甘油三乙酸酯超临界酯交换反应及其动力学研究

研究了在超临界条件下甘油三乙酸酯与甲醇或乙醇的酯交换反应,分别考察了超临界状态下醇油摩尔比和温度对反应的影响。实验结果表明,甲醇或乙醇与甘油三乙酸酯的摩尔比为14、反应温度为350℃、反应时间为20m in时,乙酸甲酯或乙酸乙酯的收率分别达100%和60%。对超临界状态下动力学的研究结果表明,甘油三乙酸酯与甲醇或乙醇的酯交换反应为拟一级反应,在相同的反应条件下,采用甲醇时酯交换反应速率比用乙醇时快,相应的甘油三乙酸酯的转化率也高;甘油三乙酸酯在超临界甲醇或乙醇中酯交换反应的表观活化能分别为58.7 kJ/mol和75.1 kJ/mol,甘油三乙酸酯与甲醇酯交换反应的活化能低于与乙醇酯交换反应的活化能,表明碳链短的醇更易进行酯交换反应。     

WASP6水质模型在渭河流域水环境容量解析中的应用

将WASP6水质模型应用于渭河流域陕西片,分析流域水环境的污染现状,并采用模型试错法模拟计算渭河陕西段水环境容量,并对比分析节水增流前后水质变化,根据分析结果提出节水增流减污的水污染控制方案,为渭河的污染治理提供依据。     

含缺陷压力管系断裂失效风险分析系统（Ⅲ）——在检修和维护中的应用

针对石油工业管道上可能存在的各种缺陷类型 ,充分考虑缺陷尺寸、工况载荷、断裂韧度和机械强度等参数的不确定性 ,应用含缺陷压力管系断裂失效风险分析系统软件 (SAPP - 2 0 0 2 )计算管道系统中每个独立缺陷的安全概率 ,并对整个管道系统进行断裂失效风险分析。另外 ,在制定管道的检修计划时 ,可以利用该系统的结构应力分析模块方便地确定出管道应力高度集中部位 ,有针对性地选择焊缝并进行射线探伤 ,使管道的安全状况分析更准确。还可以利用该系统软件的分析结果制定出旨在降低失效风险的管道结构改进措施 ,达到缓解应力集中或使应力集中区与缺陷所在位置分离 ,优化管道结构 ,以较低成本提高管道完整性水平的目的。对提高企业压力管道管理水平具有推动作用     

稀土改善09CuPTiRE耐候钢耐蚀性的作用机理

应用扫描电镜(SEM)、离子探针(IMA)、X射线光电子能谱(XPS)和交流阻抗法研究含不同稀土耐候钢稀土提高耐大气腐蚀作用机理。结果表明,合适的稀土含量可显著提高钢的耐腐蚀性,稀土能促进Si、Cu和P在内锈层中以Si~(4+)、Cu~+和P~(5+)形态富集,并观察到锈层中的稀土。钢中加入稀土形成了致密连续厚而粘附性好的含硅铜稀土的复合铁锈层,从而提高了抗大气腐蚀性能。     

一种外置式视频同步信号发生器的设计

对随机视频信号的特点进行了研究，提出了采用谱分析提取随机视频信号的同步频率的方法，根据数据传输的要求设计了基于USB接口的外置式视频同步信号发生器并给出了系统的硬件框图和软件流程。系统具有自动分析随机视频信息隐含的同步信号频率，精确产生同步脉冲信号的特点，满足随机视频信号采集和稳定显示的同步要求。同步精度达到300帧内图像漂移小于1个像素。利用该视频同步信号发生器控制非标准图像采集卡实现了计算机辐射的随机视频信号的采集和稳定显示。     

Stability studies on methyl and ethyl fatty acid esters of sunflowerseed oil

Fatty acid esters, high in linoleic acid, were prepared and stored for long-term engine tests. Storage tests with these esters were undertaken to obtain more information on optimal storage requirements and general stability characteristics. Samples were kept at three temperature levels (20 C, 30 C and fluctuating around 50 C) for a 90-day period and were removed at regular intervals for chemical and physical analysis. The influence of air, temperature, light, TBHQ and contact with mild steel was evaluated by comparing the free fatty acid, peroxide, anisidine, ultraviolet absorption, viscosity and induction periods. A statistical model was used to evaluate the data and to reduce the large number of data points to comparable curves. Storage of esters in contact with air, especially at a temperature above 30 C, resulted in significant increases in peroxide, ultraviolet absorption, free fatty acid, viscosity and anisidine values. Exclusion of air retarded oxidation at all temperature levels. A direct relationship between viscosity increases and oxidation parameters was evident. Exposure to light caused a small increase in the oxidation parameters of esters stored at the highest temperature level. Addition of TBHQ prevented oxidation of samples stored under moderate conditions. Under unfavorable storage conditions the anti-oxidant was no longer effective. Mild steel had very little effect on the oxidation parameters. Only the anisidine values of samples stored at the highest temperature level were slightly increased. Methyl esters performed slightly better than ethyl esters during the storage test. The following practical guidelines for storage of fatty acid ester fuels are: (i) airtight containers should be used; (ii) the storage temperature should be <30 C; (iii) mild steel (rust free) containers may be used, and (iv) TBHQ has a beneficial effect on oxidation stability.     

中国硬质合金工业现状及发展趋势

简要总结了中国硬质合金工业所取得的成就及与国外先进水平比较存在的差距,并对国内外硬质合金市场和技术发展趋势进行了分析。     

连轧机用人字轮齿轴断裂失效分析

用宏观断口分析、化学检验、力学性能测定、低倍检查、金相组织及夹杂物评定鉴别、受力分析及强度寿命定量估算的方法，对人字轮被动齿轴端断裂失效原因进行分析，并提出改进措施。     

C2 用于声化学研究的大功率超声系统的研制

根据声化学反应的特殊要求，我们研制了上前用于声化学研究的大功率超声系统，由参数可调节的超声发生器配合不同频率的换能器工作，并用它组合成杯式幅杆结构声化学反应器，解决了有关声化学设备的一些技术问题。为声化学技术从实验室规模向工业应用过渡做了必要的准备。