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71.
Crystallization‐Induced Emission Enhancement of a Deep‐Blue Luminescence Material with Tunable Mechano‐ and Thermochromism 下载免费PDF全文
Zhen Wu Shenzhong Mo Lina Tan Bing Fang Zhiqiang Su Yantu Zhang Meizhen Yin 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(40)
Organic luminescent materials with the ability to reversibly switch the luminescence when subjected to external stimuli have attracted considerable interest in recent years. However, the examples of luminescent materials that exhibit multiresponsive properties are rarely reported. In this work, a new stimuli‐responsive dye P1 is designed and synthesized with two identical chromophores of naphthalimide, one at each side of an amidoamine‐based spacer. This amide‐rich molecule offers many possibilities for forming intra‐ and intermolecular hydrogen bond interactions. Particularly, P1 has an intrinsic property of cocrystallizing with methanol. Compared with the pristine P1 sample, the as‐prepared two‐component cocrystalline material displays an exceptive deep‐blue emission, which is extremely rare among naphthalimide‐based molecules in the solid state. Furthermore, the target material exhibits an obvious mechanochromic fluorescent behavior and a large spectral shift under force stimuli. On the other hand, the cocrystalline material shows an unusual “turn off” thermochromic luminescence accompanied by solvent evaporation. Moreover, using external stimuli to reversibly manipulate fluorescent quantum yields is rarely reported to date. The results demonstrate the feasibility of a new design strategy for solid‐state luminescence switching materials: the incorporation of solvents into organic compounds by cocrystallization to obtain a crystalline state luminescence system. 相似文献
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以企业兼并为主要方式的企业资产重组是当前我团经济体制改革的热点之一。本文从实际出发,阐明企业兼并对我国经济建设的意义,分析近十多年来我国企业兼并的基本特征及存在的问题,并提出相关的解决问题的对策建议。 相似文献
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运用量子化学微扰理论MP2方法,采用6-311++G(d,p)基组,对吡咯与双卤分子XY(XY=ClF,BrF,BrCl)形成的卤键复合物进行构型全优化,得到各分子的稳定几何构型和分子间相互作用能.利用电子密度拓扑分析方法分析卤键复合物的拓扑性质,探讨了该类分子间卤键的作用本质.证明吡咯与双卤分子间存在Y-X...N和Y-X...π2类相互作用,且后者比前者强.复合物中的卤键介于共价键与离子键之间,偏于静电作用成分为主.形成卤键后,2种类型卤键复合物中的电子受体X-Y键伸长,其振动频率发生红移.用电子密度拓扑分析程序GTA-2000,将π型卤键体系中π电子与σ电子分开处理,绘制出π电子密度等值线图和Laplacian量等值线图,更加形象地说明π型卤键的存在和作用本质.利用AIM程序计算了卤键复合物中各原子电子积分的性质,原子积分性质随着卤键形成发生了改变. 相似文献
74.
Vo-Gia Loc Ig Mo Koo Duc Trong Tran Sangdoek Park Hyungpil Moon Hyouk Ryeol ChoiAuthor vitae 《Robotics and Autonomous Systems》2011,59(12):1036-1048
This paper presents a study on improving the traversability of a quadruped walking robot in 3D rough terrains. The key idea is to exploit body movement of the robot. The position and orientation of the robot are systematically adjusted and the possibility of finding a valid foothold for the next swing is maximized, which makes the robot have more chances to overcome the rough terrains. In addition, a foothold search algorithm that provides the valid foothold while maintaining a high traversability of the robot, is investigated and a gait selection algorithm is developed to help the robot avoid deadlock situations. To explain the algorithms, new concepts such as reachable area, stable area, potential search direction, and complementary kinematic margin are introduced, and the effectiveness of the algorithms is validated via simulations and experiments. 相似文献
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A robust scheduling method is proposed to solve uncertain scheduling problems. An uncertain scheduling problem is modeled by a set of workflow models, and then a scheduling scheme (solution) of the problem can be evaluated by workflow simulations executed with the workflow models in the set. A multi-objective immune algorithm is presented to find Pareto optimal robust scheduling schemes that have good performance for each model in the set. The two optimization objectives for scheduling schemes are the indices of the optimality and robustness of the scheduling results. An antibody represents a resource allocation scheme, and the methods of antibody coding and decoding are designed to deal with resource conflicts during workflow simulations. Experimental tests show that the proposed method can generate a robust scheduling scheme that is insensitive to uncertain scheduling environments. 相似文献
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51.引言 在许多重要研究领域中,数值模拟相当复杂,数值模拟的结果依赖于数值方法的选取,计算网络的质量,边界处理等,其复杂性表现在物理特性、数学模型、计算区域不规则的几何形状等方面.当计算区域各部分的物理特性不同而且差异较大时,比如多种物质的流体运动流场中各个部分变化程度不均匀,有些部分变化非常平缓,有些部分变化极其剧烈;或者,当计算区域极其不规则时,比如空气动力学中的进气道系统的流场计算,绕复杂形状流场的数值分析等.若在计算区域上作整体计算,不仅难以准确地描述流场变化,而且受到计算机运算速度、… 相似文献