真空填充胶晶模板法快速制备三维有序大孔二氧化钛

以丙烯酸修饰的聚苯乙烯（PS）胶体晶体为模板,采用“三明治-真空”填充法将钛酸四丁酯的乙醇溶液填充到模板间隙中,煅烧除去模板快速高效制备了表面无覆盖层的三维有序大孔二氧化钛（3DOM TiO2）材料。 制备的3DOM TiO2具有典型的反蛋白石结构,孔壁完整且孔径大小均匀,呈六方密堆积的FCC结构。 其孔径为230 nm左右,收缩率仅为14%,孔与孔之间由小窗口相连。 XRD分析表明,500 ℃下煅烧制备的3DOM TiO2为锐钛矿晶型。     

Enhancing magnetic dipole emission with magnetic metamaterials

Magnetic dipole(MD) transitions are important for a range of technologies from quantum light sources and displays to lasers and bio-probes. However, the typical MD transitions are much weaker than their electric counterparts and are usually neglected in practical applications. Herein, we experimentally demonstrate that the MD transitions can be significantly enhanced by the well-developed magnetic metamaterials in the visible optical range. The magnetic metamaterials consist of silver nanostrips and a thick silver film, which are separated with an Eu~(3+):polymethyl methacrylate(PMMA) film. By controlling the thickness of the Eu~(3+):PMMA film, the magnetic resonance has been tuned to match the emission wavelength of MDs. Consequently,the intensity of MD emission has been significantly increased by around 30 times at the magnetic resonance wavelength, whereas the intensity of electric dipole emission is well-preserved. The corresponding numerical calculations reveal that the enhancement is directly generated by the magnetic resonance, which strongly increases the magnetic local density of states around the MD emitter and can efficiently radiate the MD emission into the far field. This is the first demonstration, to the best of our knowledge, that MD transitions can be improved by an additional degree of magnetic freedom, and we believe this research shall pave a new route towards bright magnetic emitters and their potential applications.     

差动式光纤Bragg光栅沉降仪

研制了一种测量地表沉降变形的差动式光纤Bragg光栅沉降仪。等强度悬臂梁的底部固定于工地上的固定平台,顶端通过刃口、挂钩和连杆与沉降墩连接。在该测量中,沉降仪将沉降墩的地沉降量转换为悬臂梁的挠度。悬臂梁作用粘贴于其上下表面的光纤Bragg光栅产生应变,即传感光栅的Bragg波长产生了移位。对粘贴在悬臂梁上、下表面的传感光栅的Bragg波长进行差动运算,实现温度补偿,减小人为和气候因素的影响。在挂钩和沉降敦之间采用了螺旋结构连接,可通过调整螺旋或更换不同长度的挂钩来调节传感器的测量范围。荷载实验表明,该沉降仪的测量精度为0.004mm,低于变形测量中的科研级测量精度0.01~0.05mm。     

双孔平行梁光纤Bragg光栅称重传感器

采用双孔平行梁型弹性元件作为光纤Bragg光栅称重传感器的换能结构,其中,四片光栅对称地贴粘在梁的灵敏区域。值得注意的是利用弹性元件自身结构特点对称重传感器进行了温度和偏载补偿,从而得到了FBG中心波长移位与载荷的关系。加载卸载实验表明,该双孔平行梁FBG称重传感器的载荷响应灵敏度为16 pm/kg,测量精度为0.7%。     

高效液相色谱-电感耦合等离子体质谱法测定土壤和沉积物中Cr(Ⅲ)与Cr(Ⅵ)EI北大核心CSCD

Cr(III) and Cr(VI) were separated by high performance liquid chromatography by using EDTA-Naj as mobile phase. Oxygen was added to reduce the interference of40Ar12C on+52Cr in mass spectrometry. The results showed that the linear relationships of Cr(HI) and Cr(VI) were good in the concentration range of 0.5-100 μXg/L, and the correlation coefficients were 0.9997 and 0.9998, respectively. The method detection limits of Cr(TH) and Cr(VI) both were 0.1 μxg/L. The method was applied to determine standard substances of NSI Lab Solutions with three kinds of chromium speciation, and the results were agreement with the certified values. The recoveries were 91.9%-116.7% at three spiked concentrations. The method is suitable for the determination of water-soluble chromium in soil and sediment samples. © 2023, Youke Publishing Co.,Ltd. All rights reserved.     

陶寺、殷墟白灰面的红外光谱研究

采用傅里叶变换红外光谱(FTIR)对天然石灰石、模拟白灰面以及采自陶寺遗址和殷墟遗址的白灰面进行了分析检测,以探明陶寺和殷墟遗址白灰面所用原料。结果显示,人工烧制石灰碳化后所形成的方解石,其ν₂/ν₄比值高达6.31,明显高于天然石灰石中的方解石,从而表明人工烧制石灰碳化所形成的方解石较之天然石灰石中的方解石具有较高的晶体无序度;随着研磨程度的增加,天然石灰石中的方解石和人工烧制石灰碳化形成的方解石,其ν₂和ν₄值逐渐减小,人工烧制石灰碳化形成方解石的ν₂-ν₄特征趋势线斜率较高,从而为考古出土人工烧制石灰的判定提供了一种简便、有效的方法。根据此判别方法,陶寺和殷墟遗址的白灰面很可能是采用人工烧制石灰所制备的,表明中国古代先民在距今4300多年的新石器时代晚期已掌握了石灰烧制技术。     

基于ZIF-67的Co3O4/C修饰电极制备及对多巴胺传感性能研究

以金属有机骨架材料ZIF-67为前驱体,经氩气气氛高温处理制备得到了Co_2O4与碳复合材料(Co_3O4/C)。通过X射线衍射仪(XRD)和扫描电子显微镜(SEM)对Co_3O4/C的结构和形貌进行了表征。Co_3O4/C保持了前驱体ZIF-67正十二面体形貌,并发生明显皱缩现象。采用循环伏安、恒电位等方法研究了Co_3O4/C修饰玻碳电极(GCE)对多巴胺(DA)的传感性能。结果表明:在多巴胺浓度在5~500μmol/L范围内,Co_3O4/C/GCE的氧化峰电流与浓度存在良好的线性关系,检测灵敏度高达283.09μA·L/(mmol·cm2)。此外,Co_3O4/C/GCE还展示出良好的抗干扰能力、重现性和稳定性。     

表面组装CdTe量子点的中空纤维膜抗菌性能研究

聚砜中空纤维膜由于其独特的性质成为广泛使用的基膜之一,微生物污染是其使用过程中常见的一个严峻问题,量子点具有粒径小,生物毒性强等特点,在抑制微生物的生长方面有重要作用.本文主要研究量子点修饰的聚砜中空纤维膜表面的抗菌性能,通过在水相中合成了稳定的具有窄而对称荧光发射带的量子点CdTe,以巯基丙酸作为表面修饰剂,对其进行了荧光光谱、透射电镜表征,得到了粒径约为3nm的CdTe半导体纳米粒子;以二苯甲酮为光敏剂,通过连续化紫外辐照的方法将亲水性单体甲基丙烯酸β羟乙酯接枝到中空纤维膜的表面,利用羟基和羧基的反应成功地在其表面组装上量子点,通过红外光谱进行表征;从野外环境中分离培养了棒状细菌B1,其形态通过偏光显微镜和扫描电镜表征,利用紫外分光光度计测量光学密度,分析中空纤维膜上量子点的抗菌性能.结果表明,经过改性,细菌的光学密度由原膜的0.88降低到量子点改性膜的0.27.表明中空纤维膜的抗菌性有了较显著的改善.进而表明,连续化紫外辐照改性的方法切实可行,并展现了在工业应用领域的潜力.     

A-GPS辅助定位技术研究

A-GPS定位技术是结合地面网络资源和传统卫星导航定位,利用蜂窝网基站代为传送卫星星历等信息,提高接收机对卫星信号的捕获概率,缩短接收机首次定位时间。在研究A-GPS对接收机辅助定位技术过程中,重点分析了A-GPS对接收机信号捕获的辅助原理,分析表明,基于A-GPS的信号捕获时间可缩短为传统接收机的1/40。利用GNSS导航信号模拟器和蜂窝网基站模拟器组建了室内A-GPS模拟测试系统,通过模拟基站的信令方式将参考时间、多普勒频移预测值以及星历或历书等辅助数据传输给用户接收机,实现了辅助数据在信令通道的编码和传输。