Boosted hydrogen evolution activity from Sr doped ZnO/CNTs nanocomposite as visible light driven photocatalyst

CNTs were decorated onto Sr doped ZnO nanoparticles to construct an efficient photocatalyst via a facile sol-gel method. The as-fabricated Sr doped ZnO/CNTs with recyclability exhibits Sr and CNTs content dependent hydrogen evolution activit under visible light illumination. The Sr doped ZnO/CNTs photocatalyst shows the highest hydrogen evolution rate of 2732.2 μmolh^?1g^?1, which is 33.7 and 2.83 times higher than pure ZnO and Sr doped ZnO photocatalysts, respectively. The improved hydrogen evolution activity of Sr doped ZnO/CNTs is primarily assigned to high surface area, Sr doping and construction of heterojunction, which can extend the light absorption, decrease the optical band gap and improve the charge separation. Moreover, the underlying photocatalytic mechanism is proposed on the basis of Mott-Schottky study and explains the interfacial charge transfer process from ZnO to CNTs and Sr. This work open new strategies to synthesize CNTs based nanocomposite for hydrogen evolution.     

Perovskite SrFe1-xTixO3-δ (x < = 0.1) cathode for low temperature solid oxide fuel cell

Stable and compatible cathode materials are a key factor for realizing the low-temperature (LT, ≤600?°C) operation and practical implementations of solid oxide fuel cells (SOFCs). In this study, perovskite oxides SrFe_1-xTi_xO_3-δ (x?< = 0.1), with various ratios of Ti doping, are prepared by a sol-gel method for cathode material for LT-SOFCs. The structure, morphology and thermo-gravimetric characteristics of the resultant SFT powders are investigated. It is found that the Ti is successfully doped into SrFeO_3-δ to form a single phase cubic perovskite structure and crystal structure of SFT shows better stability than SrFeO_3-δ. The dc electrical conductivity and electrochemical properties of SFT are measured and analysed by four-probe and electrochemical impedance spectra (EIS) measurements, respectively. The obtained SFT exhibits a very low polarization resistance (R_p), .01 Ωcm² at 600?C. The SFT powders using as cathode in fuel cell devices, exhibit maximum power density of 551?mW?cm^?2 with open circuit voltage (OCV) of 1.15?V at 600?C. The good performance of the SFT cathode indicates a high rate of oxygen diffusion through the material at cathode. By enabling operation at low temperatures, SFT cathodes may result in a practical implementation of SOFCs.     

Silicon Mitigates Drought Stress in Wheat (Triticum aestivum L.) Through Improving Photosynthetic Pigments,Biochemical and Yield Characters

Silicon - Feeling prone to stress differs with plant production stage, water scarcity near commencement of grain filling phase has a significant reduced grain yield through fewer endosperm and sink...     

A critical review on self-lubricating ceramic-composite cutting tools

Self-lubricating ceramic cutting tools have recently gained considerable attention as the tool wear in cutting hard-to-cut materials greatly affects the production cost, integrity of the machined surface, and productivity. In an attempt to compile the progress made in this important research area, a critical review has been performed covering a range of aspects. These include the current research trends and the need for self-lubricating ceramic tools, identification of prospective high-temperature solid lubricants and their limitations followed by a presentation of recent experimental and numerical work conducted related to self-lubricant ceramic cutting tools. Various lubrication mechanisms involved in the cutting process are also examined to identify general tribological response under various tribo-systems, which is expected to provide useful directions for the researchers and cutting industry. The current and emerging synthesis techniques are discussed in detail and compared with respect to ceramic cutting tools. Finally, some research gaps and future directions are suggested that could lead to optimum design and development of innovative self-lubricating ceramic tools.     

Design of backtracking search heuristics for parameter estimation of power signals

Neural Computing and Applications - This study presents a novel implementation of evolutionary heuristics through backtracking search optimization algorithm (BSA) for accurate, efficient and robust...     

Integrative and multi-disciplinary framework for the 3D rehabilitation of large mandibular defects

The International Journal of Advanced Manufacturing Technology - The restoration of mandibular defects, especially large deformities is regarded as the most challenging surgical procedure owing to...     

Modeling and operation optimization of RE integrated microgrids considering economic,energy, and environmental aspects

Microgrids provide promising solution for integration of renewable energy sources in the electrical grid. To exploit the key benefits, achieving the economical operation of renewable aided microgrids has become necessary and is a challenging task. This paper presents an efficient optimization model to minimize the operational cost of a solar integrated microgrid. We formulate a joint optimization mixed integer problem for appropriate modeling of the system under various practical constraints. An efficient solution is obtained with a distributed approach such that the original problem is solved in two stages. Dual decomposition approach is adopted for cost, emissions, and solar share optimization. Lagrange relaxation, Lambda iteration method, and binary integer programming are employed to obtain the joint optimization solution. Finally, the performance of the proposed model is validated through simulations that show that an overall cost reduction of 4.2070e+04 $ and emission reduction of 7.2001e+03 kg are achieved with the proposed model.     

Heat transfer analysis for particle–fluid suspension thermomagnetohydrodynamic peristaltic flow with Darcy–Forchheimer medium

This theoretical analysis explores the effect of heat and mass transfer on particle–fluid suspension for the Rabinowitsch fluid model with the stiffness and dynamic damping effects through Darcy–Brinkman–Forchheimer porous medium. In this study, we also incorporate slip and transverse magnetic field effects. Using low Reynolds number, to neglect inertial forces and to keep the pressure constant during the flow, channel height is used largely as compared with the ratio of length of the wave. A numerical technique is used to solve flow governing system of differential equations. Particular attention is paid to viscous damping force parameter, stiffness parameter, and rigidity parameter; also, the numerical data for thermal profile, momentum, and concentration distribution are presented graphically. Outcomes are deliberated in detail for different fluid models (thinning, thickening, and viscous models). It is found that velocity profile increases for greater values of viscous damping effect and stiffness and rigidity parameter for shear thinning, but conflicting comportment is showed for thickening nature model. Viscous dissipation effects increases the thermal profile for all cases of fluid models. The scope of the present article is valuable in explaining the blood transport dynamics in small vessels while considering the important wall features with chemical reaction characteristics. The current analysis has extensive applications in biomedical engineering field, that is, peristaltic pumps.