Hot isostatic pressed pyrochlore glass-ceramics: Revealing structure insides at the reaction interface

As potential waste forms for immobilizing actinide-rich radioactive wastes, Eu₂Ti₂O₇ (Eu as a surrogate for minor actinides) pyrochlore glass-ceramics were fabricated via hot isostatic pressing (HIPing) at 1200°C. The structure and microstructure at the reaction interface between the glass-ceramic waste form and the stainless steel (SS) canister under HIPing conditions were carefully investigated with scanning electron microscopy (SEM), transmission electron microscopy (TEM), and synchrotron single crystal X-ray diffraction (SC-XRD). The interactions at the reaction interface led to the formations of a ~10-µm-thick Cr₂O₃ layer as the oxidation front of the SS and a layer of a mixed oxide phase (Eu_1.25SiCr_0.8Ti_1.2O_7.5) on the glass-ceramic side of the reaction interface. The crystal structure of such a unique mixed oxide phase was revealed indubitably with a combination of synchrotron SC-XRD and TEM assisted with a focused ion beam (FIB) SEM system. The improved structural understanding of the reaction interface will help to support the utilization of HIPing as a versatile hot consolidation process for the treatment of radioactive wastes.     

Simple approach for the plasma treatment of polymeric membranes and investigation of the aging effect

The modification of the surface characteristics after treatment with plasma in polymeric materials, such as the aging phenomenon, calls the attention of research in the area of nonthermal plasma technology. In this work, a direct treatment with dielectric-barrier discharge plasma was used on the surfaces of ultrafiltration membranes. The measurements of the contact angle with water, attenuated total reflectance accessory, zeta potential, atomic force microscopy and scanning electron microscopy-MEV were performed on the surfaces to verify changes after plasma treatment and to understand the occurrence and timing of the plasma aging effect. In the analysis of the membrane performance, hydraulic permeation and protein retention tests were performed. The results showed an improvement in wettability and hydrophilic properties in the post-treated membranes. The study of reversibility/aging of the post-plasma surface is important for research that deals with the modification of polymeric membranes. Changes in surface morphology, topography and wettability of the membranes were observed up to seven days after treatment, with a tendency to return to the initial characteristics of the membranes.     

Upcycling by grafting onto semi-crystalline polymers using supercritical CO2

The creation of graft copolymers by selectively grafting a second polymer to the amorphous fraction of a semi-crystalline polymer in supercritical CO₂ is demonstrated herein. The graft copolymer is synthesized by free radical polymerization of a vinyl monomer within the semi-crystalline polymer below its melt temperature. Such conditions afford selective grafting on the amorphous regions (block “B”) while leaving the crystalline domains (block “A”) unmodified. Accordingly, unique A-B, A-B-A, A-B-A-B-A, and so forth. block structures are formed. In this work, styrene is polymerized within polyamide 6, polyethylene terephthalate, and isotactic polypropylene. Purification of these material is performed to remove the un-grafted homopolymer, allowing for determination of the graft yield, the portion of polymer which covalently bonds to the semi-crystalline matrix. Grafting yields achieved in polyamide 6, polyethylene terephthalate, and isotactic polypropylene were 98%, 59%, and 15%, respectively. Property enhancements were observed upon further characterization of polystyrene-polyamide 6 copolymers, including high glass transition temperatures, the ability to be remelted, and tunable grafting molecular weight. Additionally, hydrophobicity is controlled by varying polystyrene composition. The remarkable range of accessed properties demonstrates this as a potential route to upcycling plastics.     

ZnO／Ag纳米复合材料光催化性能研究

通过XRD、TEM测试研究了自制ZnO／Ag纳米复合材料的结构和形貌，通过UV检测确定了以该纳米复合材料为光催化剂，在不同条件下对甲基橙的光催化降解率。结果表明：与空气煅烧相比，真空煅烧所得纳米复合材料的光催化降解效果更好，且光催化降解率随纳米复合材料用量增加而增大：甲基橙溶液的pH在5左右时，光催化降解率最高：H2O2浓度为0．9g／L时，光催化降解率可达100％。     

Impact of transient chemistry on the corrosion potential of a steam turbine disc steel

The adoption of two-shifting in coal-fired power generation (switching from on-load to off-load conditions on a daily basis and off-load for the weekend) results in regular cycling of the solution chemistry of the condensed steam on the turbine discs. A first stage investigation has been made of the effect of such chemistry cycling on the corrosion potential of the disc steel. The corrosion potential is typically about +0.05 V (SCE) in off-load chemistry (aerated pure water) and below −0.6 V (SCE) in on-load chemistry (deaerated solution containing chloride or chloride and sulphate anions). The critical observation was the sluggish response of the corrosion potential upon restoration of deaerated on-load conditions with the implication of a likely increase in pit and stress corrosion crack development.     

工艺参数对合成ZnO／Ag纳米复合抗菌剂产率的影响

通过正交实验，研究了反应温度、反应时间、反应物配比对ZnO／Ag纳米复合抗菌剂合成产率的影响规律。获得了高产率合成ZnO／Ag纳米复合抗菌剂的优选工艺条件：反应温度为10～25℃，ZnSO4与NH4HCO3的摩尔比为1：2-2．5，ZnSO4与NH4HCO3的反应时间为2．5～3h，AgNO3与NH4HCO3的摩尔比为1：1．5～2，反应时间为0．5h，ZnO／Ag的产率超过98％。XRD、TEM和SAED结果表明：ZnO／Ag纳米复合抗菌剂为具有纤锌矿结构的ZnO和立方结构的Ag组成。粒径为15～25nm，分散性较好。     

It's the Thought that Counts: The Mediating Effects of Information Processing in Virtual Team Decision Making

Abstract

Previous research shows that although collaboration technology can improve the exchange of information during team decision making, one of the challenges is that this better discussion often does not lead to better decisions. In this paper, we investigate the impact of individual information processing on team decision making. We investigated the effects of two types of collaboration technology when participants were either the member of a team majority or a team minority. There was little impact due to the majority/minority, but the use of collaboration technology that required users to categorize the comments they received from others resulted in increased information processing, which in turn led to better decisions and more satisfied participants.