Effects of alkali and alkaline-earth cations on the high-pressure sound velocities of aluminosilicate glasses

Physics and Chemistry of Minerals - A black tourmaline sample from Seagull batholith (Yukon Territory, Canada) was established to be a schorl with concentrations of Fe2+ among the highest currently...     

Temporal variations of surface oceanic and atmospheric CO2 fugacity and total dissolved inorganic carbon in the northwestern North Pacific

In order to examine temporal variations of the surface oceanic and atmospheric fCO₂ and the DIC concentration, we analyzed air and seawater samples collected during the period May 1992–June 1996 in the northwestern North Pacific, about 30 km off the coast of the main island of Japan. The atmospheric CO₂ concentration has increased secularly at a rate of 1.9 ppmv yr⁻¹, and it showed a clear seasonal cycle with a maximum in spring and a minimum late in summer, produced mainly by seasonally-dependent terrestrial biospheric activities. DIC also showed a prominent seasonal cycle in the surface ocean; the minimum and maximum values of the cycle appeared in early fall and in early spring, respectively, due primarily to the seasonally-dependent activities of marine biota and partly to the vertical mixing of seawater and the coastal upwelling. The oceanic fCO₂ values were almost always lower than those of the atmospheric fCO₂, suggesting that this area of the ocean acts as a sink for atmospheric CO₂. Values varied seasonally, mainly reflecting seasonal changes of SST and DIC, with a secular increase at a rate of 3.7 μatm yr⁻¹. The average values of the annual net CO₂ flux between the ocean and the atmosphere calculated by using the different bulk equations ranged between −0.8 and −1.7 mol m⁻²yr⁻¹, and its magnitude was enhanced and reduced late in spring and mid-summer, respectively, due mainly to the seasonally varying oceanic fCO₂.     

Dietary shift and feeding intensity of <Emphasis Type="Italic">Stenobrachius leucopsarus</Emphasis> in the Bering Sea

The food habits of the dominant myctophid Stenobrachius leucopsarus were examined in the central basin of the Bering Sea in relation to oceanographic conditions, in summer 2002 and 2003 and spring 2006. S. leucopsarus exhibited an ontogenetic and seasonal dietary shift. In spring, small fish (≤40 mm) preyed mainly on Neocalanus flemingeri/plumchrus whereas large fish fed mainly on Neocalanus cristatus. In summer, small fish preyed mainly on Metridia pacifica whereas large fish fed mainly on euphausiids (Thysanoessa spp.). In the summer of 2003, when water temperature in the epipelagic layer (≤100 m) was warmer, reflecting the prevalence of the Alaskan Stream, small-sized S. leucopsarus showed a higher stomach content index, perhaps reflecting the greater abundance of M. pacifica. Thus, the present study shows that the physical variability in the epipelagic layer affects not only diets but also feeding performance of micronekton.     

Does measuring azimuthal variations in sap flux lead to more reliable stand transpiration estimates?

Stand transpiration (E) estimated using the sap‐flux method includes uncertainty induced by variations in sap flux (F) within a tree (i.e. radial and azimuthal variations) and those between trees. Unlike radial variations, azimuthal variations are not particularly systematic (i.e. higher/lower F is not always recorded for a specific direction). Here, we present a theoretical framework to address the question on how to allocate a limited number of sensors to minimize uncertainty in E estimates. Specifically, we compare uncertainty in E estimates for two cases: (1) measuring F for two or more directions to cover azimuthal variations in F and (2) measuring F for one direction to cover between‐tree variations in F. The framework formulates the variation in the probability density function for E (σ_E) based on F recorded in m different azimuthal directions (e.g. north, east, south and west). This formula allows us to determine the m value that minimizes σ_E. This study applied the framework to F data recorded for a 55‐year‐old Cryptomeria japonica stand. σ_E for m = 1 was found to be less than the values for m = 2, 3 and 4. Our results suggest that measuring F for one azimuthal direction provides more reliable E estimates than measuring F for two or more azimuthal directions for this stand, given a limited number of sensors. Application of this framework to other datasets helps us decide how to allocate sensors most effectively. Copyright © 2016 John Wiley & Sons, Ltd.     

Image analysis of the solar corona from the July 11, 1991 eclipse

Morphological properties of the corona and coronal structures, and modifications occurring in a time span greater than 3 hours were investigated through image analysis of three successive color pictures obtained by the Multi-station International Coronal Experiment (MICE). The model of Saito and Akasofu (1987) for the general magnetic field of the Sun was a suitable framework for interpreting the observational results. Color-index images allowed a closer inspection of the relationships between rays and underlying chromospheric activity. Besides the chromospheric active centres, the rays exhibited clear morphological alterations. Suggestions are presented for future observational efforts searching for slight morphological changes and tiny fluctuations in brightness and color-indices.     

Precessing jets interacting with interstellar material as the origin for the light curves of gamma-ray bursts

We present an internal shock model with external characteristics for explaining the complicated light curves of gamma-ray bursts. Shocks produce gamma-rays in the interaction between a precessing beam of relativistic particles and the interstellar medium. Each time the particle beam passes the same line of sight with the observer the interstellar medium is pushed outward. Subsequent interactions between the medium and the beam are delayed by the extra distance to be travelled for the particles before the shock can form. This results in a natural retardation and leads to an intrinsic asymmetry in the light curves produced for gamma-ray bursts. In addition, we account for the cooling of the electron–proton plasma in the shocked region, which gives rise to an exponential decay in the gamma-ray flux. The combination of these effects and the precessing jet of ultrarelativistic particles produces light curves that can be directly compared with observed gamma-ray burst light curves. We illustrate the model by fitting a number of observed gamma-ray bursts that are difficult to explain with only a precessing jet. We develop a genetic algorithm to fit several observed gamma-ray bursts with remarkable accuracy. We find that for different bursts the observed fluence, assuming isotropic emission, easily varies over four orders of magnitude from the energy generated intrinsically.     

A crystal chemical study of protoanthophyllite: orthoamphiboles with the protoamphibole structure

Two new protoamphibole-type amphiboles with space group type Pnmn, have been found in nature: protoferro-anthophyllite (Fe_0.80Mn_0.20)₂ (Fe_0.98Mg_0.02)₅ (Si₄O₁₁)₂(OH)₂, and protomangano-ferro-anthophyllite, (Mn_0.70Fe_0.30)₂ (Fe_0.82Mg_0.18)₅ (Si₄O₁₁)₂(OH)₂. Protoferro-anthophyllite (PFA) occurs in pegmatites at both Gifu Prefecture, Japan and at Cheyenne Mountain, El Paso County, Colorado, USA. Protomangano-ferro-anthophyllite, (PMFA) occurs in pegmatites at Fukushima Prefecture and in a Mn mine at Tochigi Prefecture, Japan. Structure determinations of the two amphiboles show that both are isostructural with the synthetic fluorian-amphibole, protoamphibole (= protofluorian-lithian-anthophyllite). A calculation of the procrystal electron density distributions, the bond paths and the bond critical point properties of PFA, PMFA, grunerite and protoamphibole indicates that the M4 cation in these amphiboles is 4-coordinated. A calculation of the electron density distributions at the Becke3LYP/6-311G(2d,p) level for model silicate tetrahedra for these amphiboles and anthophyllite reveals that the value of the electron density at the bond critical points, ρ(r _c ), for the SiO(nbr) bonds is larger, on average (0.93 e/ų), than that for the SiO(br) bonds (0.90 e/ų). The observed SiO bond lengths decrease linearly with increasing ρ(r _c ) while the magnitudes of the curvatures of ρ(r _c ) both perpendicular and parallel to the bonds and the Laplacian of ρ(r _c ) each increases. These trends are associated with an increase in the electronegativity of the Si cation, a possible increase in the covalent character of the SiO bond and a tendency for SiO(nbr) bonds to be involved in wider OSiO angles than SiO(br) bonds. It is possible, if not likely, that protoanthophyllite has often been misidentified as anthophyllite.     

Pre-Japan-ARGO: Experimental Observation of Upper and Middle Layers South of the Kuroshio Extension Region Using Profiling Floats

We deployed two profiling floats in the region south of the Kuroshio Extension in March 2000. Temperature and salinity profiles from a depth of 1500 × 10⁴ Pa to the surface are reported every two and four weeks, respectively. The floats performed very well for first four months after deployment. Later they failed in surfacing for a few months when the sea surface temperature in the region was high. The salinity sensors seemed to suffer from some damage during their failure-in-surfacing period. Despite this trouble, the results clearly demonstrate that the profiling float is a very useful and cost-effective tool for physical oceanographic observation in the open sea. This revised version was published online in July 2006 with corrections to the Cover Date.     

Graphitization of carbonaceous matter during metamorphism with references to carbonate and pelitic rocks of contact and regional metamorphisms,Japan

This study is an attempt to correlate the graphitization process of carbonaceous matter during metamorphism with metamorphic grade. Graphitization can be parameterized using crystal structure and chemical and isotopic compositions. The extent of graphitization could be characterized mainly by temperature, duration of metamorphism and rock composition. We compared the graphitization trends for two metamorphic terrains, a contact aureole of the Kasuga area and a regional metamorphic terrain of high-temperature/low pressure type of the Ryoke metamorphic terrain in Northern Kiso area, Central Japan, and for two different lithologies (carbonate and pelite), using X-ray diffractogram, DTA-TG analysis, and chemical and stable isotope analyses. During contact metamorphism, graphitization and carbon isotopic exchange reactions proceeded simultaneously in pelitic and carbonate rocks. The decreases in basal spacing d(002) of the carbonaceous matter in carbonate rocks is greatly accelerated at temperatures higher than about 400° C. Furthermore, carbon isotopic ratios of graphite in carbonate rocks also change to ¹³C-enriched values implying exchange with carbonates. The beginning of this enrichment of ¹³C in the carbonaceous matter coincides with an abrupt increase of the graphitization processes. Carbon isotopic shifting up to 5 in pelites could be observed as metamorphic temperature increased probably by about 400° C. Carbonaceous matter in pelitic rocks is sometimes a mixture of poorly crystallized organic matter and well-crystallized graphite detritus. DTA-TG analysis is an effective tool for the distinction of detrital graphitic material. Two sources for the original carbon isotopic composition of carbonaceous matter in pelites in the Kasuga contact aureole can be distinguished, about-28 and-24 regardless of the presence of detrital graphite, and were mainly controlled by depositional environment of the sediments. Graphitization in limestones and pelitic rocks in regional metamorphism proceeds further than in a contact aureole. In the low-temperature range, the differences in extent of graphitization between the two metamorphic regions is large. However, at temperatures higher than 600° C, the extent of graphitization in both regions is indistinguishable. The degree of graphitization is different in limestones and pelitic rocks from the Ryoke metamorphic terrain. We demonstrate that the graphitization involves a progressive re-construction process of the crystal structure. The sequence of the first appearance of crystal inter planar spacing correlates with the metamorphic grade and indicates the crystal growth of three-dimensional structured graphite.     

An application of a two-layer model to wind driven sub-tidal currents in Puget Sound

A two layer model of an infinitely long channel, with one end closed, is applied to study the sub-tidal response to wind forcing of Puget Sound. The model uses a linear friction parameterization. Data show that the acceleration of current near the surface responds to the wind event almost instantaneously, however, acceleration tends to start decreasing at later times and eventually changes sign even though the wind blows in one direction throughout. Analysis of the model results show that when the forcing frequency is high, the phase lag between forcing and friction causes this phenomena, and as forcing frequency increases, phase lag between forcing and friction approaches /2. When the forcing frequency is low, phase lag between forcing and friction decreases almost linearly with forcing frequency and at extremely low frequency, they almost balance each other. Analysis of the model results show also that the amplitude of baroclinic pressure gradient increases rapidly as forcing frequency decreases and when the forcing frequency is low, the baroclinic pressure gradient becomes important. Effects of baroclinic pressure gradient propagate as a wave from the boundaries and it takes about one day to take effect at the point where the observations were made.