超临界色谱串联质谱法测定橄榄油中 维生素E含量的研究

目的建立运用超临界色谱串接质谱法同时测定橄榄油中4种生育酚和4种生育三烯酚含量的方法,并比较不同产地的特级初榨橄榄油中8种生育酚类化合物的含量差异。方法运用超临界色谱将橄榄油中多种生育酚和生育三烯酚分离,用三重四极杆质谱进行定性和定量分析,通过线性范围、回归系数、加标回收率等指标评价方法的准确性和可靠性。通过运用两个独立样本间的t检验的方法计算西班牙产和意大利产的特级初榨橄榄油中8种生育酚类化合物浓度的差异。结果 4种生育酚和4种生育三烯酚的浓度在0.10~100.0 mg/L范围内与峰面积呈良好线性关系,线性回归系数(r2)均大于0.99,加标回收率81.0%~108.3%之间。西班牙产和意大利产的特级初榨橄榄油中,未检出β-生育三烯酚、γ-生育三烯酚和δ-生育三烯酚;两地产橄榄油的α-生育酚、β-生育酚和δ-生育酚的含量无统计学差异(P0.05);两地产橄榄油中γ-生育酚浓度有统计学差异(P0.05)。结论运用超临界色谱串联质谱法可将橄榄油中4种生育酚和4种生育三烯酚完全分离,方法准确、可靠。意大利产和西班牙产特级初榨橄榄油中γ-生育酚含量不同,可作为鉴定原产地的依据之一。     

Si元素对Zn-8Al合金制备碳纤维层合板性能影响的研究

通过向Zn-8Al添加Si元素,采用热压复合工艺制备碳纤维层合板。采用SEM和EDS分析层合板微观组织结构、碳纤维分布及断口形貌。结果表明,层合板抗拉强度相比5052板提高36.2%,相较于Zn-8Al作连接剂的层合板,提高了20.5%。Si元素对层合板拉伸性能改善明显。     

基于Levy flight的特征选择算法

为了提高特征选择方法的计算速度,提出基于Levy flight随机过程的特征选择方法.该方法在寻优过程中定义基于启发式的分阶段搜索策略,在局部搜索行为中引入Levy flight随机过程,将Levy flight距离与搜索行为进行映射.在不同的搜索阶段,利用不同的映射区间改变搜索行为出现的概率,以该映射来控制局部搜索行为的方向和速度,从而避免了陷入局部最优的问题.实验结果表明,采用LevyFS算法克服了启发式特征选择方法的局限性,平均耗时仅为SFFS算法的1/3左右.     

随机填充中空纤维膜组件中非稳态渗透传质数学模型

Based on the membrane-based absorption experiment of CO2 into water, shell-side flow distribution and mass transfer in a randomly packed hollow fiber module have been analyzed using subchannel model and unsteady penetration mass transfer theory. The cross section of module is subdivided into many small cells which contains only one hollow-fiber. The cross sectional area distribution of these cells is presented by the normal probability density distribution function. It has been obtained that there was a most serious non-ideal flow in shell side at moderate mean packing density, and the large amount of fluid flowed and transferred mass through a small number of large voids. Thus mass transfer process is dominated by the fluid through the larger void area. The mass transfer process in each cell is described by the unsteady penetration theory. The overall mass transfer coefficient equals to the probability addition of the mean mass transfer coefficient in each cell. The comparisons of the values calculated by the model established with the empirical correlations and the experimental data of this work have been done.The predicted overall mass transfer coefficients are in good agreement with experimental data.     

以用户为中心的DCS操作员站人机界面设计

阐述了从用户的观点出发,以用户为中心的电厂DCS操作员站人机界面的设计方法。介绍了现场研究法,在以用户为中心的设计方法中是一个有效的信息收集方法,并给出了具体的工程实例来说明该方法在实际工程设计中的应用。