Grounded theorizing for electronically mediated social contexts

Electronically mediated social contexts (EMSCs), in which interactions and activities are largely or completely computer-mediated, have become important settings for investigation by Information Systems (IS) scholars. Owing to the relative novelty and originality of EMSCs, IS researchers often lack existing theories to make sense of the processes that emerge in them. Therefore, many IS researchers have relied upon grounded theory in order to develop new theory based on empirical observations from EMSCs. This article reviews a selected set of papers concerned with grounded IS research on EMSCs. It examines how the authors of these papers handled the characteristics of EMSCs and, in particular, addresses the topics of data collection, data analysis, and theory building. The paper also draws implications and recommendations for grounded researchers interested in investigating these original and fascinating environments in their future work. For example, it calls for grounded researchers on EMSCs to reflect upon the characteristics of their domains of inquiry, to respect the logic of discovery of grounded methods, and to articulate more clearly their theoretical ambitions along the induction/abduction continuum. The paper closes by suggesting promising areas for future grounded research on EMSCs, including taking advantage of the potential for combining qualitative and quantitative analytical methods.     

Microporous polyacrylate matrix containing hydrogen bonded nanotubular assemblies

We report the straightforward photo-polymerization of polyacrylate films containing bis-urea based self-assembled nanotubes. The obtained materials are characterized by gas adsorption measurements, 129Xe NMR spectroscopy and WAXS. The presence of the bis-ureas is shown by butane adsorption (at 273 K and ambient pressure) to be responsible for the formation of a significant microporosity. This porosity is however not detected by the classical argon adsorption procedure (at 77 K and low pressure). This effect is attributed to the contraction of the material at low temperature and pressure, and may be of general concern for other organic porous materials. One of the potential advantages of the present materials is that the porosity results from the self-assembled nanotubes and should therefore be independent of the matrix mechanical properties. It should in particular be possible to adjust the flexibility of the matrix by changing the monomer composition.     

Managed Agreement: Generalizing two fundamental distributed agreement problems

This paper presents a family of agreement problems called Managed Agreement, which is parameterized by the number of aristocrat nodes in the system; NBAC is a special case of this family when all nodes are aristocrats while Consensus is a special case of this family when there are no aristocrats. The paper also presents a parameterized family of failure detectors F(A) such that F(A) is the weakest failure detector class that enables solving Managed Agreement with a set A of aristocrats in an asynchronous environment.     

Exact boundary controllability of the Korteweg?de Vries equation around a non-trivial stationary solution

The exact boundary controllability of the non-linear Korteweg-de Vries equation on bounded domains is studied. Only the first spatial derivative at the right endpoint is assumed to be controlled. In this case, the exact controllability has been shown by Rosier (1997) when the length L of the domain is not in the set N     

Molecular Recognition of Two 2,4‐syn‐Functionalized (S)‐Glutamate Analogues by the Kainate Receptor GluK3 Ligand Binding Domain

The kainate receptors are the least studied subfamily of ionotropic glutamate receptors. These receptors are thought to have a neuromodulatory role and have been associated with a variety of disorders in the central nervous system. This makes kainate receptors interesting potential drug targets. Today, structures of the ligand binding domain (LBD) of the kainate receptor GluK3 are only known in complex with the endogenous agonist glutamate, the natural product kainate, and two synthetic agonists. Herein we report structures of GluK3 LBD in complex with two 2,4‐syn‐functionalized (S)‐glutamate analogues to investigate their structural potential as chemical scaffolds. Similar binding affinities at GluK3 were determined for the 2‐(methylcarbamoyl)ethyl analogue (K_i=4.0 μM ) and the 2‐(methoxycarbonyl)ethyl analogue (K_i=1.7 μM ), in agreement with the similar positioning of the compounds within the binding pocket. As the binding affinity is similar to that of glutamate, this type of Cγ substituent could be used as a scaffold for introduction of even larger substituents reaching into unexplored binding site regions to achieve subtype selectivity.     

Crosslinking of epoxidized natural oils with diepoxy reactive diluents

The different natural oils epoxidized with 3‐chloroperbenzoic acid were crosslinked with diepoxy reactive diluents, bisphenol A propoxylate diglycidyl ether, and 3,4‐epoxycyclohexylmethyl‐3,4‐epoxyclohexane‐carboxylate, using cationic initiator at 60°C and photoinitiators at the room temperature. The insoluble fraction of the polymeric products was 59–90%. The Young modulus of the crosslinked polymer films ranged from 2 to 861 MPa. The 10% weight loss temperatures of the crosslinked polymers estimated by thermogravimetric analysis were in the range from 250 to 420°C. The water vapor transmission rate of the crosslinked biopolymer films ranged from 6 to 49 g/m²/24 h. Biochemical oxygen demand and biodegradation in soil of the crosslinked polymers were studied. The crosslinked polymers showed higher biodegradation rate than cellulose, starch, and polyvinylalcohol. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Simple Chiral Diaminobinaphthyl Dilithium Salts for Intramolecular Catalytic Asymmetric Hydroamination of Amino‐1,3‐dienes

Simple and easily accessible chiral lithium amide salts are reported as efficient (pre)catalysts for the diastereo‐ [up to (E:Z)=92:8] and enantioselective [up to 72% ee (E)] hydroamination/cyclisation of conjugated primary aminodienes. These chiral lithium salts are straightforwardly prepared by in situ combination of an N‐substituted (R)‐(+)‐1,1′‐binaphthyl‐2,2′‐diamine ligand and a commercial methyllithium solution. Information on the solid‐state structure of these salts was obtained by X‐ray analysis of a single crystal.     

Use of polarimetric lidar for the study of oriented ice plates in clouds

A polarization lidar operating at 532 nm was converted into an automatic, polarimetric lidar capable of measuring the entire Stokes vector of backscattered light and its derived quantities. Among these quantities, circular and linear depolarizations were studied as tools for investigating the presence of anisotropic scattering media. Isotropic scatterers show a simple relationship between linear and circular depolarization, a relation that we confirm theoretically and experimentally. Deviations from this relation, which are possible in the presence of anisotropic scatterers such as horizontally oriented ice plates when they are observed with a slant lidar, were studied both numerically and experimentally.     

High-performance deep-ultraviolet optics for free-electron lasers

Working with wavelengths shorter than the deep ultraviolet involves the development of dedicated optics for free-electron lasers with devoted coating techniques and characterizations. High-performance deep-ultraviolet optics are specially developed to create low-loss, high-reflectivity dielectric mirrors with long lifetimes in harsh synchrotron radiation environments. In February 2001, lasing at 189.7 nm, the shortest wavelength obtained so far with free-electron-laser oscillators, was obtained at the European Free-electron-laser project at ELETTRA Synchrotron Light Laboratory, Trieste, Italy. In July 2001, 330-mW extracted power at 250 nm was measured with optimized transmission mirrors. Research and development of coatings correlated to lasing performance are reported.