Investigation on bonding quality of beech wood (Fagus orientalis L.) veneer during high temperature drying and aging

In the present study, the effects of high drying temperature and UV light induced aging on bonding quality of plywood manufactured from untreated and treated veneer layers were investigated. Rotary cut veneers with dimensions of 500 mm×500 mm×2 mm produced from beech (Fagus orientalis Lipsky) log were selected for topochemical, chemical and mechanical analyses. The veneer sheets were oven-dried at 100°C and 180°C after the peeling process. Afterwards, the surfaces were exposed to artificial UV irradiation in an UV chamber for 24 h, 48 h and 72 h representing natural sun irradiation of 2, 4 and 6 months, respectively. Topochemical distribution of lignin and phenolic extractives of the treated and untreated veneers was investigated on a cellular level using UV microspectrophotometry (UMSP). For the chemical characterization of accessory compounds high performance liquid chromatography (HPLC) was used. Furthermore, the shear and bending strengths of plywood manufactured from the treated samples are determined in order to study the bonding quality. The UV microscopic detection shows that after high drying temperature and aging treatment, lignin condensation occurs. With increasing drying temperature and aging duration, more phenolic extractives are situated in parenchyma cells and vessel lumens which can be proved by increased absorbance at 278 nm. The HPLC analysis of the treated tissue showed distinct signals of polymerized compounds such as catechin and 2,6-dimethoxybenzoquinone which are chromophoric compounds in discolored beech wood. The mechanical properties of plywood showed that with increasing drying temperature up to 180°C does not negatively affect shear and bending strengths of samples. After exposure of the veneers to UV irradiation (especially 6 months), decreasing shear and bending strengths of plywood samples can be observed.     

Synthesis and characterization of N‐ and O‐alkylated poly[aniline‐co‐N‐(2‐hydroxyethyl) aniline]

Poly[aniline‐co‐N‐(2‐hydroxyethyl) aniline] was synthesized in an aqueous hydrochloric acid medium with a determined feed ratio by chemical oxidative polymerization. This polymer was used as a functional conducting polymer intermediate because of its side‐group reactivity. To synthesize the alkyl‐substituted copolymer, the initial copolymer was reacted with NaH to obtain the N‐ and O‐anionic copolymer after the reaction with octadecyl bromide to prepare the octadecyl‐substituted polymer. The microstructure of the obtained polymers was characterized by Fourier transform infrared spectroscopy, ¹H‐NMR, and X‐ray diffraction. The thermal behavior of the polymers was investigated by thermogravimetric analysis and differential scanning calorimetry. The morphology of obtained copolymers was studied by scanning electron microscopy. The cyclic voltammetry investigation showed the electroactivity of poly [aniline‐co‐N‐(2‐hydroxyethyl) aniline] and N and O‐alkylated poly[aniline‐co‐N‐(2‐hydroxyethyl) aniline]. The conductivities of the polymers were 5 × 10^?5 S/cm for poly[aniline‐co‐N‐(2‐hydroxyethyl) aniline] and 5 ×10^?7 S/cm for the octadecyl‐substituted copolymer. The conductivity measurements were performed with a four‐point probe method. The solubility of the initial copolymer in common organic solvents such as N‐methyl‐2‐pyrrolidone and dimethylformamide was greater than polyaniline. The alkylated copolymer was mainly soluble in nonpolar solvents such as n‐hexane and cyclohexane. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Flow transients performance in an MTR-type research reactor

During a flow coastdown event leading to slowing down coolant flow, the rate of heat removal from the fuel element must be sufficiently high to prevent meltdown. It is essential to estimate the flow rate change and the decay heat removal capability. In many studies complete pump operating characteristics are used in analytical solutions of the problem. Under the coastdown phenomenon, retarding torque replaces motor torque. In order to determine this torque, all the induction motor losses during the event are identified and where possible these loss parameters are measured. Stator and rotor core losses, stator and rotor stray load losses and magnetizing saturation and rotor conductor skin effects are taken into account. The basics equations for coolant flow and for the rotating parts of the centrifugal pump are subsequently derived for an MTR-type research reactor such Tehran Research Reactor (TRR). Then the equation of flow motion is solved with another one which predicts the pump speed during the coastdown transient. The results of the present work are validated by comparison with experimental and analytical studies of the similar work. The model shows good agreement with the present literature.     

Optimum stacking sequence design of composite materials Part II: Variable stiffness design

A composite laminate may be designed as a permutation of several straight-fiber layers or as a matrix embracing fibers positioned in curvilinear paths. The former called a constant stiffness design and the latter known as variable stiffness design. The optimization algorithms used in constant stiffness design were studied in Part I of this review article. This paper completes the previous article by focusing on variable stiffness design of composite laminates. Different parameterization and optimization algorithms are briefly explained and compared and the advantages and shortcomings of each algorithm are discussed.     

Development of energy-saving optimization for the oval-edging oval pass design using genetic algorithm

In the multi-pass rod rolling systems, where the final products are round bars with different sizes, oval-edging oval passes are widely employed as intermediate passes. This study attempts to present a generalized strategy to support the optimal design of oval-edging oval passes. A design system based on this strategy is developed to minimize power consumption, to reduce trials and errors in industry, as well as to improve the design efficiency and flexibility. A series of equations are established for geometrical modeling and graphic plotting of oval-edging oval passes, which can realize the parametric transformation for roll pass design and optimization. A novel formula based on statistical analysis and data fitting is proposed for the calculation of power consumption. To verify this formula, results obtained are compared with those calculated from using the Smirnov’s formula. The comparison confirmed the accuracy and efficiency of this formula. Finally, the proposed approach is applied for the optimal design of oval-edging oval passes, which are widely employed for the intermediate passes in the rod rolling systems. Through the comparison between simulation results and experimental data from literature, it is concluded that the proposed method can reduce power consumption of these passes and is able to improve the efficiency and flexibility of intermediate pass design without compromising its accuracy.     

The role of thermal residual stress on the yielding behavior of carbon nanotube–aluminum nanocomposites

The initial yield envelopes of aluminum (Al) nanocomposites reinforced with carbon nanotubes (CNTs) subjected to biaxial loading are predicted in the presence of thermal residual stress (TRS) arising from the manufacturing process. Micromechanical model based on the unit cell method is presented to generate the yielding surfaces. The formation of the interphase caused by the interfacial reaction between the CNT and Al matrix is taken into account in the analysis. The effects of several important parameters, i.e. the change of temperature, CNT volume fraction, interphase thickness and Al material properties on the yielding onset of the CNT/Al nanocomposite are explored extensively. The results clearly reveal that the initial yield surfaces of nanocomposite are dependent on the TRS. Also, the interphase has a significant influence on the yielding behavior of Al nanocomposite in the presence of TRS. The results demonstrate that the size of initial yield surfaces become minimum with considering the coupled effects of TRS and interphase. With increasing the temperature variation, interphase thickness, elastic modulus and coefficient of thermal expansion of Al matrix, the size of initial yield surfaces reduces. The present study is consequential for understanding the key role of TRS on the initial damage of CNT/Al nanocomposites.     

Male Aggregation Pheromone of Date Palm Fruit Stalk Borer Oryctes elegans

Laboratory and field investigations were carried out to characterize the chemical communication system of the date palm fruit stalk borer, Oryctes elegans, and to develop pheromone-based trapping in Eastern Iran. Adults of both sexes feeding on date palm pieces attracted conspecifics, whereas date palm alone was minimally attractive. Males were twice as attractive as females. More beetles were captured at the palm crown than at ground level. Odors from adults feeding on sugarcane were sampled and analyzed by gas chromatography and mass spectrometry. Whereas females did not emit sex specific volatiles, males emitted a blend of 4-methyloctanoic acid (1: major component) and ethyl 4-methyloctanoate (2), occasionally mixed with minor components: 4-methyloctanyl acetate (3), methyl 4-methyloctanoate (4), 4-methyloctanol (5), and nonanyl acetate (6). Electroantennography and field trapping experiments demonstrated that compound 1 is an essential component of the male aggregation pheromone of O. elegans. It was barely attractive by itself but synergistic with fresh date palm odor. It attracted many more beetles than any of compounds 2-6. The addition of one or several of compounds 2-6 to 1 did not improve trap captures. During the course of 2 years, we captured 4000 beetles, with a weekly average of 6.3 beetles/trap, and were able to monitor the seasonal flight of O. elegans. Our results provide the basis for developing mass trapping for control of this pest.