Catalytic reduction of 2,4‐dinitrophenylhydrazine by cuttlebone supported Pd NPs prepared using Conium maculatum leaf extract

A facile and green process to synthesise cuttlebone supported palladium nanoparticles (Pd NPs/cuttlebone) is reported using Conium maculatum leaf extract and in the absence of chemical solvents and hazardous materials. The antioxidant content of the C. maculatum leaf extract played a significant role in converting Pd²⁺ ions to Pd NPs. Various techniques were used for the characterisation of the Pd NPs/cuttlebone such as field‐emission scanning electron microscopy, X‐ray diffraction, energy dispersive X‐ray spectroscopy, Fourier transform infrared and ultraviolet–visible spectroscopy. This Pd NPs/cuttlebone showed excellent catalytic activity in the reduction of 2,4‐dinitrophenylhydrazine to 2,4‐diaminophenylhydrazine by sodium borohydride as the source of hydrogen at ambient condition. The catalyst could be separated and recycled up to five cycles with no loss of its activity.Inspec keywords: catalysis, catalysts, chemical engineering, palladium, nanoparticles, field emission electron microscopy, scanning electron microscopy, X‐ray diffraction, X‐ray chemical analysis, sodium compounds, ultraviolet spectroscopy, visible spectroscopyOther keywords: catalytic reduction, 2,4‐dinitrophenylhydrazine, cuttlebone, Conium maculatum leaf extract, green process, palladium nanoparticles, antioxidant content, field‐emission scanning electron microscopy, X‐ray diffraction, energy dispersive X‐ray spectroscopy, Fourier transform infrared, ultraviolet–visible spectroscopy, 2,4‐diaminophenylhydrazine, sodium borohydride     

Multi expression programming: a new approach to formulation of soil classification

This paper presents an alternative approach to formulation of soil classification by means of a promising variant of genetic programming (GP), namely multi expression programming (MEP). Properties of soil, namely plastic limit, liquid limit, color of soil, percentages of gravel, sand, and fine-grained particles are used as input variables to predict the classification of soils. The models are developed using a reliable database obtained from the previously published literature. The results demonstrate that the MEP-based formulas are able to predict the target values to high degree of accuracy. The MEP-based formulation results are found to be more accurate compared with numerical and analytical results obtained by other researchers.     

Aeroelastic tailoring using lamination parameters

The aim of the present work is to passively reduce the induced drag of the rear wing of a Formula One car at high velocity through aeroelastic tailoring. The angle-of-attack of the rear wing is fixed and is determined by the required downforce needed to get around a turn. As a result, at higher velocity, the amount of downforce and related induced drag increases. The maximum speed on a straight part is thus reduced due to the increase in induced drag. A fibre reinforced composite torsion box with extension-shear coupled upper and lower skins is used leading to bending-torsion coupling. Three-dimensional static aeroelastic analysis is performed loosely coupling the Finite Element code Nastran and the Computational Fluid Dynamics panel code VSAERO using ModelCenter. A wing representative of Formula One rear wings is optimised for minimum induced drag using a response surface methodology. Results indicate that a substantial induced drag reduction is achievable while maintaining the desired downforce during low speed turns.     

Nadir compromise programming: A model for optimization of multi-objective portfolio problem

In problem of portfolio selection, financial Decision Makers (DMs) explain objectives and investment purposes in the frame of multi-objective mathematic problems which are more consistent with decision making realities. At present, various methods have introduced to optimize such problems. One of the optimization methods is the Compromise Programming (CP) method. Considering increasing importance of investment in financial portfolios, we propose a new method, called Nadir Compromising Programming (NCP) by expanding a CP-based method for optimization of multi-objective problems. In order to illustrate NCP performance and operational capability, we implement a case study by selecting a portfolio with 35 stock indices of Iran stock market. Results of comparing the CP method and proposed method under the same conditions indicate that NCP method results are more consistent with DM purposes.     

FPGA implementation and performance evaluation of a high throughput crypto coprocessor

This paper describes the FPGA implementation of FastCrypto, which extends a general-purpose processor with a crypto coprocessor for encrypting/decrypting data. Moreover, it studies the trade-offs between FastCrypto performance and design parameters, including the number of stages per round, the number of parallel Advance Encryption Standard (AES) pipelines, and the size of the queues. Besides, it shows the effect of memory latency on the FastCrypto performance. FastCrypto is implemented with VHDL programming language on Xilinx Virtex V FPGA. A throughput of 222 Gb/s at 444 MHz can be achieved on four parallel AES pipelines. To reduce the power consumption, the frequency of four parallel AES pipelines is reduced to 100 MHz while the other components are running at 400 MHz. In this case, our results show a FastCrypto performance of 61.725 bits per clock cycle (b/cc) when 128-bit single-port L2 cache memory is used. However, increasing the memory bus width to 256-bit or using 128-bit dual-port memory, improves the performance to 112.5 b/cc (45 Gb/s at 400 MHz), which represents 88% of the ideal performance (128 b/cc).     

A new homotopy perturbation method for solving systems of partial differential equations

In this paper, a new homotopy perturbation method (NHPM) is introduced for obtaining solutions of systems of non-linear partial differential equations. Theoretical considerations are discussed. To illustrate the capability and reliability of the method three examples are provided. Comparison of the results of applying NHPM with those of applying HPM reveal the effectiveness and convenience of the new technique.     

Relaxed constraints support vector machines for noisy data

Real-world data collected for computer-based applications are frequently impure. Differentiation of outliers and noisy data from normal ones is a major task in data mining applications. On the other hand, elimination of noisy and outlier data from training samples of a dataset may lead to over-fitting or information loss. A fuzzy support vector machine (FSVM) provides an effective means to deal with this problem. It reduces the effect of the noisy data and outliers by using a fuzzy membership functions. In this paper, a new formation for SVMs is introduced that considers importance degrees for training samples. The constraints of the SVM are converted to fuzzy inequalities. The proposed method, RSVM, shows better efficiency in the classification of data in different domains. Especially, using the proposed RSVM for multi-class classification of arrhythmia disease is presented at the end of this paper as a practical case study to show the effectiveness of the proposed system.     

Energy Consumption Optimization for Mobile Robots Motion Using Predictive Control

Operation of mobile robots in off-road environment requires the attention to the torque saturation problem that occurs in the wheels DC motors while climbing hills. In the present work, off-road conditions are utilized to benefit while avoiding torque saturation. Energy optimization algorithm using predictive control is implemented on a two-DC motor-driven wheels mobile robot while crossing a ditch. The predictive control algorithm is simulated and compared with the PID control and the open-loop control. Predictive control showed more capability to avoid torque saturation and noticeable reduction in the energy consumption. Furthermore, using the wheels motors armature current instead of the supply voltage as control variable in the predictive control showed more efficient speed control. Simulation results showed that in case of known ditch dimensions ahead of time, the developed algorithm is feasible. Experimental examination of the developed energy optimization algorithm is presented. The experimental results showed a good agreement with the simulation results. The effects of the road slope and the prediction horizon length on the consumed energy are evaluated. The analytical study showed that the energy consumption is reduced by increasing the prediction horizon until it reaches a limit at which no more energy reduction is obtained. This limit is proportional to the width of the ditch in front of the mobile robot. Curve fitting is applied to the obtained results to address further the effect of the parameters on the energy consumption.     

Adaptive synchronization between two non-identical BAM neural networks with unknown parameters and time-varying delays

International Journal of Control, Automation and Systems - In this paper, the synchronization of two non-identical bidirectional associative memory (BAM) neural networks with unknown parameters and...     

Processing Optimal Sequenced Route Queries Using Voronoi Diagrams

The Optimal Sequenced Route (OSR) query strives to find a route of minimum length starting from a given source location and passing through a number of typed locations in a specific sequence imposed on the types of the locations. In this paper, we propose a pre-computation approach to OSR query in both vector and metric spaces. We exploit the geometric properties of the solution space and theoretically prove its relation to additively weighted Voronoi diagrams. Our approach recursively accesses these diagrams to incrementally build the OSR. Introducing the analogous diagrams for the space of road networks, we show that our approach is also efficiently applicable to this metric space. Our experimental results verify that our pre-computation approach outperforms the previous index-based approaches in terms of query response time. This research has been funded in part by NSF grants EEC-9529152 (IMSC ERC), IIS-0238560 (PECASE), IIS-0324955 (ITR), IIS-0534761, and unrestricted cash gifts from Google and Microsoft. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the NSF.

---