The kinetics and mechanism of absorption/desorption of nitrogen in liquid Nb were investigated in the temperature range of
2470 °C to 2670 °C in samples levitated in a N2/Ar stream with various nitrogen partial pressures. The nitrogen solution reaction in liquid Nb was found to be exothermic,
with the standard enthalpy and entropy of solution of −236.4 ± 23.3 kJ/mol and −-5.3 ± 8.3 J/K · mol, respectively. Above
the threshold flow rate of the N2/Ar stream, the absorption process was determined to be second order with respect to nitrogen concentration, indicating that
the rate-controlling step is either the adsorption of nitrogen molecules on the liquid surface or dissociation of adsorbed
nitrogen molecules into surface-adsorbed atoms. The desorption process was found to be second order as well. At lower flow
rates, however, the absorption rate was found to depend on the gas-phase mass transfer rate. The rate equation for nitrogen
absorption in the range of 2470 °C to 2670 °C is given by
with the value ofQ calculated to be −327.2 ± 20.6 kJ/mol, while nitrogen desorption at 2670 °C follows the relation
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