Synthesis and characterization of poly(ethylene tetrasulfide)/graphene oxide nanocomposites by in situ polymerization method

Poly(ethylene tetrasulfide) (PSP) is synthesized via interfacial polycondensation of 1,2 dichloroethane and sodium tetrasulfide, in the presence of graphene oxide (GO). This process resulted in homogeneously dispersed PSP/GO nanocomposites. Nanocomposites of 0.3 and 0.5?wt% of GO are synthesized and their morphology, chemical characteristics behavior are studied employing field emission scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction techniques. Thermal characterization of composites is performed by differential scanning calorimetry and thermogravimetry analysis. Results indicate that the addition of only small amounts (0.5?wt%) of well-dispersed GO can increase the melting point more than 16°C resulting in better thermal properties for the composite. The solubility of nanocomposite is also studied and results show that the solubility depends on solvent concentration in addition to reinforcement (GO) deals.     

Dam break flood wave under different reservoir’s capacities and lengths

Dam failure has been the subject of many hydraulic engineering studies due to its complicated physics with many uncertainties involved and the potential to cause many losses of lives and economical losses. A primary source of uncertainties in many dam failure analyses refers to prediction of the reservoir’s outflow hydrograph, which is studied in the present investigation. This paper presents an experimental study on instantaneous dam failure flood under different reservoir’s capacities and lengths in which the side slopes change within a range of 30°–90°. Thus, several outflow hydrographs are calculated and compared. The results reveal the role of the side slopes on dam break flood wave, such that lower side slope creates more catastrophic outflow. The reservoir capacity and length are also recognized to be important factors, such that they do affect peak discharge and time to peak of the outflow hydrograph. Finally, the paper presents two simple relations for peak discharge and maximum water level estimation at any downstream location.     

Effect of Shot Peening Operation on the Microstructure and Wear Behavior of AZ31 Magnesium Alloy

Protection of Metals and Physical Chemistry of Surfaces - Shot peening is a treatment used to increase surface hardness and wear resistance. In this study, the effect of shot peening on the...     

A comprehensive review of solar‐driven desalination technologies for off‐grid greenhouses

This paper is motivated by the crisis of freshwater in remote areas around the world and responds to the growing need for sustainable food production in arid lands. It focuses on utilizing solar energy to yield freshwater from the sea or brackish water with less environmental impacts, for greenhouses, which can produce sustainable food all over the year. The integration of various solar‐driven desalinations such as solar still, humidification‐dehumidification, reverse osmosis, electrodialysis, and multieffect and multistage flash with greenhouses are evaluated, for better sustainability towards greenization. The paper first discusses the specifications of solar‐driven desalinations and compares their advantages and limitations. Then, different types of greenhouses are introduced, and their total water requirement is discussed based on their locations, crop type, greenhouse technology, irrigation type, and environmental conditions, as well as their cooling and heating strategies. Later, the existing integration of solar‐driven desalinations with greenhouses are reviewed, and their advantages and limitations are deliberated. Finally, the paper discusses the criteria to be considered when selecting solar‐driven desalinations for greenhouses and presents a detailed comparison between the water production rate and cost as well as the energy consumption of these systems. In the end, the most appropriate combinations of solar‐driven desalinations with greenhouses are recommended based on their water requirement and production cost.     

Quantitative characterization of carrier injection across metal–organic interfaces using Bardeen theory

We have investigated the contact between a metal and an organic/polymeric (o/p) material and we have introduced a relation for carrier injection using Bardeen theory. A series of narrow barriers is considered in the semiconductor side to account for the localized nature of the carriers in the o/p material. As an application of the model, we have calculated the hopping rate of carriers in terms of the contact parameters. Also, we have discussed the hopping of carriers deep into the organic dielectric. Finally, we have explored the hopping rate in practical contacts between polyfluorene-based polymers and different electrodes.     

Overaluminizing of a CoNiCrAlY Coating by Inward and Outward Diffusion Treatments

Overaluminizing is a commercially accepted treatment to enhance high temperature oxidation resistance of MCrAlY overlay coatings. In the current investigation, a low pressure plasma-sprayed CoNiCrAlY coating was aluminized by two different growth modes: outward growth and inward growth. The resultant microstructures were characterized by means of scanning electron microscopy, energy dispersive spectroscopy, and X-ray diffraction analysis. The results showed that the final microstructure of both types of overaluminized coatings was similar and included Al-rich NiAl and Ni-rich NiAl zones from the top to the bottom. The details of the microstructures are discussed and compared with the results of simple aluminizing of the nickel-based substrate.     

Mathematical Modeling of Coke Formation and Deposition due to Thermal Cracking of Petroleum Fluids

A two‐dimensional mathematical dynamics model is presented to predict coke formation due to thermal cracking inside the tubes of fired heaters on two types of petroleum fluid. The laminar and turbulent flows are analyzed for both petroleum fluids. The second‐order k‐? standard model is adopted to make this mathematical model more accurate than previous models of coke formation. The radial and axial variations for temperature, velocity, and concentration due to the high temperature gradients inside the tubes are considered in the model equations. The finite volume method is the numerical model used to discretize the conservation equations. The proposed model is suitable to predict coke formation inside heater tubes since it indicates operational conditions where coke formation is minimized.     

Determination of phenolic profile and antioxidant activity of pistachio hull using high-performance liquid chromatography–diode array detector–electro-spray ionization–mass spectrometry as affected by ultrasound and microwave

The phytochemicals content and radical scavenging activity of pistachio (Pistacia vera L.) hull extract obtained by different solvents (water, ethanol, and butanol) were measured and compared. Water was selected as superior solvent. Ultrasound-assisted aqueous extraction of the hull by power ultrasound (35 kHz) was more efficient in ascending the phytochemicals content than the sonochemical ultrasonication (130 kHz). High-performance liquid chromatography-mass spectrometry showed increased amounts of vanillic acid, p-coumaric acid, naringenin, and catechin in ultrasound-assisted extracts. Post-extraction sonication declined significantly the phenolics amount and antioxidant property of the aqueous extract. Microwave-assisted extraction increased the phenolics and flavonoids content at extract in a power-dependent trend.     

Strand Current Distribution Modeling in Turbo-generators Using Finite-element Method Based on Proposed Dual Method

Abstract—The necessity of using a 3D model is one of the main problems for modeling Roebel bar transposition in turbo-generators by the finite-element method. This article proposes a 2D dual model for computing strand current distribution in the Roebel bar of turbo-generators. Considering the leakage and mutual inductances for each strand and the coupling inductances between them, the end winding region is modeled in this 2D dual model. In this article, the Roebel bar structure including 16 strands was considered, and these distributions are calculated for different transpositions using the finite-element method. In the finite-element method model, the circulating currents are calculated by subtracting a load current at each strand from the total of strand current. Also, for different transpositions, such as 90°, 180°, 360°, and 540°, the circulating currents are calculated using an analytical method. The obtained strand current distributions from the 2D dual model have good agreement with the obtained results from the analytical method for the 180° and 360° transposed coil models.