压力容器标准对不等厚板材对接要求的分析

欧盟、美国和我国压力容器标准对不等厚板材对接时均有削薄要求,通过有限元方法计算不同条件下连接时的应力分布,认为不等厚板材对接连接时,按照EN13445(2002)要求增加直边段,对减小局部应力有一定好处,对提高射线检测灵敏度有利.     

活性炭载体的超声波处理对Pt／C催化剂活性的影响分析

通过对活性炭载体进行不同条件的超声波处理获得了具有不同表面化学性质的载体，使用比表面积（BET）、酸碱滴定等技术手段对载体的物理化学性质进行了表征。将经过超声波处理的活性炭载体制备成Pt／C催化剂，并将催化剂直接用于催化反应，考察了活性炭载体的不同超声波处理条件对Pt／C催化剂性能的影响。实验发现，活性炭载体经过超声波处理后，表面灰分含量、pH值和中孔孔容有较大的变化；使用经过60min超声波处理后中孔孔容较大的活性炭作为载体制备的Pt／C催化剂，在催化加氢反应性能测试中显示了最高的催化活性。在此基础上，就活性炭载体的超声波处理对Pt／C催化剂活性的影响进行了讨论。     

Simple autocorrelation technique based on degree-of-polarization measurement

We demonstrate a simple optical-fiber-based autocorrelator for picosecond short pulses based on degree-of-polarization measurement while tuning the relative delay of the two orthogonal polarization states of the pulse. The pulsewidths of 20-, 40-, and 80-GHz pulse trains and 2-ps pulses generated by a mode-locked laser are measured. The <-10-dBm optical powers are used in the experiment. The measurement results agree well with the measurements using conventional techniques. Compared with conventional autocorrelators, this technique has the advantages of 1) wavelength independent, 2) significant less alignment, and 3) no high power required.     

Correction for photon attenuation in SPECT: analytical framework, average attenuation factors, and a new hybrid approach

We provide a unified framework for the investigation of convergence properties of the iterative algorithms for photon attenuation correction in SPECT, including the iterative Chang method--a commonly used approach in which an average attenuation factor calculated over all projection angles is employed in a pointwise correction scheme. A new average attenuation factor calculated along the projection line is introduced, which can compensate exactly for the attenuation effect in the case of a uniform activity distribution. We propose a new hybrid approach in which we use this new average attenuation factor initially and then shift to the iterative Chang method in later iterations. This hybrid approach was evaluated in a simulation study by use of a computer-generated phantom with both non-uniform activity and non-uniform attenuation distributions. The results demonstrate that this hybrid approach improves the convergence speed of the iterative Chang method and produces reconstructed images of high quality.     

碱土金属氧化物催化氧化异丙苯反应研究

考察了碱土金属氧化物CaO、MgO和SrO在催化氧化异丙苯合成过氧化氢异丙苯 (CHP)反应中的性能。3种催化剂的活性顺序为 :CaO >MgO >SrO。采用Hammett指示剂分别表征了碱土金属氧化物的碱强度。碱强度H-=15 0～ 18 4的碱性中心有利于异丙苯过氧化合成CHP反应。采用红外光谱分析了异丙苯在MgO、CaO催化剂表面的吸附态。异丙苯通过异丙基叔碳原子上的氢原子与CaO催化剂表面碱中心发生化学吸附 ,弱化了异丙基叔碳原子上的C—H键 ,从而有利于催化异丙苯氧化合成CHP的反应。MgO与异丙苯的异丙基叔碳上的氢原子的相互作用弱于CaO与异丙苯的异丙基叔碳上的氢原子的相互作用 ,使MgO催化异丙苯氧化的反应活性低于CaO催化异丙苯氧化的反应活性     

用EVA复配物改善高含蜡原油低温流动性的研究

本文研究了采用化学处理剂改善南海高含蜡原油的低温流动性,结果表明,添加150ppm EVA复合化学处理剂,原油低温流动性得到明显改善,凝固点由32℃降至11.5℃,表观粘度降低86.9%,1;℃时屈服值降低98%。同时考察了添加温度,冷却速度以及化学处理剂的化学组成和结构对改善原油低温流动性的影响。根据南海高含蜡原油中蜡的组成和正构烷烃的碳数分布及其对不同结构的EVA的感受性,讨论了化学处理剂改善原油低温流动性的机理,指出,EVA中乙烯链长与原油中正构烷烃链长相近时才能形成共晶,起到改变原油中蜡的结晶形态的作用,达到降凝减粘效果。     

Glass-ceramics of barium strontium titanate for high energy density capacitors

Barium strontium titanate glass-ceramics were successfully produced with one major crystalline phase when Al₂O₃ was added to the melt. A dielectric constant of 1000 and a breakdown strength of 800 kV/cm was achieved; however the energy density was only measured to be 0.3–0.9 J/cm³. These energy density values were lower than anticipated due to the presence of dendrites and pores in the microstructure. Using BaF₂ as a refining agent improved the microstructure and doubled the energy density for BST 80/20 samples. However, no refining agent reduced the increasing amount of hysteresis that developed with increasing applied electric field. This phenomenon is believed to be due to interfacial polarization.     

飞行器火工装置的冲击隔离结构方案实验研究

飞行器由于采用了××炸药索作为级间分离及壁板减重的火工装置，当火工品引炸时，对周围的仪器支架和脱拔插头产生高达３００００ｇ的冲击加速度。为保护仪器支架和脱拔插头，本文，总结了多种隔冲击结构方案的试验结果，选出了一种最佳方案，即二级硅橡胶缓冲器与阻尼复合结构的结合形式。该方案可使冲击加速度衰减至１６０ｇ以下。测的是周向过载。４结语粘弹阻尼复合结构用于高频响、高过载的冲击衰减系统尚是一种新的尝试。由于本课题所设计的缓冲支架采用了多级隔冲方式，冲击载荷传递的环节多，而且是三维冲击响应，载荷的波形复杂，不确定因素多，无法采用理论分析的方法进行研究。虽然如此，缓冲器的隔冲特性以及粘弹阻尼复合结构的减振性能还是可以估算的。这方面的理论问题有待于进一步研究。从试验角度而言，本次试验已解决了飞行器的仪器盒及脱拔插头的隔冲击振动问题，证明所设计的隔冲击支架满足使用要求。通过对不同支承界面联接方式的研究，选出了较佳的支承结构形式，即文中的标准状态。该结构形式隔冲击性能好，衰减倍数大，安装和更换方便，防热性能好。试验数据表明，仪器架的衰减倍数大于４００倍，脱拔插头支架大于２９０倍；在最大过载约３００００ｇ，最大响应频率约２２．４