BaCeO3 钙钛矿型氧化物的储氮和抗硫性能研究

采用改进的溶胶-凝胶法制备了钙钛矿结构的BaCeO3样品,在此基础上再用浸渍法制备了Pt/BaCeO3、 Rh/BaCeO3、 Pt-Rh/BaCeO3样品,并用机械混合γ-Al2O3,再浸渍贵金属的方法制备了Pt/BaCeO3/γ-Al2O3、 Rh/BaCeO3/γ-Al2O3、 Pt-Rh/BaCeO3/γ-Al2O3样品.储氮量(NSC)结果表明:对未加γ-Al2O3的BaCeO3来说,贵金属的加入反而使NSC减小.加入贵金属催化剂的储氮量(NSC)大小为: Pt的最大, Rh的次之, Pt-Rh的最小.γ-Al2O3的加入对BaCeO3吸收NO和O2没有影响.而对于BaCeO3/γ-Al2O3样品,贵金属的加入使NSC值提高了3倍以上.讨论了贵金属加入到BaCeO3/γ-Al2O3样品中显著提高样品储氮能力的原因.结合XRD结果表明,钙钛矿 BaCeO3相是Ba-Ce-O样品主要的NOx储存活性中心.NSC结果还表明, BaCeO3和Pt/BaCeO3催化剂在SO2为≤0.006%时具有较好的抗硫性能.而Pt/BaCeO3/γ-Al2O3催化剂不但具有较好的储氮能力而且具有更好的抗硫性能.     

Capacitated dynamic lot sizing problems in closed-loop supply chain

In this paper, we address the capacitated dynamic lot sizing problem arising in closed-loop supply chain where returned products are collected from customers. These returned products can either be disposed or be remanufactured to be sold as new ones again; hence the market demands can be satisfied by either newly produced products or remanufactured ones. The capacities of production, disposal and remanufacturing are limited, and backlogging is not allowed. A general model of this problem is formulated, and several useful properties of the problem are characterized when cost functions are concave. Moreover, this problem is analyzed and solved to optimality using dynamic programming algorithms under different scenarios. It is shown that the problem with only disposal or remanufacturing can be converted into a traditional capacitated lot sizing problem and be solved by a polynomial algorithm if the capacities are constant. A pseudo-polynomial algorithm is proposed for the problem with both capacitated disposal and remanufacturing. The problem with capacitated production and remanufacturing and the problem with uncapacitated production and capacitated remanufacturing are also analyzed and solved. Through numerical experiments we show that the proposed algorithms perform well when solving problems of practical sizes. From the experimental results also indicates that it is worthwhile to expand the remanufacturing capacity only when returned products exist in a relatively long planning horizon, and production capacities have little effect on the remanufacturing plan when the demand is mainly satisfied by the production.     

HL—1M弹丸加料等离子体中约束改善和MHD特性研究

在ＭＬ－１Ｍ装置实验中，多发弹丸注入在ｑ＝１磁面内区域产生了高度峰化的密度和压强分布，明显改善了等离子体约束特性。标志着弹丸注入约束改善的峰化的密度、压强分布，在出现第一个大锯齿后平化。弹丸注入后的锯齿崩溃，在密度和压强峰化因子均较高时，具有在更高密度、更高压强下才出现的类理想的特性。随着弹丸穿中 部区域的密度梯度变陆，在中心ＭＨＤ活性受到弹丸注入强烈影响，锯齿崩溃特征从完全重连型变成部分重连型，     

Cross‐linking induced thermoresponsive hydrogel with light emitting and self‐healing property

Development of self‐healing hydrogels with thermoresponse is very important for artificial smart materials. In this article, the self‐healing hydrogels with reversible thermoresponses were designed through across‐linking‐induced thermoresponse (CIT) mechanism. The hydrogels were prepared from ketone group containing copolymer bearing tetraphenyl ethylene (TPE) and cross‐linked by naphthalene containing acylhydrazide cross‐linker. The mechanical property, light emission, self‐healing, and thermo‐response of the hydrogels were investigated intensively. With regulation of the copolymer composition, the hydrogels showed thermoresponse with the LCST varied from above to below body temperature. At the same time, the hydrogels showed self‐healing property based on the reversible characteristic of the acylhydrazone bond. The hydrogel also showed temperature‐regulated light emission behavior based on AIE property of the TPE unit. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 869–877     

通用组合型层析摄影反演

本文采用Ｂｅｓｓｅｌ函数与Ｚｅｒｎｉｃｋｅ函数组合的方式，编制了一通用的Ｔｏｍｏｇｒａｐｈｙ程序。它既可用于撕裂模磁岛结构的研究，又可用于杂质剖面的反演。结果说明，这种组合方式既有Ｂｅｓｓｅｌ函数的优点－在边界无毛齿，又有Ｚｅｒｎｉｃｋｅ函数的优点－在中心反演精度较高。     

A MICRO-MECHANICAL MODEL OF KNITTED FABRIC AND ITS APPLICATION TO THE ANALYSIS OF BUCKLING UNDER TENSION IN WALE DIRECTION： MICRO-MECHANICAL MODEL

The typical micro-knitting structure of knitted fabric, which makes it very different from woven fabric, is described. The tensile tests of knitted fabric are reported. The deformations of the micro-knitting structures are carefully studied. The study indicates that when a knitted fabric sheet is subjected to a tension along w-direction an extra compressive stress field inside loop in c-direction is induced. The extra stress field is also determined through analysis. Finally, a micro-mechanical model of knitted fabric is proposed. This work paves the way for the simulations of buckling modes of a knitted fabric sheet as are observed in experiments. The project supported by the National Natural Science Foundation of China (10272079)     

Dynamical behavior of delayed Hopfield neural networks with discontinuous activations

In this paper, a general class of neural networks with arbitrary constant delays is studied, whose neuron activations are discontinuous and may be unbounded or nonmonotonic. Based on the Leray–Schauder alternative principle and generalized Lyapunov approach, conditions are given under which there is a unique equilibrium of the neural network, which is globally asymptotically stable. Moreover, the existence and global asymptotic stability of periodic solutions are derived, where the neuron inputs are periodic. The obtained results extend previous works not only on delayed neural networks with Lipschitz continuous neuron activations, but also on delayed neural networks with discontinuous neuron activations.     

Co助剂对稀燃NOx阱Pt/Ba-Al-O结构和性能的影响

 采用共沉淀－浸渍法制备了Pt／Co－Ba－Al－O催化剂，用X射线衍射、X射线吸收近边结构和扩展X射线吸收精细结构等手段表征了催化剂的微观结构，并在连续流动微型反应器上测定了催化剂对NOx的储存性能．载体经过800℃焙烧后，Co物种主要以四面体配位的铝酸钴相存在．在富氧条件下，高分散的小颗粒铝酸钴相促进了NO向NO2的转化，大大改善了催化剂对NOx的储存性能．铂物种则以小的金属原子簇形式存在，分散度很高．钴助剂的添加改善了氧化铝相的分散度，抑制了金属铂原子簇与载体的相互作用，使铂在催化剂表面分散得更均匀，从而有利于NOx的储存．     

测定极化聚合物膜的二阶非线性光学系数的新方法──偏振红外光谱法

本文报道在一维刚性取向气体模型基础上用偏振红外光谱测出的极化膜的取向度估算其二阶非线性光学系数α值的方法。方法表明,在目前采用的各种极化方法所能达到的极化效率范围内,取向因子可表示为     

(＋∞∑n-1)1/n2m的初等解法

本文用初等的方法研究(＋∞∑n-1)1/n2m(m∈N)的求和问题. 这个问题最先由Euler[8]解决.文献[1][6]给出了另两种求解方法.特别地,对于m=1的情形,即(＋∞∑n-1)1/n2=∏2/6,已有许多不同的证明方法,可见文献[2][3][4][5]以及那里的参考文献.本文的想法,主要受文献[5][6]的启发而来的.