全文获取类型
收费全文 | 1160篇 |
免费 | 5篇 |
国内免费 | 2篇 |
学科分类
数理化 | 1167篇 |
出版年
2022年 | 11篇 |
2021年 | 28篇 |
2020年 | 25篇 |
2019年 | 30篇 |
2018年 | 24篇 |
2017年 | 30篇 |
2016年 | 48篇 |
2015年 | 12篇 |
2014年 | 40篇 |
2013年 | 53篇 |
2012年 | 23篇 |
2011年 | 38篇 |
2010年 | 37篇 |
2009年 | 26篇 |
2008年 | 40篇 |
2007年 | 30篇 |
2006年 | 45篇 |
2005年 | 39篇 |
2004年 | 35篇 |
2003年 | 27篇 |
2002年 | 41篇 |
2001年 | 35篇 |
2000年 | 18篇 |
1999年 | 12篇 |
1998年 | 13篇 |
1997年 | 19篇 |
1996年 | 14篇 |
1995年 | 15篇 |
1994年 | 10篇 |
1992年 | 13篇 |
1990年 | 29篇 |
1989年 | 16篇 |
1988年 | 16篇 |
1987年 | 12篇 |
1986年 | 11篇 |
1985年 | 16篇 |
1984年 | 18篇 |
1983年 | 11篇 |
1982年 | 10篇 |
1981年 | 13篇 |
1980年 | 14篇 |
1979年 | 10篇 |
1978年 | 16篇 |
1977年 | 12篇 |
1975年 | 14篇 |
1973年 | 10篇 |
1972年 | 11篇 |
1971年 | 12篇 |
1969年 | 8篇 |
1966年 | 11篇 |
排序方式: 共有1167条查询结果,搜索用时 46 毫秒
31.
N. S. Vul'fson V. A. Puchkov Yu. V. Denisov B. V. Rozynov V. N. Bochkarev M. M. Shemyakin Yu. A. Ovchinnikov V. K. Antonov 《Chemistry of Heterocyclic Compounds》1967,2(4):468-474
Analysis of mass-spectra of various 2, 5-diketopiperazines gives the basic fragmentation rules for their molecular ions, and the effects of nature and positions of substituents on the process.Mass-spectrometry Laboratory of the Institute of the Chemistry of Natural Compounds.Antibiotics Chemistry Laboratory of the Institute of the Chemistry of Natural Compounds. 相似文献
32.
A. V. Sokolov A. A. Nikanorov E. M. Pliss E. T. Denisov 《Russian Chemical Bulletin》1985,34(4):705-708
Conclusions The rate constant of the reaction of peroxide radicals of acrylic and methacrylic esters of polyols with nonpolar cumene is not dependent on the number of ester groups, and with polar 2,4,6-tri-tert-butylphenol decreases with an increase in the number of ester groups in the peroxide radical. Both findings are in agreement with the model of a dipole-dipole interaction in reactions of polyfunctional compounds.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 778–781, April, 1985. 相似文献
33.
Jesik R Abramov V Antipov Y Baldin B Crittenden R Dauwe L Davis C Denisov S Dyshkant A Dzierba A Glebov V Goldberg H Gribushin A Koreshev V Krider J Krinitsyn A Li R Margulies S Marshall T Martin J Mendez H Petrukhin A Sirotenko V Smith P Solomon J Sulanke T Sulyaev R Vaca F Zieminski A Blusk S Bromberg C Chang P Choudhary B Chung W de Barbaro L Dlugosz W Dunlea J Engels E Fanourakis G Ginther G Hartman K Huston J Kapoor V Lirakis C Lobkowicz F Mani S Mansour J Maul A Miller R Oh B Pothier E 《Physical review letters》1995,74(4):495-498
34.
Isotonic and isobaric dependencies of nuclear charge radii in the region between Z=54 and Z=70 are obtained from the analysis of isotope shift data r2 and muonic and electron scattering data on r2. They are compared with the predictions of the droplet model and the Hartree-Fock calculations. The isobaric dependencies of r2 have proven to be especially sensitive to the choice of an effective nucleon-nucleon interaction. 相似文献
35.
Morelos A Albuquerque IF Bondar NF Carrigan RA Chen D Cooper PS Lisheng D Denisov AS Dobrovolsky AV Dubbs T Endler AM Escobar CO Foucher M Golovtsov VL Gottschalk H Gouffon P Grachev VT Khanzadeev AV Kubantsev MA Kuropatkin NP Lach J Lang Pengfei Li Chengze Li Yunshan Luksys M Mahon JR McCliment E Newsom C Pommot Maia MC Samsonov VM Schegelsky VA Shi Huanzhang Smith VJ Tang Fukun Terentyev NK Timm S Tkatch II Uvarov LN Vorobyov AA Yan Jie Zhao Wenheng Shuchen Z Zhong Yuanyuan 《Physical review letters》1993,71(21):3417-3420
36.
Morelos A Albuquerque IF Bondar NF Carrigan RA Chen D Cooper PS Dai Lisheng Denisov AS Dobrovolsky AV Dubbs T Endler AM Escobar CO Foucher M Golovtsov VL Gottschalk H Gouffon P Grachev VT Khanzadeev AV Kubantsev MA Kuropatkin NP Lach J Lang Pengfei Li Chengze Li Yunshan Luksys M Mahon JR McCliment E Newsom C Pommot Maia MC Samsonov VM Schegelsky VA Shi Huanzhang Smith VJ Tang Fukun Terentyev NK Timm S Tkatch II Uvarov LN Vorobyov AA Yan Jie Zhao Wenheng Zheng Shuchen Zhong Yuanyuan 《Physical review letters》1993,71(14):2172-2175
37.
V. E. Agabekov N. L. Budeiko E. T. Denisov N. I. Mitskevich 《Reaction Kinetics and Catalysis Letters》1977,7(4):437-443
A competition method (R.+O2RO
2
.
, R.+XHRH+X.) is proposed to measure the relative rate constants for the interaction of alkyl radicals with different organic compounds. Partial (per C–H bond) rate constants have been determined for the reaction of undecyl radicals with cumene, ethylbenzene and toluene.
(R.+O2RO 2 . , R.+XHRH+X.), . ( C–H ) , .相似文献
38.
Ultraviolet absorption spectra in the range 300-200 K were used to study the composition and structure of complexes formed in solutions by the fluorinated amine (4-CF3C6F4)2NH as a proton donor with dibutylamine. A program is developed for quantitative analysis of sets of the spectra of equilibrium multicomponent systems, that allow to find spectral and thermodynamic characteristics of the individual components. In the systems in study, 1:1 and 1:2 fluorinated diamine-dibutylamine complexes are formed. The first of them in a molecular complex with an NHN hydrogen bond, and the second is an ionic proton-transfer complex. The equilibrium constants between the complexes and the free molecules are found, the enthalpies and entropies of formation of both complexes are found, and the spectra of the complexes are measured. 相似文献
39.
S. F. Bureiko N. S. Golubev G. S. Denisov I. Ya. Lange 《Reaction Kinetics and Catalysis Letters》1977,7(2):139-144
The kinetic isotope effect in proton exchange between methanol and water in CCl4 solution was studied by1H and2H NMR and kinetic IR spectroscopy. The exchange rate increases in the series CD3OH+H2O3OD+H2O3OD+D2O. It has been concluded that the limiting step of the reaction involves the formation of an H-bonded cyclic intermediate.
1H 2H - CCl4. , CD3OH+H2O相似文献3OD+H2O 3OD+D2O. , - -.
40.
Hsueh SY Muller D Tang J Winston R Zapalac G Swallow EC Berge JP Brenner AE Grafstrom P Jastrzembski E Lach J Marriner J Raja R Smith VJ McCliment E Newsom C Anderson EW Denisov AS Grachev VT Kulikov AV Schegelsky VA Seliverstov DM Smirnov NN Terentyev NK Tkatch II Vorobyov AA Cooper PS Razis P Teig LJ 《Physical review letters》1985,54(22):2399-2402