Quantitative estimation of sucrose esters of plamitic acid

Thin layer chromatography was adapted for direct quantitative estimation of sucrose esters of palmitic acid. Urea-phosphoric acid spray was used to detect the sucrose moiety of the various esters. The photometrically metermined density density of each spot on the thin layer plate was found to be proportional to its sucrose content. Ester content was then obtained by multiplying sucrose found by the factor, mol. wt. ester/mol. wt. sucrose. Ester mixtures were prepared by interesterifying sucrose with various proportions of methyl palmitate in dimethylformamide solution. Positional isomers were observed at each level of substitution but could not be adequately separated from each other for quantitative evaluation. Presented at the AOCS Meeting, Minneapolis, October 1969. So. Utiliz. Res. Dev. Div., ARS, USDA.     

Oxygen permeation of blends of copolymers of siloxanes and poly(methylmethacrylate)

A series of low molecular weight (≈40000) copolymers of methylmethacrylate (MMA) and 4-(methacryloyloxy)butylpentamethyldisiloxane (MBPD) have been synthesized by free radical polymerization in dimethylformamide solution. The microstructure, as derived from ¹³C NMR spectra, indicates that the copolymers are about 80% syndiotactic with an overall random distribution of mers. At room temperature, copolymers rich in MMA are clear, rigid glasses but become liquid at high MBPD content. Blends of these copolymers with PMMA are all heterogeneous with visible phase separation over most of the composition range. Differential scanning calorimetry studies show the presence of two T_g's when the relative concentration of PMMA to copolymer is high. Blends of two co-polymers of similar siloxane content produce clear films with no indication of phase separation. The permeability to oxygen at 25°C increases from 0.20 for pure PMMA to 3.0 (fmol/m·s·Pa.) for a copolymer of MMA/MBPD of the mole ratio of 3:1. Evaluation of the permeation behaviors of the blends suggests that blends rich in siloxane exist as a layered structure with the PMMA rich component dominating the observed permeability.     

冠带层新平台技术

子午线轮胎出现不久，就采用钢丝带束层代替了纤维带束层，这对于实现子午线轮胎提高使用寿命和改善操纵性能的潜能是必要的。     

Control policies for an industrial acetylene hydrogenation reactor

This paper addresses the problem of finding optimal operational policies for an acetylene reactor for day to day operation. A lumped parameter model based on four main reactions is developed and used to examine the effects of the reactor manipulated variables on key reaction parameters. An optimal and a sub-optimal operational policy which minimize the ethylene loss over time are formulated and the solution techniques are presented. The results indicate that the reactor model is in good agreement with industrial plant data. The performance of the optimal control policy is very similar to the performance of the sub-optimal control policy. However, the sub-optimal formulation, while retaining the dominant features of the optimal response, reduces the computational requirements. Finally, some issues concerning the real-time implementation of an advanced acetylene reactor control scheme are presented. These include the estimation of the optimum regeneration cycle, a recursive model update algorithm, the process optimizer and their overall coordination. A preliminary analysis of the benefits associated with the advanced control scheme suggests a considerable reduction in the yearly ethylene loss.     

The synthesis and characterization of calcium aluminate monoiodide

The hydrated calcium aluminate AFt and AFm phases are known hosts for a wide variety of chemical species. This characteristic is beneficial to those using portland cement to solidify/encapsulate radioactive waste which more often than not contains a wide variety of elements. In order to investigate the potential of the calcium aluminate hydrates as host phases for selected ions, the following experiments were carried out. Bottle hydration studies (water/solid > 1) were used to investigate the suitability of the AFt and AFm phases as hosts for iodine, one of the more mobile radioactive waste elements. Trial compositions along the AFt and AFm joins in the systems 3CaO·Al₂O₃---CaSO₄---CaI₂---H₂O were investigated. No stable iodine end-member AFt phase was formed at room temperature. The end-member AFm phase, 3CaO·Al₂O₃·CaI₂·12H₂O, was synthesized and was designated monoiodide. Characterization was carried out using chemical analysis, scanning electron microscopy, x-ray diffraction (conventional and high temperature), thermogravimetric analysis and differential thermal analysis. Monoiodide was indexed as hexagonal and thus isostructural with previously described AFm phases. Monoiodide is stable to about 85°C. A loss of approximately four molecules of water occurs between 71° and 101°C. The lower hydrate, tentatively identified as 3CaO·Al₂O₃·CaI₂·8H₂O, is stable to approximately 300°C. The latter hydrate was observed to revert to the original hydrate on exposure to the relative humidity in the laboratory.     

Application of scanning tunnelling microscopy to the quality control of tungsten carbide (WC-Co) ball bearings

Scanning tunnelling microscopy (STM) has been applied to the topographical study of tungsten carbide (with 6% Co) ball bearings in air. It is shown that, for this material, scanning tunnelling microscopy can provide not only general topographical information on the surface microtexture with a resolution of nearly 0.1 nm if required, but also quantitative information for the measurement of surface roughness. Thus, scanning tunnelling microscopy has utility as a quality control tool of particular relevance in the submicron range. The STM topographical results from specific tungsten carbide ball bearings are presented, and the limitations and applicability of the STM technique when used as a quality control tool are discussed.     

Forming an intention to act on recommendations given via online social networks

Online social networks (OSN) are technology-enabled relationship tools in which a user creates a profile, connects to other individuals, and shares user-generated content with them. One of the many features OSN offer is the ability to post messages in the form of product and service recommendations. Although word-of-mouth research has examined this type of personal communication to intentionally influence consumer decisions, limited understanding exists regarding when a user acts upon a recommendation received from one of their contacts. In this study, we draw on relationship theories and research on trust to analyze the impact relationship characteristics and behaviors of the OSN contacts have on trust in the recommendation that subsequently leads a user to act on this OSN contact’s recommendation. The results of a survey of 116 OSN users showed that closeness, excessive posting behavior, and past recommendation experience have a positive impact on trust and intention to act on the recommendation. One characteristic of the relationships, that is, similarity, however, does not affect recommendation trust in the context of OSN. The findings enhance our understanding of relationships and their defining characteristics in OSN. The results also provide insights into how companies might leverage OSN in their marketing efforts.     

Psychometric Evaluation of the EMO and the SUS in the Context of a Large-Sample Unmoderated Usability Study

This article describes the psychometric properties of the Emotional Metric Outcomes (EMO) questionnaire and the System Usability Scale (SUS) using data collected as part of a large-sample unmoderated usability study (n = 471). The EMO is a concise multifactor standardized questionnaire that provides an assessment of transaction-driven personal and relationship emotional outcomes, both positive and negative. The SUS is a well-known standardized usability questionnaire designed to assess perceived usability. In previous research, psychometric evaluation using data from a series of online surveys showed that the EMO and its component scales had high reliability and concurrent validity with loyalty and overall experience metrics but did not find the expected four-factor structure. Previous structural analyses of the SUS have had mixed results. Analysis of the EMO data from the usability study revealed the expected four-factor structure. The factor structure of the SUS appeared to be driven by item tone. The estimated reliability of the SUS (.90) was consistent with previous estimates. The EMO and its subscales were also quite reliable, with the estimates of reliability for the various EMO scales ranging from .86 to .96. Regression analysis using SUS, EMO, and Effort as predictors revealed different key drivers for the outcome metrics of Satisfaction and Likelihood-to-Recommend. The key recommendations are to include the EMO as part of the battery of poststudy standardized questionnaires, along with the SUS (or similar questionnaire), but to be cautious in reporting SUS subscales such as Usable and Learnable.