PEG20000中试放大的工艺研究

在一定温度和催化剂作用下 ,分别利用本体聚合和溶剂聚合的方法 ,在 1L、10 0L不锈钢高压反应釜中合成了相对分子质量为 2 0 0 0 0的聚乙二醇 ,并讨论了聚合反应机理 ,研究了催化剂用量、反应温度、反应时间对聚合反应的影响。经过红外、核磁共振、凝胶色谱、化学分析等方法对产物进行了表征。     

钢缆带式输送机驱动轮的更换方法

钢缆带式输送机在长期使用过程中 ,它的驱动轮轴承以及齿轮联轴器都要磨损 ,最终导致磨损超标。为了保证设备运行安全 ,必须解决它的更换问题。针对这一问题 ,介绍了运用松驰牵引钢丝绳的方法 ,实现了不截断牵引钢丝绳进行驱动轮的整体更换 ,通过对平煤集团一矿 4个驱动轮的更换 ,证明这种方法简便易行 ,安全可靠。     

High-resolution electron microscopy of the twinning and intergrowth in Ca4Al6SO16 and Ca3SrAl6SO16

The microstructures of unhydrated calcium aluminosulphate Ca₄Al₆SO₁₆ and Ca₃SrAl₆SO₁₆ have been studied by high-resolution electron microscopy (HREM). The results showed that twinning and twinned slabs could be introduced taking the [1 1 2] direction as the twin axis so that it seems to be coincident with the law of twinning formed in body-centred cubic structures. A previously reported superlattice with a repeat period twice that of the fundamental structure along the 〈1 1 0〉 direction has also been found in both matrix and twin variants. The close intergrowth of Ca₃SrAl₆SO₁₆ and another phase, possibly Sr₃Al₂O₆ existing as an inclusion between these two twin variants, was determined and clearly revealed by electron diffraction and HREM images. The coherent interphase boundaries and orientation relationship between them can also be deduced.     

最忆湘西情与梦率真至诚是刘虹--为"湘酒鬼"新任董事长刘虹写真

刘虹，湘西之子，亿万富翁。在“湘酒鬼”“迷途”之际，以3．5亿元民营资本入主“湘酒鬼”，担负起“扭转乾坤”的使命，可谓“玩家”大手笔。然“醉翁”之意本在酒、在振兴湘酒、振兴湘西。上任伊始，战略目标既定：一要制订发展远景规划，二要培养高素质的营销管理队伍，三要制订有“酒鬼”发展特色的标准化管理体系。以“统一文化观念，重塑企业精神”运作“湘酒鬼”。以“尊重科学、尊重知识、培养人才、合理用人、严格管理”发展“湘酒鬼”。(小雨)     

Cooling and Solidification of Melted Drops in an Immiscible Cooling Medium

The cooling and solidification of melted drops during their movement in an immiscible cooling medium is widely employed for granulation in the chemical industry, and a study of these processes to provides a basis for the design of the granulation tower height and the temperature of the cooling medium is reported. A physical model of the cooling and solidification of the drop is established and the numerical calculation is performed. The influences of the key factors in the solidification, i.e., Bi number, drop diameter, temperature of the cooling medium, etc. are presented. The cooling and solidification during wax granulation in a water‐cooling tower and during urea granulation in an air‐cooling tower (spraying tower) are described in detail. Characteristics of the solidification and temperature distribution within the particle at different times are shown. The model and calculations can be used for structure design of the granulation tower and optimization of the operation parameters.     

确定最佳起爆点的磁探测仪研究

雷的作战效果取决于雷体起爆时距离目标的远近程度,为了改善现存部分库存雷没有确定最佳起爆点这一现状,在此设计了确定最佳起爆点的磁探测仪.本探测仪采用磁阻传感器探测目标,目标信号经过后续的放大电路,微分电路处理,确定最佳起爆点,并在最佳起爆点时输出触发信号,引爆雷体.本设计还为以后智能雷的发展提供了一些研究思路.     

Interfacial strength and chemistry of additive-free silicon nitride ceramics brazed with aluminium

Two kinds of additive-free silicon nitride ceramics were brazed with aluminium; one was with as-ground faying surfaces and the other was with faying surfaces heat-treated at 1073K for 1.8 ksec in air. The heat-treatment of the silicon nitride ceramics formed a silicon oxynitride layer on the faying surfaces and increased the brazing strength of the joints. A silica-alumina non-crystalline layer and a β′-sialon layer were formed successively from the aluminium side at the interface of the joints. The heat-treatment which made the former layer thicker is a necessary process in making reliable, strong brazed joints.     

Theoretical analysis of RAIM in the occurrence of simultaneous two-satellite faults

Most algorithms on receiver autonomous integrity monitoring (RAIM) are under the assumption of a single-satellite fault, because there is an extremely small probability that significant simultaneous multiple-satellite faults may occur. However, after the implementation of the Galileo system in a few years, there will be more satellites in view for the user to utilise together with GPS satellites, and a combination of them will bring better performance for RAIM. On the other hand, with the help of wide area augmentation system and the use of dual-frequency operation, pseudo-range errors will be reduced greatly. Thus, tighter alert limits are required for RAIM, and formerly `small' errors should not be neglected. All of those factors make it necessary to consider simultaneous multiple-satellite faults. A detailed theoretical analysis of RAIM under the condition of two-satellite faults for both vertical and horizontal directions is presented. The characteristic/max slopes for every pair of satellites are then deduced in order to calculate the tighter vertical/horizontal protection level for RAIM     

On structural and high temperature electrochemical properties of ZrO2 thin film coating on Zr metal produced by carbonate melt

Melt of NaCO₃ can favor oxidation of Zr to form ZrO₂ thin film on Zr surface, which is used to make Zr/ZrO₂ oxidation/reduction electrode of pH sensor for testing elevated temperature aqueous solutions. Using SEM, EPMA, XPS, EXAFS and HRTEM, we found that ZrO₂ film is tightness and solid with 20 μm thickness composed by nanometer-sized monoclinic crystals. Zr/ZrO₂ interface is characterized of zoning structure according to topography and chemical composition in five zones: oxygen-rich ZrO₂, ZrO₂, oxygen-rich Zr metal, oxygen-bearing Zr and Zr from outmost to center. Melt oxidation process of Zr involved oxidation time, air and temperature. The air is important effect on structural and electrochemical properties of ZrO₂ thin film for making elevate temperature electrochemical sensor. If oxygen air largely presented in carbonate melting process, ZrO₂ thin film is not tightness and not for oxidation/reduction electrode.     

Probing the thermal decomposition process of layered double hydroxides through in situ <Superscript>57</Superscript>Fe Mössbauer and in situ X-ray diffraction experiments

The thermal decomposition properties of Mg–Fe hydrotalcites were studied through in situ ⁵⁷Fe Mössbauer spectroscopy and in situ X-ray diffraction. Abrupt changes in the quadrupolar splitting measured in the Mössbauer spectra revealed a phase transition from the starting lamellar structure to a new crystalline arrangement. By analyzing the Mössbauer parameters we show that the material is highly disordered in the 300–400 °C temperature range. This hypothesis is confirmed by the X-ray results whose diffractograms indicated the collapse of the lamellar structure and the formation of a solid solution.