Upgrading of Raw Gas from Biomass and Waste Gasification: Challenges and Opportunities

The depletion of fossil fuel-based resources and concerns for increasing emissions of CO₂ call for new ways of producing environmentally-friendly substitutes for motor fuels and chemicals. Thermo-chemical conversion of biomass and waste using gasification is a strong candidate to meet these challenges. For efficient and cost-effective application of this technique, novel solutions for hot gas cleaning are needed. This review highlights some important areas for improvement of upgrading technologies for pressurised fluidised bed gasification systems using biomass as a fuel.     

Industrial aspects and literature survey: Fleet composition and routing

The purpose of this paper is to describe industrial aspects of combined fleet composition and routing in maritime and road-based transportation, and to present the current status of research in the form of a comprehensive literature review. First, presents a classification of problems, and then focuses on a basic definition of combined fleet composition and routing: the fleet size and mix vehicle routing problem. A basic mathematical formulation from the literature is presented. Further, the literature of extended and related problems is described and categorized. Surveys of application oriented research in road-based and maritime transportation conclude the review. Finally, we contrast the literature with aspects of industrial applications from a critical, but constructive stance. Major issues for future work are suggested.     

Nanometer-thick films of titanium oxide acting as electrolyte in the polymer electrolyte fuel cell

0-18 nm-thick titanium, zirconium and tantalum oxide films are thermally evaporated on Nafion 117 membranes, and used as thin spacer electrolyte layers between the Nafion and a 3 nm Pt catalyst film. Electrochemical characterisation of the films in terms of oxygen reduction activity, high frequency impedance and cyclic voltammetry in nitrogen is performed in a fuel cell at 80 °C and full humidification. Titanium oxide films with thicknesses up to 18 nm are shown to conduct protons, whereas zirconium oxide and tantalum oxide block proton transport already at a thickness of 1.5 nm. The performance for oxygen reduction is higher for a bi-layered film of 3 nm platinum on 1.5 or 18 nm titanium oxide, than for a pure 3 nm platinum film with no spacer layer. The improvement in oxygen reduction performance is ascribed to a higher active surface area of platinum, i.e. no beneficial effect of combining platinum with zirconium, tantalum or titanium oxides on the intrinsic oxygen reduction activity is seen. The results suggest that TiO₂ may be used as electrolyte in fuel cell electrodes, and that low-temperature proton exchange fuel cells could be possible using TiO₂ as electrolyte.     

Data‐driven Analysis of Sulfur Flows and Behaviour in the Blast Furnace

Sulfur has for long been known as a problematic element for the quality of iron, but along with its accumulation it also causes physical problems in the blast furnace, so it is of central importance to safeguard its removal from the process. Sulfur‐related problems in the blast furnace were studied by applying a balance equation for the element at three industrial blast furnaces, tracking errors in the in‐ and outflows and estimating changes in the amount of accumulated sulfur. A hypothesis on the behaviour of sulfur in the process was proposed and supporting evidence of it was found through an analysis of dynamic phenomena in the hearth of one of the furnaces.     

Changes in liquid‐holding capacity,water distribution and microstructure during chill storage of smoked salmon

BACKGROUND: During recent years, increases in liquid loss and soft texture in cold smoked salmon have been reported, possibly due to increased lipid content and a change in muscle structure. These problems can lead to downgrading of the product. This study aimed to investigate the influence of raw material composition and chill storage on quality parameters of cold smoked salmon. RESULTS: Initial smoked fish had a higher liquid‐holding capacity (LHC) than samples stored for 20 days. Large fish lost more liquid than small fish. The difference in LHC was consistent with a change in water distribution, which could indicate denaturation of muscle protein. Studies of the microstructure showed the influence of both processing and chill storage. An indication of lipid released from the cells was seen after 20 days of chill storage, which could be related to the reduced LHC at that time. CONCLUSION: Both raw material composition and chill storage affected the quality parameters of smoked salmon. This study has improved knowledge about the relationships between muscle structure, liquid‐holding properties and water distribution in smoked salmon. Copyright © 2007 Society of Chemical Industry     

A large-time-stepping scheme for balance equations

A well-balanced, large-time-stepping method for conservation laws with source terms is presented. The numerical method is based on a local reformulation of the balance law as a conservation law with a discontinuous flux function, and the approximate solution of this equation by a front tracking method. This yields an unconditionally stable method which is particularly well suited to calculate stationary states. The viability of this approach is demonstrated by several numerical examples. KHK has been supported in part by an Outstanding Young Investigators Award from the Research Council of Norway.     

Implementation of energy-conservation policies: the case of electric heating conversion in Denmark

This article analyses which kinds of public planning, regulation and initiatives are suitable for the implementation of energy-conservation policies. The policies are important elements of the Danish plans for implementing CO₂-reduction targets. The plans are characterised by a move away from energy systems, based on large power stations and large gas and oil extraction systems, to far more decentralised systems based on energy efficiency at the individual places of consumption and renewable energy systems adapted to local conditions. This change demands not only technical modifications, but also large, organisational changes, which will often entail the establishment of completely new organisations. The nature and complexity of the needed technological changes call for public regulation instruments of the same nature, i.e. numerous, differentiated and multi-purpose. In the case of electric-heating conversion, such public regulation so far has managed to achieve CO₂ reductions together with the creation of 150 jobs. In the near future, more than 1000 permanent jobs can be created without negative consequences for the balance-of-payment. The same kind of job creation is possible in most other European countries.     

Creep in phosphorus alloyed copper during power-law breakdown

During the first phase of storage, creep will take place in the copper canisters in the KBS-3 package for nuclear waste. The temperatures are below 100 °C, and the creep is well inside the power-law breakdown regime. Creep models for this situation have been developed. The analysed material is pure copper with about 50 ppm phosphorus. Constitutive equations for creep and other plastic deformation have been set up based on a generalised Norton expression and Kocks-Mecking’s model for the back stress. A model for the minimum creep rate based on fundamental principles for climb and glide has been derived. This model gives the correct order of magnitude for the creep rate in the temperature range from 400 to 20 °C without the use of fitted parameters. The creep exponent varies from 5 to 105 in this interval. The constitutive equations have also been formulated for multiaxial stress states.