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Y and Eu co-doped nano-TiO2 photocatalysts were successfully prepared via a sol-gel method and characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), ultraviolet-visible spectrophotometry(UV-vis), photoluminescence(PL) and Fourier transform infrared(FT-IR) spectra. Experimental results indicated that Y and Eu doping inhibited the growth of crystalline size and the transformation from anatase to rutile phase and had the function of reducing particle reunion. At the same time, co-doping could also enhance the absorption in visible region and then narrowed the band gap. The photocatalytic activities of the samples were evaluated by the degradation of methylene blue(MB) under ultraviolet(UV) light irradiation, which showed much enhanced photocatalytic activities over un-doped TiO2. The degradation rate of 1.5% Y/Eu-TiO2 of methylene blue was 86%, which was about 5 times of that of un-doped TiO2, and the possible reasons for the improvement of photocatalytic activities were analyzed. In this experiment, the dopant amount of rare earth was 1.5% and the ratio of Y:Eu was 2:3 for the maximum photocatalytic degradation, and the sample calcined at 500 oC showed the best reactivity. For the best samples above, the removal rate of phenol under visble light was 53% whthin 2 h. 相似文献
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以钛酸四丁酯、硝酸镧和氟化钠等为原料,采用原位掺杂的方式制备了La-F两步共掺杂TiO2光催化剂。通过XRD、SEM、XPS和UV-Vis对样品进行了表征,并对样品进行了光催化性能及电化学交流阻抗的测试。结果表明所制样品均为锐钛矿型TiO2,La-F共掺杂使TiO2的晶格发生了较大畸变且晶粒得到了细化,两步共掺杂会加剧样品颗粒间的团聚,同时两步共掺杂也使TiO2的吸收带边发生红移,禁带宽度降低。两步共掺杂样品中TiO2与Lax-Fy-TiO2之间形成的n-n异质结,由于二者费米能级不同而形成的内建电场,对半导体内部电子起到定向的迁移作用,从而有效降低光生电子-空穴的复合,提高载流子浓度。当La和F的掺杂比例分别为1.5%和10%时,两步共掺杂样品的载流子浓度为1.5×1020/cm-3,对亚甲基蓝表现出优异的可见光降解效果,120min降解率达到96%,为同等条件下纯TiO2的2.6倍。 相似文献
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为提高内燃机中回转运动副,特别是曲轴等运动件的润滑效果,建立了一套由基本试验平台、标定和试验回路构成的用于研究黏性流体在管路中流动特性的实验系统.基于Bernoulli方程等,试验研究了3种润滑油的流动摩擦因数、管件出口流量系数、能量损失系数.研究表明:在雷诺数为10<Re<140范围内的流动特性参数实验系统是有效和适用的,为预测和深入研究对应管路中流体的流动特性提供了基础. 相似文献