A Dual Physical Cross-Linking Strategy to Construct Tough Hydrogels with High Strength,Excellent Fatigue Resistance,and Stretching-Induced Strengthening Effect

Hydrogels with excellent stiffness, toughness, anti-fatigue, and self-recovery properties are regarded as promising water-containing materials. In this work, a dual physically cross-linked (DPC) sodium alginate (SA)/poly[acrylamide (AAm)-acrylic acid (AAc)-octadecyl methacrylate (OMA)]-Fe³⁺ hydrogel is reported, which is constructed by hydrophobic association (HA) and ionic coordination (IC). The optimal DPC hydrogel demonstrates excellent mechanical performance: tensile modulus of 0.65 MPa, tensile strength of 3.31 MPa, elongation at break of 1547%, and toughness of 27.8 MJ m^–3. SA/P(AAm-AAc-OMA)-Fe³⁺ DPC hydrogels also exhibit prominent anti-fatigue and self-recovery performance (99.1–109.7% modulus recovery and 90.4–108.9% dissipated energy recovery after resting for 5 min without additional stimuli at ambient temperature) through the reconstruction of reversible physical cross-linking. Some of the SA/P(AAm-AAc-OMA)-Fe³⁺ DPC hydrogels even exhibit a stretching-induced strengthening effect, which is similar to the performance of muscle—“the more training, the more strength.” Hence, the combination of HA and IC will provide an effective approach to design DPC hydrogels with desirable mechanical performances and a longer service life for wider applications of soft materials.     

Zirconium-Embedded Polyhedral Oligomeric Silsesquioxane Containing Phosphaphenanthrene-Substituent Group Used as Flame Retardants for Epoxy Resin Composites

A zirconium hybrid polyhedral oligomeric silsesquioxane derivative (Zr–POSS–bisDOPO) is synthesized by the corner-capping and Kabachnik–Fields reactions. It is characterized by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance spectroscopy (NMR), and then used as a flame retardant in diglycidyl ether of bisphenol A (DGEBA) to endow epoxy resin (EP) with flame retardancy. The flame retardancy, thermal stability, and mechanical properties of the cured EP/Zr–POSS–bisDOPO composites are investigated. The results show that when Zr–POSS–bisDOPO is added by 5–7 wt%, the EP/Zr–POSS–bisDOPO composites pass the UL-94 V-0 rating test. In addition, they have a better flame-retardant effect than pure EP. The combination of Zr atom embedded in the Si O cubic cage and the two phosphaphenanthrene substituent groups in one corner of cubic cage is expected to realize the Zr/Si/P ternary intramolecular hybrid synergistic effect and achieve the possibility of dispersing metal–POSS cages at a sub-micrometer-scale level into polymer matrix. It also proves that Zr–POSS–bisDOPO produces phosphorus-containing free radicals and terminates the chain reactions in gas phase. Meanwhile the Si O Si and Zr O units are retained in the solid phase, which promote the char formation and enhance the flame retardancy. This kind of Zr-doped POSS will be helpful for developing the new metal–POSS hybrid flame-retardant and polymer composites.     

GM模型的几何性质及统计检验

以空间向量几何理论为基础，详细地分析了Ｇａｕｓｓ－Ｍａｒｋｏｖ线性模型的几何性质；在实现了模型图形化描述的基础上，利用各解向量的几何及统计性质构造出了不同情形下的统计检验方法和相应的检验统计量，为全面、深入地研究和灵活运用该模型提出了一种简洁直观的数学方法     

水压环形缝隙泄漏量的试验研究

在水压系统环形缝隙泄漏试验基础上，对圆柱形配合状态下的缝隙泄漏量进行了理论和试验对比研究，分析了两者的变化规律。得出的结果可以为水压元件的设计提供试验依据。     

用攀枝花钛矿和云南钛矿冶炼钛渣工业试验研究

通过磁性测量和X-射线衍射研究了Gd2(Co，Al)17化合物的结构和磁晶各向异性。当x≤4时，样品具有菱方Th2znl7型结构，x=5时，具有六方CaCu5型结构。随着Al浓度增加，晶格常数和单胞体积单调增大，而居里温度和自发磁化强度近似线性地减小；在x≥l时，观察到Co亚点阵的磁晶各向异性变号，室温易磁化方向由易面转变为易轴，且易轴各向异性场和各向异性常数随Al原子浓度增加出现极大值；基于补偿温度(65K)下自由粉末颗粒的磁化曲线，导出了亚点阵间的分子场系数和Gd-co交换耦合常数，结果表明，Al原子对Gd-Co交换耦合作用的影响较小。根据Al原子在Co亚点阵4种晶位的择优占位，分析了磁晶各向异性的演变。     

Properties and Microstructuresof Three Kinds of Silversheathed Bi-2223 Tapes

ＰｒｏｐｅｒｔｉｅｓａｎｄＭｉｃｒｏｓｔｒｕｃｔｕｒｅｓｏｆＴｈｒｅｅＫｉｎｄｓｏｆＳｉｌｖｅｒｓｈｅａｔｈｅｄＢｉ－２２２３ＴａｐｅｓＺｅｎｇＲｏｎｇ；ＺｈｏｕＹｉｒｕ；ＹｅＢｉｎ；ＺｈｏｕＭｉｎ；ＺｈａｎｇＪｉａｎｇｕｏ（曾荣）（周贻茹）（叶斌）...     

辊底式热处理炉的改造

原江西新钢钢管有限责任公司的2座辊底式热处理炉,由于是采用人工手动调节煤气流量来控制温度,由此导致钢管热处理质量不稳定,加之冷料入炉,加热时间长、出炉烟气温度高,需进行改造。通过对炉型结构、燃烧系统及炉温控制系统3个方面的改造,达到了提高炉子产量、产品质量及节能降耗的效果。     

中美法学教育之比较

当代中国的法学教育发展很快，但由于起步晚，至今在很多方面仍有不足。为便于借鉴美国法学教育之长，特从教育管理、教育目标、教育层次、教育方法、师资等方面进行比较，以探索一条有中国特色的法学教育之路。     

TiAl合金的电子束蒸发行为

建立了TiAl合金蒸发和沉积数学模型，采用活度系数体现溶池中不同组元的相互作用，影响组元蒸发速率的因素主要有元素饱和蒸气压和活度系数，计算值与试验值符合良好。研究结果表明，TiAl合金可以采用底部连续进给单一水冷铜坩埚通过电子束物理气相沉积得到。     

微细粒技术在洁净煤技术中的作用和地位

从煤加工利用对颗粒粒度及其分布的要求，解离度对超纯煤的制备以及煤炭组分工业化分离的影响等方面论述了微细粒技术在洁净煤技术中的作用和地位。研究表明煤的粒度及其分布对水煤浆制备及其利用，燃烧等有极其重要的影响；