Rheological Characterization of Nitrocellulose Gels

Various nitrocellulose, NC, based propellant formulations need to be processed using new and more environmentally friendly solvent combinations on the one hand and using continuous processing methodologies on the other hand. A detailed understanding of the significant changes that take place in the structure and hence the rheological behavior of NC based formulations during manufacture is required to minimize the use of organic solvents and to revert to safer and green solvents. Towards achieving these objectives, experimental methodologies were developed for the first time to enable the accurate characterization and thus fingerprinting of the rheological behavior of NC gels. In these methodologies linear viscoelastic measurements are employed. The concentration of the solvents existing in the gel sample during rheological characterization is concomitantly monitored to allow the documentation of the major source of error associated with the rapid loss of the typical solvents, which generally exhibit relatively high vapor pressures. These measurements have indicated that the source of the NC fibers and the treatment method alter the rheological behavior and can be tracked. The rheological properties of the NC gels can be linked to their manufacturability and such data can be used to pinpoint optimum geometries and processing conditions. The processability of the NC based formulations can also be tailored on the basis of rheological characterization, allowing the manufacturers greater latitude for reducing costs and environmental footprint during manufacture, as well as improving the quality of their NC based energetic formulations.     

Effects of structural parameters on compressibility and soiling properties of machine woven carpets

Compressibility performance of the machine woven carpet after a static or dynamic loading expresses the texture deformation tendency of the carpet. This study is an experimental attempt to investigate the effects of pile height and pile density on compressibility and soiling property by dynamic loading, prolonged heavy static loading, compression recovery and artificial soiling tests. In this study, a total of 12 carpet samples with three different pile heights and four different pile densities were tested. As a result of this study, it was seen that higher pile density provides a lower thickness loss and so a lower level of texture deformation. On the other hand, pile height has a preventing effect for texture deformation for static loading and compression recovery tests whereas there is no considerable effect on dynamic loading test. There is no considerable difference between the soiling properties of the samples.     

Modified current follower-based immittance function simulators

In this paper, four immittance function simulators consisting of a single modified current follower with single Z? terminal and a minimum number of passive components are proposed. The first proposed circuit can provide +L parallel with +R and the second proposed one can realise ?L parallel with ?R. The third proposed structure can provide +L series with +R and the fourth proposed one can realise ?L series with ?R. However, all the proposed immittance function simulators need a single resistive matching constraint. Parasitic impedance effects on all the proposed immittance function simulators are investigated. A second-order current-mode (CM) high-pass filter derived from the first proposed immittance function simulator is given as an application example. Also, a second-order CM low-pass filter derived from the third proposed immittance function simulator is given as an application example. A number of simulation results based on SPICE programme and an experimental test result are given to verify the theory.     

Control of buoyancy-induced temperature and flow fields with an embedded adiabatic thin plate in porous triangular cavities

Natural convection has been performed in an insulated horizontally thin plate embedded in a triangular enclosure filled with fluid saturated porous medium, numerically. Bottom and inclined wall of triangular enclosure are isothermally heated and cooled, respectively. Vertical wall of enclosure is adiabatic. Steady, two-dimensional, laminar governing equations, which are written with Darcy model, were solved with finite-difference method. Calculations are conducted for different lengths and locations of thin plate, different aspect ratios, and Darcy-modified Rayleigh number. Prandtl number was chosen as 0.71. It is observed that the change on plate location in vertical and horizontal axes makes small effect on heat transfer; however flow field and temperature distribution strongly affected from these parameters.     

Natural convection in a vertically divided square enclosure by a solid partition into air and water regions

Numerical analyses of the flow and heat transfer due to buoyancy forces in a square enclosure divided by an impermeable partition between air and water filled chests were carried out using a finite difference technique. The enclosure was heated from left wall and cooled from right, isothermally. Horizontal walls were adiabatic. The partition divided the enclosure into air and water regions. Thus, two cases were examined: left side of partition was filled with air and right side was filled with water (Case I, air-partition-water) and left side was filled with water and right side with air (Case II, water-partition-air). Epoxy was chosen as partition material. Results were obtained for different Grashof numbers (10³  Gr  10⁶), thickness of the partition (0.05  ε  0.2) and location of the partition (0.25  c  0.75). An analytical treatment has been performed for low Grashof numbers. Numerical and analytical results gave an acceptable agreement. It was found that filling of fluid into chests is important for obtaining maximum heat transfer and energy saving. When left chest was filled with air (Case I), higher heat transfer was formed. It was an interesting result that heat transfer decreased with increasing of location of the partition for all values of partition thickness at Case I. On the contrary, heat transfer was a decreasing function of increasing value of location of the partition.     

Visualization of natural convection heat transport using heatline method in porous non-isothermally heated triangular cavity

Natural convection heat transfer in a porous media filled and non-isothermally heated from the bottom wall of triangular enclosure is analyzed using finite difference technique. Darcy law was used to write equations of porous media. Dimensionless heatfunction was used to visualize the heat transport due to buoyancy forces. Three different boundary conditions were applied for the vertical and inclined boundaries of triangular enclosures as Case I; both vertical and inclined walls were isothermal, Case II; vertical wall was adiabatic and inclined one was isothermal, Case III; vertical wall is isothermal and inclined one is adiabatic. A cosine function was utilized to get non-isothermal wall condition. The study was performed for different aspect ratios (0.25 ? AR ? 1.0) and Darcy-modified Rayleigh numbers (100 ? Ra ? 1000). It was observed that heat transfer enhancement was formed when vertical and inclined walls were isothermal while bottom wall was at non-uniform temperature. Heat transfer from bottom wall did not vary when the value of aspect ratio was higher than 0.50. In addition, heatline visualization technique was a useful technique for non-isothermally heated and porous media filled triangular enclosures.     

Natural convection flow in porous enclosures with heating and cooling on adjacent walls and divided by a triangular massive partition

The problem of steady, laminar, natural convection flow in a porous enclosure divided by a triangular massive partition has been formulated. The massive triangular partition is a solid adiabatic body which is located to the right and top wall. Bottom and left vertical wall of porous enclosure are isothermally heated and cooled, respectively. Remaining wall is adiabatic. Governing equations using Darcy model are solved numerically by the finite-difference method and the Successive Under Relaxation (SUR) technique is used to solve linear algebraic equations. Thanks to massive partition, two different enclosure are formed, depends on dimensions of the triangular body, as triangle and trapezoidal. Flow patterns and temperature distributions were presented at different aspect ratios (0 ≤ AR ≤ 1) and Rayleigh numbers (100 ≤ Ra ≤ 1000). Results are given for different aspect ratios (AR) for AR = 0, 0.25, 0.50, 0.75 and 1. A parametric study is conducted and a set of representative results for flow and temperature characteristics are presented and discussed.     

Pyrolysis of giant mullein (Verbascum thapsus L.) in a fixed-bed reactor: Effects of pyrolysis parameters on product yields and character

Slow pyrolysis of giant mullein (Verbascum thapsus L.) stalks have been carried out in a fixed-bed tubular reactor with (Al₂O₃, ZnO) and without catalyst at four different temperatures between 400 to 550°C with a constant heating rate of 50°C/min and with a constant sweeping gas (N₂) flow rate of 100 cm³/min. The amounts of bio-char, bio-oil, and gas produced were calculated and the compositions of the obtained bio-oils were determined by gas chromatography-mass spectrometry. The effects of pyrolysis parameters, such as temperature and catalyst, on the product yields were investigated. The results show that both temperature and catalyst have significant effects on the conversion of Verbascum thapsus L. into solid, liquid, and gaseous products. The highest liquid yield of 40.43% by weight including the aqeous phase was obtained with 10% zinc oxide catalyst at 500°C temperature. Sixty-seven different products were identified by gas chromatography-mass spectrometry in the bio-oils obtained at 500°C temperature.     

Synthesis of block copolymers by using polysilanes

Poly(methyl phenyl silane) was used to photoinitiate the polymerization of methyl methacrylate. Poly(methyl methacrylate) (PMMA), obtained this way, contains remaining polysilane chains. Photolysis of this PMMA in the presence of vinyl monomers such as styrene makes it possible to prepare block copolymers. Such PMMA prepolymers were also used to induce the polymerization of cyclohexene oxide through formation of PMMA-attached silyl radicals and subsequent oxidation to the corresponding ions in the presence of N-ethoxy-2-methylpyridinium hexafluorophosphate resulting in the formation of a block copolymer.