Polycyclic aromatic hydrocarbons in commercial fish and lobsters from the coastal waters of Madagascar following an oil spill in August 2009

Concentrations of polycyclic aromatic hydrocarbons were determined in species of commercial fish and lobsters following an oil-spill just off the protected Madagascan coastline. Samples were collected along the coastline within and outside the affected area. Summed PAH concentrations ranged from 1.9 μg kg⁻¹ to 63 μg kg⁻¹ wet weight, but with no higher molecular weight PAHs (>202 Da) being detected. All concentrations of benzo[a]pyrene, benz[a]anthracene and dibenz[a,h]anthracene were <0.1 μg kg⁻¹ wet weight, well within the EU and UK set limits for the protection of human health. Additionally, samples were calculated as the benzo[a]pyrene toxic equivalency quotient (TEQ) and found to be well below the level of concern in relation to health of human consumers. Evaluation of the biota PAH data indicated the origin of PAH was predominantly petrogenic with >80% arising from oil sources. Profile studies indicate a low-level multisource petrogenic contamination probably representing a pre-spill background for the area.     

Polycyclic aromatic hydrocarbons in sediments,mussels and crustacea around a former gasworks site in Shoreham-by-Sea,UK

Concentrations of polycyclic aromatic hydrocarbons have been determined in sediments, mussels and crustacea in the vicinity of a former gasworks site by Shoreham Harbour, UK. Very high concentrations of PAH were found in the substrate, an ash-like material deposited on the former gasworks site, which exhibited a profile consistent with the major source of contamination being coal or coke tar produced during the period of gas production at the site. Elevated PAH concentrations were also found in mussels both from the beach below the former gasworks site, and from sites further to the east in Portslade and Hove. The significance of these concentrations were assessed using an approach which involved the calculation of benzo[a]pyrene equivalent conoentrations (BaPEs), summing concentrations of individual PAH on the basis of their comparative potency as carcinogens. BaPE ranged from values of, or close to, zero for crustacea, to 336 microg kg(-1) wet weight in mussels from Southwick Beach. The contaminated mussels are not exploited commercially but may be taken by casual gatherers, and notices have been posted to warn potential consumers.     

Buried paleo-channels on the New Jersey continental margin: channel porosity structures from electromagnetic surveying

We report on a marine electromagnetic (EM) survey across two portions of the New Jersey continental margin that have been previously shown to contain buried paleo-channels. The EM method used provides bulk porosity estimates to depths of around 20 m below the seafloor and is thus able to place porosity constraints on the nature of the channel infill and the contrast in physical properties across the channel boundaries. Our data show that a key condition for the channels to have an electrical signature is that they incise an underlying regional unconformity, R, thought to represent a subaerially eroded surface, exposed during the late Wisconsinan glaciation. Channels that cut R are seen through increases in apparent porosity. Another seismically imaged channel sequence, which lies within the outer-shelf sediment wedge sequence above R, does not have an electrical signature, indicating that the sediments above and below the channel boundaries have similar physical properties.     

Applicability of Kinetic Models for In Situ Combustion Processes with Different Oil Types

The in situ combustion (ISC) process is of interest as an enhanced oil recovery method because it is an alternative to traditional steam-based processes for heavy oil and bitumen recovery. ISC is a technique applicable outside the window of reservoir conditions deemed appropriate for steam injection (such as deeper and thinner reservoirs). The process involves complex chemical reactions and physical recovery mechanisms, and predicting the likelihood of successful ISC in field applications remains challenging. This paper describes a numerical investigation of the capability of different ISC kinetic models to predict the combustion behaviors of different types of oils (light oil, heavy oil, and bitumen). Three kinetic models (of Coats, Crookston, and Belgrave) were selected from literature and compared using data from four published combustion-tube experiments. The comparison procedure is as follows: (1) validate the numerical modeling of each kinetic model by matching the selected experimental results or duplicating the numerical results found in published literature; (2) adjust fluid viscosities and densities to match the fluid properties of each experiment;and (3) use each validated kinetic model to predict the performance of the other experiments without further tuning the kinetic parameters. The knowledge derived from the experiments provides guidance for choosing the appropriate kinetic model when no other data are available and for the preliminary design and screening study of a potential ISC project.     

地勘部门建筑施工企业应关注的法律问题

从案例分析入手，列举并分析地勘部门工程施工企业应关注的工程合同要体、主体资格规定、各种程序要件及有关的法律知识，以使地勘部门工程施工企业能够把握这些内容，维护自身的合法权益。     

The interaction of binary vortices in a barotropic model

Summary The interaction of binary cyclonic vortices is investigated using the nondivergent barotropic model of Chan and Williams (1987) under two situations: a quiescent environment and a linearly-sheared background flow. It is found that the mutual interaction between the vortices results from a combination of two processes: the advection of symmetric vorticity by the asymmetric flow and the advection of asymmetric vorticity by the symmetric flow. The latter contribution is rather significant. Whether the vortices in a binary system attract or repel each other depends on the asymmetric vorticity distribution associated with the two vortices. Such a distribution is governed by the structure (size) of and the separation between the vortices. In the presence of a sheared flow, the contribution from the advection of asymmetric vorticity by the symmetric flow may also become appreciable depending on the structure and magnitude of the shear. Furthermore, the geographical locations of the vortices in relation to the sheared flow are also important in determining the relative movement of the vortices.In the presence of , the movements of the vortices are modified by the northwestward -drift However, the relative motion between the vortices is almost identical to that on an f-plane. In other words, the mutual interaction between the vortices is largely independent of . Alternatively, the two vortices can be considered to be one system which drifts towards the northwest under the influence of while they interact with each other within the system. Physically, this independence arises because the two relative vorticity advection terms have much larger magnitudes than the planetary vorticity advection term. However, the -effect is still important in that it modifies the asymmetric flow associated with each vortex and hence the asymmetric vorticity. Such modifications change the advection patterns compared with the =0 case and hence lead to different vortex movements. The presence of a linear shear causes the binary system to move as if it was a large (for a cyclonic shear) or smaller (for an anticyclonic shear) vortex under the influence of .With 22 Figures     

Garnet morphology distribution in the northern part of the Moine Supergroup,Scottish Caledonides

Garnet is a versatile and useful indicator mineral exploited in numerous geological studies. Despite its utility in providing thermobarometry and geochronology constraints, many difficulties remain in making meaningful interpretations of such data. In this paper, we characterize garnet grains from over 140 garnet‐bearing metasedimentary rock samples collected from the northern part of the Moine Supergroup (Scottish Caledonides). Large, euhedral garnet grains are interpreted to be indicative of prograde metamorphic growth during the most recent (Scandian, c. 430 Ma) phase of orogenesis. Anhedral garnet is largely restricted to the relatively low‐grade (greenschist – lower amphibolite facies) Moine thrust sheet, with an abrupt change in morphology and grain size when traced across the overlying Ben Hope and Sgurr Beag thrusts into the higher grade, more hinterland‐positioned thrust sheets. Our results suggest that caution should be exercised in using anhedral garnet in the Moine thrust sheet to estimate peak P–T conditions associated with low temperature (< ~500 °C) Scandian metamorphism, because in at least some cases garnet growth may have occurred during an earlier metamorphic event. However, chemical and isotopic data from this structurally lower anhedral garnet may still be useful for deconvolving a possible polymetamorphic history for this thrust sheet. In the immediately overlying Ben Hope thrust sheet, garnet has prograde euhedral (Scandian?) rims, indicating that the Ben Hope thrust must represent a significant thermal and/or chemical break. Inclusion distribution and mineral assemblages in garnet have been used to gain further insight on garnet growth conditions and to distinguish garnet that likely contains multiple generations of growth. Although our results are specific to the Caledonides of northern Scotland, this work highlights the general necessity of a comprehensive petrographic assessment in advance of interpreting large suites of garnet‐derived thermodynamic and geochronological data.