Synthesis and aqueous solution behaviors of sodium sulfonate‐terminated dendritic poly(ester‐amine)

Sodium sulfonate‐terminated dendritic poly(ester‐amine) (SPEA) was synthesized by sulfonation of acrylic double bond‐terminated dendritic poly(ester‐amine) (APEA) with sodium hydrogen sulfite (NaHSO₃) in mixture of diglycol and 2‐butanone under normal pressure. The structure of SPEA was characterized by IR, ¹H‐NMR, and elemental analysis. SPEA was water‐soluble. 1.0–40.0% (mass) SPEA aqueous solutions appeared as dilatant fluid. When pH value varied from 1.5 to 12.0, the viscosity of 1–5% (mass) SPEA aqueous solutions changed very small, and the electric conductivity almost kept stable within pH 3.0–10.0. The relationship between the viscosity and the concentration of SPEA water solutions was similar to that of NaCl water solutions. The surface tension of SPEA water solutions was lower than that of polyethylene glycol 2000 water solutions with the same concentration. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Shear-induced crystallization of poly(phenylene sulfide)

The crystalline morphology of poly(phenylene sulfide) (PPS) isothermally crystallized from the melt under shear has been observed by polarized optical microscope (POM) equipped with a CSS450 hot-stage. The shish–kebab-like fibrillar crystal structure is formed at a higher shear rate or for a longer shear time, which is ascribed to the tight aggregation of numerous oriented nuclei in the direction of shear. The crystallization induction time of PPS decreases with the shear time, indicating that the shear accelerates the formation of stable crystal nuclei. Under shear, the increase of spherulite growth rate results from highly oriented chains. The melting behavior of shear-induced crystallized PPS performed by differential scanning calorimetry (DSC) shows multiple melting peaks. The lower melting peak corresponds to melting of imperfect crystal, and the degree of crystal perfection decreases as the shear rate increases. The higher melting peak is related to the orientation of molecular chains. These oriented molecular chains form the orientation nuclei which have higher thermal stability than the kebab-like lamellae that are developed later. A new model based on the above observation has been proposed to explain the mechanism of shish–kebab-like fibrillar crystal formation under shear flow.     

宝钢曲轴用非调质钢的生产与展望

在实验室研究的基础上，开发了屈服强度为520MPa级的曲轴用微合金化非调质钢48MnV。工业生产了6000余吨φ151mm大规格圆钢，其各项性能满足了用户要求。指出了宝钢曲轴用非调质钢开发和努力的方向。     

单片机在产生特殊复合磁场系统中的应用

探讨了在电磁铸轧中采用单片机作为核心监控装置的工作原理，论述了用单片机实现函数信号发生的硬件设计和软件流程，实现了对感应器产生特殊复合磁场的控制，并提出了一种新的随机数的产生方法。     

钢轨试验方法的研究

结合即将颁布的新国家标准GB2585<铁路用热轧钢轨>和国家标准TB/T2344-2003<43 Kg/m-75 Kg/m热轧钢轨订货技术条件>,通过对武钢生产的U71Mn重轨进行拉伸性能、布氏硬度、脱碳层分布情况、非金属夹杂物以及显微组织等试验方法的研究,分析了U71Mn重轨在新旧标准要求下的质量水平,为改善U71Mn的质量、符合新标准提供了重要的检验理论依据.     

电子式电能表的接线方式及误差分析

针对电子式电能表与机械式电能表之间的不同结构和工作原理，提出应根据不同应用情况来决定其安装接线方式。另外通过对电子式电能表做线损、三相负荷平衡率和走字试验的实例分析，认为应根据两者不同的结构状况和工作原理才能保证正确计量。     

Study of Liquid Phase Shifter for ICRF on EAST

A method of current drive with Ion Cyclotron Range of Frequency （ICRF） on Experimental Advanced Superconducting Tokomak （EAST） is described. A variety of liquid silicon oil heights in the phase shifter will bring the phase difference to the current drive. It is found that the current drive can be achieved by using the phase shifter. The liquid phase shifter is one of the impedance matching systems too.     

Al2O3/TiB2/SiCw三元复合材料的力学性能及显微结构

以Al₂O₃为基体,SiC晶须和TiB₂颗粒两种增韧剂,采用热压烧结工艺制备了Al₂O₃/TiB₂/SiC_w三元复合陶瓷材料。研究了热压工艺参数对材料致密度的影响和晶须含量对该复合材料的力学性能和显微结构的影响。结果表明;随晶须含量的增加,该复合材料的热压温度和保温时间需要相应的增加;晶须拔出、裂纹偏转和晶须的桥接为该复合材料的主要增韧机理;随晶须含量的增加,该材料的室温断裂韧性增加;该材料的断裂韧性随温度的升高而呈增大趋势,并且晶须含量越高,材料的高温断裂韧性增幅越大。     

掺Tb_2O_3法拉第旋转玻璃

本文研究了掺Tb_2O_3的法拉第旋转玻璃的组成、物理化学性质及制备技术,实验结果表明维尔德常数V随着Tb_2O_3浓度的增大而增大,硼硅酸盐玻璃中Tb_2O_3含量大于20％(mol)时,维尔德常数可以达到-0.0030min/A/m·cm,从熔制试验结果0.5L铂坩埚可以获得质量较好的φ50×25mm的样品。