A preliminary study of carbon system in the East China Sea

In the central part of the East China Sea, the activity of CO₂ in the surface water and total carbonate, pH and alkalinity in the water column were determined in winter and autumn of 1993. The activity of CO₂ in the continental shelf water was about 50 ppm lower than that of surface air. This decrease corresponds to the absorption of about 40 gC/m²/yr of atmospheric CO₂ in the coastal zone or 1 GtC/yr in the global continental shelf, if this rate is applicable to entire coastal seas. The normalized total carbonate contents were higher in the water near the coast and near the bottom. This increase toward the bottom may be due to the organic matter deposited on the bottom. This conclusion is supported by the distribution of pH. The normalized alkalinity distribution also showed higher values in the near-coast water, but in the surface water, indicating the supply of bicarbonate from river water. The residence time of the East China Sea water, including the Yellow Sea water, has been calculated to be about 0.8 yr from the excess alkalinity and the alkalinity input. Using this residence time and the excess carbonate, we can estimate that the amount of dissolved carbonate transported from the coastal zone to the oceanic basin is about 70 gC/m²/yr or 2 GtC/yr/area-of-global-continental-shelf. This also means that the rivers transport carbon to the oceans at a rate of 30 gC/m²/yr of the coastal sea or 0.8 GtC/yr/ area-of-global shelf, the carbon consisting of dissolved inorganic carbonate and terrestrial organic carbon decomposed on the continental shelf.     

Air-Sea Gas Transfer Velocity in Stormy Winter Estimated from Radon Deficiency

Thirteen vertical profiles of ²²⁶Ra and ²²²Rn in the near-surface water were obtained in the western North Pacific in winter, and the gas transfer velocities across the air-sea interface were estimated. The transfer velocities found by applying a steady state model varied widely from 2.1 to 30.2 m day⁻¹ with a mean of 9.4 m day⁻¹. The mean value is almost 5 times higher than that in summer in other oceans, and the maximum value is a record high for world oceans. This is partly due to the inadequacy of the steady state model, which overestimates when stronger winds blow in more recent days than the ²²²Rn half-life of about 4 days. In fact, a strong low pressure zone passed through the station about 2 days earlier, which was one of the low pressure zones that with a period of develop once a week or so in the northwestern North Pacific in winter. Instead of steady-state removal, if half of the radon removal occurred sporadically every 7 days, and the last removal took place two days before the observation, the transfer velocity would be 26 m day⁻¹. Our mean transfer velocity, which is less than 20% different from the steady state value including both overestimated and underestimated values, 9.4 ± 4.8 m day⁻¹, seems to represent the mean state of this region in winter. This suggests that the gas exchange fluxes under extremely rough conditions in the open ocean are larger than those estimated by using a transfer velocity equation with a linear or quadratic relationship with wind speed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Radiocarbon anomaly found in aquicultural scallops suspended in coastal sea

The radiocarbon content of scallops aquiculturally suspended and grown in coastal sea, Funka Bay, were determined. While the ¹⁴C values of carbonate shells coincided with that of ambient seawater, those of soft tissues were smaller than the seawater value and varied rather widely. To clarify the cause of this variation, we further divided the soft tissues of composite scallops into each organ and determined their radiocarbon content. The results show that only the ¹⁴C of adductor (Kaibashira in Japanese) of scallops was significantly smaller than the others, those of gill and mantle coincided to that of seawater. This strange finding cannot be explained by the present knowledge on the dietary sources of scallops and the present theory of isotopic fractionation, unless any unknown physiological or oceanographical process determines the radiocarbon content of the organisms.     

超浅海风暴潮的数值模拟(一)——零阶模型对渤海风潮的初步应用

由我国北方的寒潮或冷空气所引起的渤海风潮,按文献的分析,该属于“超浅海风暴潮”类型.以渤海风潮为例,按超浅海风暴潮理论进行数值计算,不仅对该理论是一有力的检验,且对探讨渤海风潮的机制和预报也是一个有益的参考. 将冷锋所造成的大风风场重现在计算网格上,在现场海面风资料极度贫乏的情况下,显然是一较难的课题.本文仅就发生渤海风潮时,渤海上空风场的几个主要力学特征,设计了几个理论模式风应力场,对渤海风潮进行了数值计算,以期获得全过程概貌及主要特征.计算结果达到了这一预期目的.     

Polar and neutral isopranyl glycerol ether lipids as biomarkers of archaea in near-surface sediments from the Nankai Trough

The molecular and carbon isotopic compositions of polar isopranyl glycerol ether lipids, which are direct indicators of viable archaea, and neutral isopranyl glycerol ether lipids, which are derived from polar lipids via hydrolysis, in near-surface sediments from a methane seep in the Nankai Trough (off central Japan) were investigated. Procedures for extracting, separating and derivatizing polar and neutral ether lipids for detection using gas chromatography were first examined with one sediment sample and a cultivated methanogen. For all sediment samples, archaeol and hydroxyarchaeol were detected in both the polar and neutral ether lipid fractions. Acyclic and cyclic biphytanes were also detected in both types of lipid fractions after treatment with HI/LiAlH₄ for ether cleavage and alkylation. The δ¹³C values of archaeol, sn-2-hydroxyarchaeol, and sn-3-hydroxyarchaeol in the sample from 0.82 m below the seafloor were lower than −100‰ relative to PDB, indicating that diverse living methanotrophic archaea are present in the seep sediments. Biphytanes released from polar ether lipids in the same sample were less depleted in δ¹³C (−71‰ to −36‰). The wide range of δ¹³C values suggests that the biphytanes were derived not only from methanotrophic but also from non-methanotrophic archaea, and that the relative contributions of the methanotrophic and non-methanotrophic archaea differed, depending on the biphytane compound. The vertical profiles and δ¹³C values of the neutral ether lipids were similar to those of the intact polar ether lipids, suggesting that neutral ether lipids derived from fossil archaea in the samples had mainly been lost by the time of sampling.     

Numerical study on inter-tidal transports in coastal seas

Inter-tidal(subtidal) transport processes in coastal sea depend on the residual motion, turbulent dispersion and relevant sources/sinks. In Feng et al.(2008), an updated Lagrangian inter-tidal transport equation, as well as new concept of Lagrangian in- ter-tidal concentration(LIC), has been proposed for a general nonlinear shallow water system. In the present study, the LIC is nu- merically applied for the first time to passive tracers in idealized settings and salinity in the Bohai Sea, China. Circulation and tracer motion in the three idealized model seas with different topography or coastline, termed as ‘flat-bottom', ‘stairs' and ‘cape' case, re- spectively, are simulated. The dependence of the LIC on initial tidal phase suggests that the nonlinearities in the stairs and cape cases are stronger than that in the flat-bottom case. Therefore, the ‘flat-bottom' case still meets the convectively weakly nonlinear condi- tion. For the Bohai Sea, the simulation results show that most parts of it still meet the weakly nonlinear condition. However, the de- pendence of the LIS(Lagrangian inter-tidal salinity) on initial tidal phase is significant around the southern headland of the Liaodong Peninsula and near the mouth of the Yellow River. The nonlinearity in the former region is mainly related to the complicated coast- lines, and that in the latter region is due to the presence of the estuarine salinity front.     

观测分析El Ni?o衰减早晚对南亚与青藏高原夏季降水和气温的影响

El Ni?o（厄尔尼诺）事件对东亚和南亚次年夏季降水影响及其机理已经得到充分研究,但其对夏季青藏高原降水是否有显著影响还不清楚。本研究根据1950年后El Ni?o事件次年衰减期演变速度,对比分析衰减早型与晚型El Ni?o事件对南亚季风区与青藏高原夏季（6～9月）季节平均和月平均气候影响差异。结果显示在衰减早型次年夏季热带太平洋海温转为La Ni?a（拉尼娜）型且持续发展,引起Walker环流上升支西移,印度洋和南亚季风区上升运动加强,同时激发异常西北太平洋反气旋（NWPAC）,阿拉伯海异常气旋和伊朗高原异常反气旋性环流响应,增加7～9月对流层偏南气流和印度洋水汽输送,导致南亚和高原西南侧降水偏多。衰减晚型次年6～8月热带太平洋El Ni?o型海温仍维持,印度洋暖异常海温显著,对应的印度洋和南亚季风区上升运动较弱,NWPAC西伸控制南亚季风区,阿拉伯海和中西亚分别呈现异常反气旋和气旋性环流,导致青藏高原西风加强,水汽输送减少,南亚北部和高原降水一致偏少。结果表明:（1）El Ni?o显著影响次年青藏高原西南部夏季季节和月平均降水与温度,是印度和高原西南部夏季降水显著相关的重要原因;（2）El Ni?o衰减快慢速度对南亚和青藏高原西南部夏季季节内降水的影响有着重要差异。     

Origin of calcium in aerosols over the western North Pacific

Weekly aerosol samples were collected from March 1981 to June 1983 at the six stations in the western North Pacific region and analyzed for Ca and Na. By coupling data with those previously reported for Al (Tsunogai et al., 1985), the following results and conclusion have been obtained. There was a positive correlation between the atmospheric concentration of Al and the concentration of nonsea salt Ca (nssCa). The nssCa/Al ratios from the six stations, however, considerably varied (from 0.84±0.36 to 3.00±1.91), and the ratios were usally larger than those of the crustal average or of usual soil in Japan. The Ca/Al ratios of Asian desert soil and loess vary from 0.52 to 1.29, which are similar to the nssCa/Al ratios of aerosols in the surface air over the western North Pacific region except at Onna, Okinawa. The exception may be due to a local effect of coral. These results suggest that a large part of nonsea salt Ca in the surface air over the western North Pacific is derived from arid regions in Asia and that the nssCa/Al ratio in aerosol varies with that of the source material.     

Annual cycle and budgets of nutrients in the Bohai sea

The environmental problems in the Bohai Sea have become more serious in the last decade. High nutrient concentration contributes much to it. A Sino-German cooperation program has been carried out to improve the understanding of the ecosystem by observations and modelling. A three-dimensional ecosystem model, coupled with a physical transport model, is adopted in this study. The simulation for the year 1982 is validated by the data collected in 1982/1983. The simulated annual mean nutrient concentrations are in good agreement with observations. The nutrient concentrations in the bohai Sea, which are crucial to the algal growth, are high in winter and low in summer. There are depletion from spring to summer and elevation from autumn to winter for nutrients. The nutrients’ depletion is a response to the consumption of the phytoplankton bloom in spring. Internal recycle and external compensation affect the nutrient cycle. Their contributions to the nutrient budgets are discussed based on the simulated results. Production and respiration are the most important sink and source of nutrients. The process of photosynthesis consumes 152 kilotons-P and 831.1 kilotons-N while respiration releases 94.5 kilotons-P and 516.6 kilotons-N in the same period. The remineralization of the detritus pool is an important source of nutrient regeneration, It can compensate 23 percent of the nutrient consumed by the production process. The inputs of phosphates and nitrogen from rivers are 0.55 and 52.7 kilotons respectively. The net nutrient budget is −3.05 kilotons-P and 31.6 kilotons-N.