Nanocarrier-Loaded Imidaclothiz Promotes Plant Uptake and Decreases Pesticide Residue

There is a great demand for improving the effective utilization of pesticides and reducing their application for sustainable agriculture, and polymeric nanoparticles have provided strong technical support for the efficient delivery of pesticides. To this context, we tried to construct a relatively safe imidaclothiz nano-delivery system for enhanced plant uptake, reduced pesticide residue and improved bioactivity toward green peach aphids. The imidaclothiz could be assembled with the hydrophobic core of SPc through hydrophobic association, which led to the self-assembly of nanoscale imidaclothiz/SPc complex consisting of nearly spherical particles. The SPc decreased the contact angle of imidaclothiz drops and remarkably increased the plant uptake. Furthermore, the bioactivity and control efficacy of imidaclothiz were significantly improved with the help of SPc in both laboratory and field. Excitingly, the residue of imidaclothiz decreased with the help of SPc 7 d after the treatment due to the faster degradation of nanoscale imidaclothiz/SPc complex, which exhibited no negative effects on agronomic traits of tobacco plants. The current study successfully constructed a nano-delivery system for imidaclothiz, which can not only increase the effective utilization of pesticides, but also decrease the pesticide residue.     

钢制安全壳焊后热处理工程应用与建议

根据钢制安全壳的结构尺寸、建造方式和焊后热处理要求,分析对比了适宜钢制安全壳焊后热处理的加热方式,并通过应用证明了局部焊后热处理的可行性.结合工程经验,提出了推动厚度小于60 mm的SA-738 Gr.B钢板免除焊后热处理,或采用超声波冲击处理代替焊后热处理的建议.     

连铸中间包控流装置优化数值模拟研究

针对板坯连铸机的中间包采用商业软件建立三维数学模型,计算不同中间包控流装置条件下中间包内的流场,分析不同方案对钢液流动状态和平均停留时间的影响,分析采用优化方案时钢中夹杂物的情况。结果表明,中间包控流装置的优化方案与原方案相比中间包的死区体积减少10.61%,中间包内开始出现示踪剂时间延长4.31%,均有利于中间包内钢液的混合和夹杂物上浮去除,同时采用优化方案钢中夹杂物水平能够满足生产工艺的要求。     

长沙市煤炭坝地区岩溶发育机理及空间分布规律研究

以长沙市煤炭坝地区为例,重点研究岩溶塌陷灾害的空间分布特征及岩溶发育程度控制因素.综合分析表明,区内岩溶发育强弱与岩溶塌陷灾害发育区域基本一致,平面上呈现"环状分布、北东向辐射"的特征,断裂带区域岩溶相对较发育;在垂向100 m深度范围内强发育,随深度增加而减弱,但靠近断层地带,岩溶局部强发育.     

几种纳米加工技术的原理、特点及其应用

从整体上介绍了基于传统半导体加工的纳米加工技术、探针直接书写式纳米加工技术、纳米复制加工技术,以及这几种纳米加工技术的原理、特点及其应用。     

机务体制改革的成效和解决既有问题的对策

根据沈阳铁路局机车运用、质量及管理现状调研,总结了重载提速和机务体制改革后所取得的成效,指出了现存的问题;在实事求是分析的基础上,提出了应对措施和解决办法.     

基于矩阵束方法的传输线系统瞬态响应分析

带有频变负载的传输线系统的瞬态响应分析是电磁兼容领域的一个重要内容,特别是对于频变负载网络较为复杂或内部结构不清晰的情况,其瞬态响应的分析较为困难。本文首先在采样频率点处对频变负载端口导纳进行测量或计算得到相应的采样导纳,并采用有理函数逼近的方式对端口导纳进行等效;之后采用矩阵束(MPM)方法求解出有理逼近函数所需的极点和留数,并将其代入到分段线性递归卷积(PLRC)技术中,实现传输线和频变负载连接点处电压的分段线性递归卷积表达;最后,结合传输线方程实现带有频变负载的传输线系统的瞬态响应分析,并通过2个算例对所提方法的性能进行验证。结果表明,所提方法在计算精确度上具有明显的优势。     

窨制方式对玫瑰红茶品质的影响

传统花茶的窨制主要是以鲜花与茶叶结合,为探究不同的窨制方法对玫瑰红茶的滋味和品质的影响,通过4种窨制方法（鲜花赋香、玫瑰细胞液喷洒赋香、玫瑰细胞液蒸气赋香、花瓣与细胞液蒸气结合赋香）对红茶进行赋香,完成玫瑰红茶的窨制。以色差、茶多酚总量、游离氨基酸含量、儿茶素等指标为依据,结合HS-SPME-GC-MS对不同窨制工艺制得的玫瑰红茶香气成分进行分析。结果表明,4种赋香方式所得玫瑰红茶的理化成分具有显著性差异（P<0.05）。用鲜花赋香和细胞液喷洒赋香的两种红茶茶汤偏红、偏黄,明亮度不及其它2种赋香方式。以喷洒玫瑰细胞液的窨制方式得到的玫瑰红茶氨基酸含量较高（112.66 mg/L）;以玫瑰鲜花窨制得到的玫瑰红茶茶多酚含量较低（680.38 mg/L）。玫瑰红茶的主要呈香化合物为苯乙醛、芳樟醇、（E,E）-2,4-庚二烯醛、水杨酸甲酯、乙酸苯乙酯、β-紫罗酮、香叶醇、2-正戊基呋喃和正己醛这9种,玫瑰鲜花细胞液窨制的玫瑰红茶中含有的9种主要呈香化合物显著高于其它3种。本研究有助于创新玫瑰红茶的窨制方式,为高品质玫瑰红茶的窨制提供参考。     

NiCoLDH nanosheets grown on MOF-derived Co_3O_4 triangle nanosheet arrays for high-performance supercapacitor

Hierarchical Co₃O₄@NiCoLDH nanosheets(NSs)were prepared on carbon cloth through a multistep method,containing Metal-organic frameworks(MOF)-templated thermal annealing and electrodeposition.The triangle-shaped Co₃O_(4 NSs)were firstly obtained by thermal treatment of MOF templates in air.Then,ultrathin NiCoLDH_NSswere in-situ electrodeposited on the surface of Co₃O_4NSs,constructing a core-shell structure.Benefiting the unique hierarchical structure,high conductivity of Co₃O_(4 NSs)core and large surface area of NiCoLDHNSs shell,the Co₃O₄@NiCoLDH_NSsarray served as supercapacitor electrode exhibits excellent electrochemical properties,such as high specific capacitance of 1708 F g^-1(850 C g^-1)at a current density of 1 A g^-1,good rate capability,and excellent cycling stability.Further,the asymmetric supercapacitor assembled by Co₃O₄@NiCoLDH_NSsand activated carbon,also displays superior electrochemical perfo rmance with high energy density and power density.Remarkably,the strategy of constructing core-shell structure based on MOF templates could be extended to other electrochemical fields.     

基于FAHP的装配式建筑施工质量风险分析及管理

为解决由于装配式建筑施工质量风险目标不明确、质量控制措施储备不足而导致质量风险问题频发的问题,对装配式建筑质量风险相关概念进行梳理,分析国内外相关文献及实际案例,按照风险类型提炼出装配式建筑质量存在的四类主要影响因素。在此基础上,建立基于模糊层次综合评价法的装配式建筑质量风险评价模型,对装配式建筑从设计到完工过程中各方面的多种因素进行识别分析、评价管理。应用该方法对工程实例进行分析,验证该方法切实可行,并制定相应的装配式建筑质量风险管理措施方案。