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81.
Walter Gsele Wolfgang Egel-Hess Klaus Wintermantel Friedrich Richard Faulhaber Alfons Mersmann 《化学,工程师,技术》1990,62(7):544-552
Formation of solids by crystallization and precipitation. Formation of solids from solutions can take place by crystallization or precipitation. The principal factor is the relationship between solubility and supersaturation. In crystallization, the solubility of the crystallising substance is so high that the formation of solids occurs largely in the metastable zone in the immediate vicinity of the solubility limits. Crystal growth and nucleation are functions of supersaturation. If a high supersaturation is required at low substance-specific growth rates for an adequate crystal growth, high nucleation rates and hence small crystals will result. On this basis, the authors present information for the specific design of crystallization processes. In contrast, the solubility of the precipitated product must be very low for precipitation. Direct crystal formation is possible only for substance systems of high solubility. As a rule, however, the precipitated substance is so insoluble that solids are formed via amorphous intermediates. The results of a large number of experiments show the influence of various parameters of the precipitation process on the filtrability of the precipitated product. 相似文献
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86.
The contribution to energy supply of oil recovered by distillation of oil shale and tar sands . Following a world-wide survey of the most important deposits of oil shale and tar sands, the current activities in the USSR, China and Canada in the field of the industrial recovery of shale oil and bitumen from tar sand are described in broad terms. Thereafter, the current large-scale projects for the production of synthesis oil from these feedstocks are dealt with. The operating method and development status of modern processes for distilling oil shale are covered, as is the working principle of the hot water extraction of tar sand which is already commercially in application. The LR-Process method of operation and its especial feature of circulating the distilled residue as solid heat carrier are discussed in more detail. This is followed by information on the throughput potential of this process. The characteristic reactions influencing the quality of the LR products (oil, gas, residue, flue gas) are handled. Typical quality data for oil and gas obtained from oil shale and tar sands are given. A route is indicated for further processing of the condensate streams from the Lurgi-Ruhrgas Process. This consists of precipitation of solids, distillative separations and one hydrogenation step for the naphtha and oil fraction. These process steps produce a ?syncrude”? which can be further processed together with crude oil in conventional refineries. Examples are given for the independent further processing of syncrude to end-products customary on the market. 相似文献
87.
Fölling J Polyakova S Belov V van Blaaderen A Bossi ML Hell SW 《Small (Weinheim an der Bergstrasse, Germany)》2008,4(1):134-142
We have designed and synthesized a new functional (amino reactive) highly efficient fluorescent molecular switch (FMS) with a photochromic diarylethene and a rhodamine fluorescent dye. The reactive group in this FMS -N-hydroxysuccinimide ester- allows selective labeling of amino containing molecules or other materials. In ethanolic solutions, the compound displays a large fluorescent quantum yield of 52 % and a large fluorescence modulation ratio (94 %) between two states that may be interconverted with red and near-UV light. Silica nanoparticles incorporating the new FMS were prepared and characterized, and their spectroscopic and switching properties were also studied. The dye retained its properties after the incorporation into the silica, thereby allowing light-induced reversible high modulation of the fluorescence signal of a single particle for up to 60 cycles, before undergoing irreversible photobleaching. Some applications of these particles in fluorescence microscopy are also demonstrated. In particular, subdiffraction images of nanoparticles were obtained, in the focal plane of a confocal microscope. 相似文献
88.
During low cycle fatigue tests on TRIP700 for a current research project some anomalies were noticed. In comparison to previous fatigue life tests on nominally identical material, substantially different material characteristics were measured. The cyclic strength of the current lot of material has substantially increased. It is investigated where the differences come from and whether an influence from forming can cause such changes of the cyclic behaviour. 相似文献
89.
Gian Luca Chiarello Davide Ferri Jan-Dierk Grunwaldt Lucio Forni Alfons Baiker 《Journal of Catalysis》2007,252(2):137-147
A 0.5 wt% Pd/LaCoO3, prepared by flame-spray pyrolysis (FP), was tested as catalyst for the low-temperature selective reduction of NO by H2 in the presence of excess O2. In particular, the effect of the precalcination and prereduction temperature on catalytic activity was compared with that of a similar Pd/LaCoO3 sample prepared by impregnation with a Pd solution of FP-prepared LaCoO3. The FP-made catalyst allowed full NO conversion at 150 °C, with 78% selectivity to N2, thus outperforming the catalytic behavior of the corresponding sample prepared by impregnation. The higher activity of the FP-made catalyst has been attributed to the formation of segregated Co metal particles, not present in the impregnated sample, formed during the precalcination at 800 °C, followed by reduction at 300 °C. Two reaction mechanisms can be deduced from the temperature-programmed experiments. The first of these, occurring at lower temperatures, indicates cooperation between the Pd and Co metal particles, with formation of active nitrates on cobalt, successively reduced by hydrogen spillover from Pd. The second, occurring at higher temperature, allows 50% conversion of NO, with >90% selectivity to N2, and involves N adatoms formed by dissociative NO adsorption over Pd. Prereduction at 600 °C led to a slight increase in catalytic activity, due to the formation of a PdCo alloy, which is more stable on reoxidization compared with Pd alone. Moreover, the cooperative reaction mechanism seems to be favored by the proximity of Co and Pd in metal particles. 相似文献
90.
Deadlock detection in distributed database systems: a new algorithm and a comparative performance analysis 总被引:4,自引:0,他引:4
Natalija Krivokapić Alfons Kemper Ehud Gudes 《The VLDB Journal The International Journal on Very Large Data Bases》1999,8(2):79-100
This paper attempts a comprehensive study of deadlock detection in distributed database systems. First, the two predominant
deadlock models in these systems and the four different distributed deadlock detection approaches are discussed. Afterwards,
a new deadlock detection algorithm is presented. The algorithm is based on dynamically creating deadlock detection agents (DDAs), each being responsible for detecting deadlocks in one connected component of the global wait-for-graph (WFG). The
DDA scheme is a “self-tuning” system: after an initial warm-up phase, dedicated DDAs will be formed for “centers of locality”,
i.e., parts of the system where many conflicts occur. A dynamic shift in locality of the distributed system will be responded
to by automatically creating new DDAs while the obsolete ones terminate. In this paper, we also compare the most competitive
representative of each class of algorithms suitable for distributed database systems based on a simulation model, and point
out their relative strengths and weaknesses. The extensive experiments we carried out indicate that our newly proposed deadlock
detection algorithm outperforms the other algorithms in the vast majority of configurations and workloads and, in contrast
to all other algorithms, is very robust with respect to differing load and access profiles.
Received December 4, 1997 / Accepted February 2, 1999 相似文献