the first time as a viable cathode material for calcium-ion batteries (CIBs). In contrast to layered α-V2O5 and δ-CaxV2O5·nH2O, which have limited capacity, the β-phase delivers a reversible capacity of ≈247 mAh g−1, which corresponds to the insertion/extraction of Ca2+ between Ca0.14V2O5 and Ca1.0V2O5. The process of Ca2+ insertion process and the accompanying structural relaxation are theoretically and experimentally verified. The initial insertion of Ca2+ into Ca0.14V2O5 causes a slight shift of oxygen atoms surrounding hepta-coordination sites, creating penta-coordinated sites that are then partially filled up to Ca0.33V2O5. Further insertion occurs through the stepwise occupation of up to 50% of neighboring hexa- and tetra-coordination sites to form Ca0.67V2O5 and Ca1.0V2O5, respectively. The rearrangement of oxygen atoms in Ca0.14V2O5 also minimizes dimensional changes, leading to high cyclic stability during repeated charge/discharge cycles. The remarkable electrochemical performance of full cells containing a Ca0.14V2O5 cathode and a K metal anode in Ca2+/K+ hybrid electrolytes, is also demonstrated, thanks to the inertness of K+ insertion into Ca0.14V2O5 and the absence of calcium plating/stripping. The cyclic stability and high capacity of Ca0.14V2O5 is not compromised in hybrid electrolytes, making it a viable CIB cathode.  相似文献   
48.
Although there have been remarkable improvements in stretchable strain sensors, the development of strain sensors with scalable fabrication techniques and which both high sensitivity and stretchability simultaneously is still challenging. In this work, a stretchable strain sensor based on overlapped carbon nanotube (CNT) bundles coupled with a silicone elastomer is presented. The strain sensor with overlapped CNTs is prepared by synthesizing line‐patterned vertically aligned CNT bundles and rolling and transferring them to the silicone elastomer. With the sliding and disconnection of the overlapped CNTs, the strain sensor performs excellently with a broad sensing range (≥145% strain), ultrahigh sensitivity (gauge factor of 42 300 at a strain of 125–145%), high repeatability, and durability. The performance of the sensor is also tunable by controlling the overlapped area of CNT bundles. Detailed mechanisms of the sensor and its applications in human motion detection are also further investigated. With the novel structure and mechanism, the sensor can detect a wide range of strains with high sensitivity, demonstrating the potential for numerous applications including wearable healthcare devices.  相似文献   
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