全文获取类型
收费全文 | 26372篇 |
免费 | 2712篇 |
国内免费 | 1875篇 |
学科分类
工业技术 | 30959篇 |
出版年
2024年 | 86篇 |
2023年 | 361篇 |
2022年 | 668篇 |
2021年 | 993篇 |
2020年 | 781篇 |
2019年 | 639篇 |
2018年 | 733篇 |
2017年 | 717篇 |
2016年 | 670篇 |
2015年 | 993篇 |
2014年 | 1271篇 |
2013年 | 1436篇 |
2012年 | 1658篇 |
2011年 | 1686篇 |
2010年 | 1710篇 |
2009年 | 1526篇 |
2008年 | 1485篇 |
2007年 | 1440篇 |
2006年 | 1308篇 |
2005年 | 1100篇 |
2004年 | 1212篇 |
2003年 | 1660篇 |
2002年 | 2190篇 |
2001年 | 1879篇 |
2000年 | 910篇 |
1999年 | 542篇 |
1998年 | 267篇 |
1997年 | 207篇 |
1996年 | 195篇 |
1995年 | 146篇 |
1994年 | 106篇 |
1993年 | 71篇 |
1992年 | 72篇 |
1991年 | 38篇 |
1990年 | 43篇 |
1989年 | 29篇 |
1988年 | 29篇 |
1987年 | 23篇 |
1986年 | 15篇 |
1985年 | 13篇 |
1984年 | 13篇 |
1983年 | 3篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1980年 | 10篇 |
1979年 | 5篇 |
1959年 | 8篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 218 毫秒
11.
Mingzhi Zhao Jianwei Cao Zhi Wang Guohua Li 《Journal of the European Ceramic Society》2019,39(7):2427-2435
The crystallization phenomena of spinel in CaO-MgO-Al2O3-SiO2-Fe2O3 glass have received much attention due to the particular role in preparation of glass-ceramic materials, which represent an effective option to manage hazardous waste. In this study, both preliminary spinel and secondary spinel were precipitated in the precursor glass. The formation of these spinel was meticulously assessed by a combination of X-ray diffractometry and scanning electron microscopy. The structure of the microenvironment in the precursor glass was characterized by Raman spectrums. These advanced techniques highlight the potential for one-step crystallization of the glass. The investigation, which focused on one-step crystallization, demonstrated the growth of pyroxene on spinel accompanying a migration of chromium. The results also show the microstructure of the obtained glass-ceramic was very dependent on the heat-treat temperature. This study not only unambiguously reveals the precipitation mechanisms of spinel but also provides more documentation for one-step crystallization in the glass-ceramics field. 相似文献
12.
Longzhi Li Xiaowei Jiang Zhiguo Bian Jianwei Wang Fumao Wang Zhanlong Song 《Drying Technology》2019,37(2):173-185
Microwave lignite drying with assistance of biomass-derived char was addressed and effect of bio-char on drying rate and energy consumption was investigated in this work. Effective diffusion coefficient and activation energy for the drying process were also analyzed. The results indicated the drying process was largely dependent on the variation of sample temperature. Bio-char originated from pine wood was most favorable for lignite drying, considering its better promoting effect and advanced security. There existed an optimal bio-char addition ratio for drying process at different power. The corresponding optimal ratio was 10% at 231?W and 15% at 385?W, at which the biggest drying rate and the least energy consumption were reached. It was compared lignite drying initiated at 385?W was better for energy conservation. Effective diffusivity was improved and activation energy was simultaneously reduced, with the addition of bio-char. The minimum activation energy was 15.54?W?·?g?1, which was gained at bio-char addition ratio of 10%. The results revealed the effect of bio-char on depressing activation energy could rival that of metal-based additives. The drying process with assistance of microwave and bio-char could present technical and economical benefits on lignite upgrading. 相似文献
13.
14.
Hong Wei Li Li Ya‐Li Ma Ru‐Xue Liu Shuang‐Yan Meng Li‐Tong Niu Zhe Zhang Zhi‐Wang Yang 《火与材料》2019,43(7):868-879
Through the simple precipitation of palygorskite (PGS) by zinc borate (ZB) (to make PGS@ZB) and the decoration of PGS@ZB by dodecylamine (N), a novel organic‐inorganic@inorganic hybrid flame retardant of PGS@ZB‐N was prepared and was incorporated with ethylene vinyl acetate copolymer (EVA) to improve its flame retardance. The structure and morphology of PGS@ZB‐N were characterized by Fourier transform infrared (FTIR) spectroscopy, X‐ray diffraction (XRD), and scanning electron microscopy (SEM), and it was confirmed that the PGS@ZB‐N hybrid had been successfully prepared. The flame retardancy and burning behavior of EVA/PGS@ZB‐N/EG (EG = expandable graphite) composite were studied through thermogravimetric analysis (TGA), limiting oxygen index (LOI), UL‐94 (by the vertical burning test), and cone calorimeter test (CCT) characterizations. The prepared EVA/PGS@ZB‐N/EG composite obtained an LOI value of 41.2% with the addition of 30 wt% PGS@ZB‐N/EG. It was found that EVA/PGS@ZB‐N/EG was protected through a gas phase and condensed phase alternating synergistic effect mechanism. 相似文献
15.
Qiang Wang Lei Shen Tong Xue Gao Cheng Cheng Zhi Huang Hong Jin Fan Yuan Ping Feng 《Advanced functional materials》2021,31(2):2002187
The {100} facet of single-crystalline TiO2(B) is an ideal platform for inserting Li ions, but it is hard to be obtained due to its high surface energy. Here, the single-crystalline TiO2(B) nanobelts from H2Ti3O7 with nearly 70% {100} facets exposed are synthesized, which significantly enhances Li-storage capacity. The first-principle calculations demonstrate an ab in-plane 2D diffusion through the exposed {100} facets. As a consequence, the nanobelts can significantly accommodate Li ions in LiTiO2 formula with specific capacity up to 335 mAh g−1, which is in good agreement with the electrochemical characterizations. Coating with conductive and protective poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), the cut-off discharge voltage is as low as 0.5 V, leading to a capacity of 160.7 mAh g−1 after 1500 cycles with a retention rate of 66% at 1C. This work provides a practical strategy to increase the Li-ion capacity and cycle stability by tailoring the crystal orientation and nanostructures. 相似文献
16.
Three-dimensional (3D) YBO3:Tb3+ flower-like and dense flower-like hierarchitecture constituted of nanoflakes are solvothermally synthesized in the presence of polyborate precursors in the mixture of ethanol and water. The growth process of the YBO3:Tb3+ flowers and dense flowers was explored based on the time-dependent experiment and the results showed that the growth mechanism follows an in situ growth rather than self-assembly process as reported previously. YBO3:Tb3+ morphologies composed of nanoflakes are achieved by controlling the concentration of ethanol and dependence of photoluminescence on morphology was studied. Remarkable photoluminescence enhancement was observed for YBO3:Tb3+ with flower-like morphology demonstrating the potential of the microstructure in future applications as a green phosphor. Such a synthetic method and growth mechanism may be applied to fabricate complex 3D architectures of other materials. 相似文献
17.
18.
某水泥厂钢丝胶带提升机(下文简称提升机)的驱动电机为三相异步电动机,其型号为:YE3-280M-4/90 kW,技术参数为:380 V/50 Hz/IP55/B3/F。在提升机空载试车过程中,电机三相电流出现不平衡现象,偏差达到了12%,实测三相电流数值分别为:60 A、65 A、75 A,其对应的三相电压分别为399 V、402 V、402 V。
针对上述现象,我们对产生三相电流不平衡的原因进行归纳,并对每种原因进行实验研究,最终得出了较为客观的结论。 相似文献
19.
三维最短路径法射线追踪及改进 总被引:1,自引:0,他引:1
射线追踪技术在地震学领域有着广泛的应用,其中以最短路径算法在复杂介质中走时计算稳定性最好。理论上最短路径法的误差来源为速度模型采样误差、空间离散化误差和角度离散化的误差,由此造成网格稀疏时射线路径呈之字形,计算走时比实际走时偏大。弯曲法追踪精度高,但是射线追踪速度受初始路径与真实射线路径逼近程度制约,在复杂介质中可能找不到全局最小走时路径。最短路径法追踪出来的网格射线路径,可以作为较理想的初始路径,供弯曲法迭代优化。将最短路径法和弯曲法结合,通过射线在初始路径附近的扰动得到Fermat原理约束下的最短路径。文章对常速模型的试算,显示了改进方法对射线路径优化的作用,在模型网格稀疏的情况下效果尤其明显。本算法适用于计算三维任意复杂介质中初至波走时和射线路径,可应用于三维走时层析成像等领域。 相似文献
20.
碳纳米管膜的场致发射电流密度仅由它表面的宏观电场决定,无论其表面形状是平的还是半球状的。对于理想的平行板电极系统,其表面电场强度均匀(UId),发射电流密度、总电流与发射面积成正比:对于半球一平面电极系统半球形的阴极存在一个宏观场增强因子ks,一个与两极距离和球半径之比(d/r)相关的函数,其表面的平均场强为ks U/d。对于d/r=0,ks=1,d≥r的情况,ks接近于常数。对于10〈d/r〈100的情况,存在一个经验的表达式:ks=1+0.15d/s=0.005(d/r)^2。在引入ks后,不同作者给出的平面电极系统和半球一平面电极系统碳纳米管膜的场致发射电流I与宏观表面电场强度E的关系都可以近似用-经验公式描述:I=a(E-Eo)^b,a,b为常数。该经验公式可为稳定生产的CNT膜片应用产品设计提供方便。 相似文献