Confined and Interface Phonons in Chirped GaAs-A1GaAs Superlattices

The confined longitudinal optical, transverse optical and interface phonon modes in chirped GaAs-AIGaAs superlattices grown on the （O01）-oriented GaAs substrate are studied by the micro-Raman spectroscopy. The phonon modes are probed at the （001） and （110） faces. The temperature dependence of the longitudinal optical, transverse optical and interface phonon modes are achieved. The temperature dependence of the longitudinal optical phonon frequencies demonstrates that a tensile strain exists in the GaAs layers of the chirped superlattices, which is significant for analyzing the device failure of a terahertz quantum cascade laser.     

超大口径光学制造均力支撑布局优化

为降低支撑控制难度和节约制造成本,同时又保证在线光学加工-检测所需的支撑精度,提出超大口径反射镜的支撑布局优化方法。研究支撑状态下的反射镜面形精度,解决面形拟合和优化目标提取的问题;以斜率均方根(SlopeRMS)为目标建立非圆形口径的超薄反射镜加工支点布局优化模型,使其具备自适应有限元分析的功能;针对工程中大量使用的轻量化反射镜,设计出适应其几何变化的支撑转换结构,并展开以面形均方根(RMS)误差为目标的支点位置的优化设计;通过30m口径望远镜(TMT)第三镜和某2m口径反射镜的支撑布局优化,验证了所采用方法的效果。算例结果表明,所提方法具有较好的几何适应性,布局优化后支撑系统的精度满足超大口径反射镜的光学制造要求。     

Energy transfer mechanism in Er3＋ doped fluoride glass sensitized by Tm3＋ or no3＋ for 2.7-μm emission

Enhanced 2.7 μm emission is obtained in Er3＋/Tma＋ and Era＋/Ho3＋ codoped ZBYA glasses. Absorp- tion and emission spectra are tested to characterize the 2.7 μm emission properties of Era＋/Tm3＋ and Era＋/Ho3＋ doped ZBYA glasses and a reasonable energy transfer mechanism of 2.7 μm emission between Er3＋ and Tm3＋Ho3＋） ion is proposed. Codoping of Tm3＋ or Ho3＋ significantly reduces the lifetime of the Era＋： 4I13/2 level due to the energy transfer of Er3＋：4I13/2 →Tm3＋：3F4 or Er3＋：4I13/2 →Ho3＋： 5I7. Thus, the 2.7μm emission is strengthened and the 1,5μm emission is decreased accordingly especially in the Era＋/Tma＋ sample. The upconversion effects between the Er3＋/Tm3＋ and Er3＋/Ho3＋ doped ZBYA glasses are different attribute to the different energy transfer efficiencies. Both of the two codoped samples possess nearly equal large emission cross section （16.6 × 10 -21 cm-2） around 2.7 μm. The results indicate that this Er3＋/Tm3＋ or Er3＋/Ho3＋ doped ZBYA glass has potential applications in 2.7 μm laser.     

Molecular dynamics simulations of the nano-droplet impact process on hydrophobic surfaces

Large-scale molecular dynamics simulations are used to study the dynamic processes of a nano-droplet impacting on hydrophobic surfaces at a microscopic level. Both the impact phenomena and the velocity distributions are recorded and analyzed. According to the simulation results, similar phenomena are obtained to those in macro-experiments. Impact velocity affects the spread process to a greater degree than at a level of contact angle when the velocity is relatively high. The velocity distribution along the X axis during spread is wave-like, either W- or M-shaped, and the velocity at each point is oscillatory; while the edges have the highest spread velocity and there are crests in the distribution curve which shift toward the edges over time. The distribution along the Y axis is 〈- or 〉-shaped, and the segments above the middle have the lowest decrease rate in the spreading process and the highest increase rate in the retraction process.     

复杂网络中带有应急恢复机理的级联动力学分析

提出带有应急恢复机理的网络级联故障模型,研究模型在最近邻耦合网络,Erdos-Renyi随机网络,Watts-Strogatz小世界网络和Barabasi-Albert无标度网络四种网络拓扑下的网络级联动力学行为.给出了应急恢复机理和网络效率的定义,并研究了模型中各参数对网络效率和网络节点故障率在级联故障过程中变化情况的影响.结果表明,模型中应急恢复概率的增大减缓了网络效率的降低速度和节点故障率的增长速度,并且提高了网络的恢复能力.而且网络中节点负载容量越大,网络效率降低速度和节点故障率的增长速度越慢.同时,随着节点过载故障概率的减小,网络效率的降低速度和节点故障率的增长速度也逐渐减缓.此外,对不同网络拓扑中网络效率和网络节点故障率在级联故障过程中的变化情况进行分析,结果发现网络拓扑节点度分布的异质化程度的增大,提高了级联故障所导致的网络效率的降低速度和网络节点故障率的增长速度.以上结果分析了复杂网络中带有应急恢复机理的网络级联动力学行为,为实际网络中级联故障现象的控制和防范提供了参考.     

表面张力对疏水微结构表面减阻的影响

通过构造具有棋盘状微结构的疏水表面,考虑表面张力的影响,利用定常与非定常结合的数值模拟方法,研究了疏水表面在湍流状态下的减阻特性以及微结构内气体封存的效果,其中Re=3000—30000.在低雷诺数下,疏水表面微结构内气体封存状态良好,减阻率最高约为30%;随着雷诺数的增大,压差阻力增大,减阻率有下降趋势.当来流速度过大时,水会大量进入微结构,疏水表面的减阻率变化剧烈,且已经不再减阻.结果表明,表面张力削弱了壁面切应力的影响,使得低雷诺数下微结构内气体能够有效封存,进而减小壁面阻力.     

35kV超导可控电抗器电流引线设计

35kV高温超导可控电抗器工作于70K液氮温区,通过控制超导线圈的工作状态来实现电抗的调节。线圈工作时,电流引线的焦耳热以及传导热是引线漏热的主要来源;当超导线圈开路时,线圈及电流引线则要承受高达十几千伏的感生电压,因此,电流引线的漏热优化以及电气绝缘水平是设计的重点。文中结合电流引线运行工况,设计了35kV超导可控电抗器电流引线,仿真结果表明,该设计漏热量低且温度分布均匀。此外,针对线圈开路时引线的高压情况确立了APG注射环氧绝缘的方案,有效的保证了绝缘水平。     

基于绝缘硅的微环谐振可调谐滤波器

采用电子束光刻和感应耦合等离子刻蚀等工艺,研制了一种基于绝缘硅材料的的微环谐振可调谐滤波器.滤波器微环半径为5 μm左右,波导截面尺寸为(350～500 nm)×220 nm不等.测试结果表明,波导宽度为450 nm时器件性能最为理想,其自由频谱宽度为16.8 nm,1.55 μm波长附近的消光比为22.1 dB.通过对微环滤波器进行热光调制,在21.4 ℃～60 ℃温度范围内实现了4.8 nm波长范围的可调谐滤波特性,热光调谐效率达到0.12 nm/℃.研究了基于单环和双环的多通道上下载滤波器,实验结果表明多通道滤波器的信号传输存在串扰,主要是不同信道之间的串扰,尤其在信号上载时,会在相邻信道产生较大串扰.     

Beam dynamics simulations of the injector for a compact THz source

Terahertz radiation has broad application prospects due to its ability to penetrate deep into many organic materials without the damage caused by ionizing radiations. A free electron laser （FEL）-based THz source is the best choice to produce high-power radiation. In this paper, a 14 MeV injector is introduced for generating high-quality beam for FEL, is composed of an EC-ITC RF gun, compensating coils and a travelling-wave structure. Beam dynamics simulations have been done with ASTRA code to verify the design and to optimize parameters. Simulations of the operating mode at 6 MeV have also been executed.     

通过接枝苄基磺酸在MCM-41上固载手性Mn(salen)配合物

首先通过两步后合成处理,在MCM-41上接枝苄基磺酸;然后,以苄基磺酸为过渡产物,用手性Mn(salen)配合物修饰处理,得到了苄基磺酸轴向负载手性Mn(salen)配合物的MCM-41;实现了在廉价且温和条件下均相手性Mn(salen)催化剂的非均相化。采用X射线衍射(XRD)、低温N2吸附-脱附、红外光谱、热重-差示扫描量热(TG-DSC)分析、电感耦合等离子体发射光谱(ICP)和酸度滴定等对样品进行了表征。结果表明,手性Mn(salen)配合物成功固载在MCM-41上,且MCM-41的介孔结构和Mn(salen)配合物的手性特征仍然保留。以间氯过氧苯甲酸为氧化剂,考察了所得固载型催化剂对α-甲基苯乙烯的不对称环氧化催化性能,结果表明在0℃反应2 h,催化剂用量为0.02 mmol,无需加入轴向配体N-甲基吗啉氮氧化物(NMO)的条件下对映体过量(enantiomeric excess,e.e.)值可达99%以上,转化率为77%。归因于苄基磺酸基起到了很好的轴向配体作用。经适当处理,固载型催化剂在循环使用5次后e.e.值依然有71%,表现出较好的活性和重复使用性能。