Reprogrammable optical phase array

A novel reprogrammable optical phase array (ROPA) device is presented as a reconfigurable electro-optic element. One specific application of the ROPA, a 1 x 6 electro-optic space switch, is fully described. Switching angles are within 2 degrees , and switching is achieved through a complementary metal-oxide semiconductor (CMOS) controlled, diffraction based, optical phase array in a bulk BaTiO3 crystal. The crystal is flip-chipped to the CMOS chip, creating a compact fully integrated device. The design, optical simulation, and fabrication of the device are described, and preliminary experimental results are presented.     

An Overview and Future Perspectives of Aluminum Batteries

A critical overview of the latest developments in the aluminum battery technologies is reported. The substitution of lithium with alternative metal anodes characterized by lower cost and higher abundance is nowadays one of the most widely explored paths to reduce the cost of electrochemical storage systems and enable long‐term sustainability. Aluminum based secondary batteries could be a viable alternative to the present Li‐ion technology because of their high volumetric capacity (8040 mAh cm^?3 for Al vs 2046 mAh cm^?3 for Li). Additionally, the low cost aluminum makes these batteries appealing for large‐scale electrical energy storage. Here, we describe the evolution of the various aluminum systems, starting from those based on aqueous electrolytes to, in more details, those based on non‐aqueous electrolytes. Particular attention has been dedicated to the latest development of electrolytic media characterized by low reactivity towards other cell components. The attention is then focused on electrode materials enabling the reversible aluminum intercalation‐deintercalation process. Finally, we touch on the topic of high‐capacity aluminum‐sulfur batteries, attempting to forecast their chances to reach the status of practical energy storage systems.     

Influence of the microstructure of gums on the mechanical properties of silicone high consistency rubbers

This paper is devoted to the characterization and processing of high molar mass vinyl‐bearing polysiloxanes in high consistency silicone rubber (HCR) formulations. The molar masses of five different polydimethylsiloxane gums, bearing vinyl groups at the ends and along their chains, were evaluated by size exclusion chromatography and rheometry. ²⁹Si and ¹H NMR spectroscopy allowed the precise determination of the vinyl content and of the distribution in the different polymers. Typical HCRs formulated from these gums were heat‐cured to process silicone rubber materials that were then tested mechanically. The macromolecular properties were correlated to the final material network structure. The amount of reactive vinyl moieties, rather than their distribution along or at the end of chains, is a key parameter to tailor the material mechanical properties. © 2016 Society of Chemical Industry     

Quantitative Assessment of Affinity Selection Performance by Using DNA-Encoded Chemical Libraries

DNA-encoded chemical libraries are often used for the discovery of ligands against protein targets of interest. These large collections of DNA-barcoded chemical compounds are typically screened by using affinity capture methodologies followed by PCR amplification and DNA sequencing procedures. However, the performance of individual steps in the selection procedures has been scarcely investigated, so far. Herein, the quantitative analysis of selection experiments, by using three ligands with different affinity to carbonic anhydrase IX as model compounds, is described. In the first set of experiments, quantitative PCR (qPCR) procedures are used to evaluate the recovery and selectivity for affinity capture procedures performed on different solid-phase supports, which are commonly used for library screening. In the second step, both qPCR and analysis of DNA sequencing results are used to assess the recovery and selectivity of individual carbonic anhydrase IX ligands in a library, containing 360 000 compounds. Collectively, this study reveals that selection procedures can be efficient for ligands with sub-micromolar dissociation constants to the target protein of interest, but also that selection performance dramatically drops if 10⁴ copies per library member are used as the input.     

Encoding Information on the Excited State of a Molecular Spin Chain

The quantum states of nano-objects can drive electrical transport properties across lateral and local-probe junctions. This raises the prospect, in a solid-state device, of electrically encoding information at the quantum level using spin-flip excitations between electron spins. However, this electronic state has no defined magnetic orientation and is short-lived. Using a novel vertical nanojunction process, these limitations are overcome and this steady-state capability is experimentally demonstrated in solid-state spintronic devices. The excited quantum state of a spin chain formed by Co phthalocyanine molecules coupled to a ferromagnetic electrode constitutes a distinct magnetic unit endowed with a coercive field. This generates a specific steady-state magnetoresistance trace that is tied to the spin-flip conductance channel, and is opposite in sign to the ground state magnetoresistance term, as expected from spin excitation transition rules. The experimental 5.9 meV thermal energy barrier between the ground and excited spin states is confirmed by density functional theory, in line with macrospin phenomenological modeling of magnetotransport results. This low-voltage control over a spin chain's quantum state and spintronic contribution lay a path for transmitting spin wave-encoded information across molecular layers in devices. It should also stimulate quantum prospects for the antiferromagnetic spintronics and oxides electronics communities.     

The novel low temperature synthesis of nanocrystalline MgAl2O4 spinel using “gel” precursors

Nanocrystalline MgA1₂O₄ was synthesized by pyrolysis of the homogeneous spinel precursor, Mg(C₄H₅O₂)₂·(H₂O):Al₂(OH)₃(C₃H₃O₂)₃·(H₂O)₂:NH₄(C₃H₃O₂)·(H₂O). The spinel precursor gel is composed of a mixture of magnesium and aluminum acrylate salts dissolved in an ammonium acrylate gel. The reaction of acrylic acid with magnesium hydroxide in water produced magnesium methacrylate, and a similar reaction of basic aluminum acetate produced the aluminum salt of acrylic acid. The reaction of acrylic acid with ammonium hydroxide produced the ammonium acrylate gel. Ammonium acrylate gel was found to absorb many times its own weight of water. Although similar properties have been identified in PMMA and in the polymer of sodium acrylate, only the ammonium acrylate gel exists as an unpolymerized monomer. The spinel precursor gel is a pre-ceramic material that yields an amorphous oxide phase at 425°C that begins to crystallize to the MgAl₂O₄ spinel at 600°C and is fully crysta1line at 1030°C with a uniform particle size of 7-100 nm. The spinel precursor gel and the nanocrystalline MgA1₂O₄ spinel were characterized by XRD and TEM.     

Shape Factor Effect on Inclusion Sedimentation in Aluminum Melts

Metallurgical and Materials Transactions B - The quality requirements of aluminum products are steadily increasing, and the presence of non-metallic inclusions have a large impact on the quality of...     

Modeling and detecting response of micromachining square and circular membranes transducers based on AlN thin film piezoelectric layer

Vibration analysis of square and circular piezoelectric micro ultrasonic transducers (pMUTs) in the 100 kHz range as a function of experimental tools are reported. Analytical and 3D finite element method analysis using Comsol software has been performed to model static, modal and vibration behavior of these membranes. Comparison with standard impedancemeter measurement is shown to assess the performance of Laser Doppler Vibrometry system. Mechanical and electrical characterization and comparison with a model results are presented and discussed. The measured resonances frequencies of membrane can be weak and superimposed on important parasitic signal, which may mask the desired mechanical resonance signal. Our results revealed the real roles of the simulations and the combination of the experimental tools to get measurement accuracy. Subsequently, this piezoelectric micro-transducer was successfully tested as a sounder in air. These investigations offer guidance for the pMUTs design and associated electronic circuit but might at the same time be instructive and beneficial to further sensor applications.

     

Thermodynamic and spectroscopic measurements of the electron-hole drop binding energy in Ge: An old problem revisited

One can expect to get the electron-hole (EHD) binding energy φ either from spectroscopic or from threshold measurements. While the value obtained by the former is in excellent agreement with theory, the results given by the latter did not seem to lead to φ in a simple way. We present here new optical threshold studies in which we think that the right conditions to obtain a direct thermodynamic measurement of φ have been mastered. Besides, our results present novel features like a sharp jump of the EHD luminescence at threshold above 2.4 K and observation of hysteresis in the whole temperature range of our work.