Pre‐drill Groundwater Geochemistry in the Karoo Basin,South Africa

Enhanced production of unconventional hydrocarbons in the United States has driven interest in natural gas development globally, but simultaneously raised concerns regarding water quantity and quality impacts associated with hydrocarbon extraction. We conducted a pre‐development assessment of groundwater geochemistry in the critically water‐restricted Karoo Basin, South Africa. Twenty‐two springs and groundwater samples were analyzed for major dissolved ions, trace elements, water stable isotopes, strontium and boron isotopes, hydrocarbons and helium composition. The data revealed three end‐members: a deep, saline groundwater with a sodium‐chloride composition, an old, deep freshwater with a sodium‐bicarbonate‐chloride composition and a shallow, calcium‐bicarbonate freshwater. In a few cases, we identified direct mixing of the deep saline water and shallow groundwater. Stable water isotopes indicate that the shallow groundwater was controlled by evaporation in arid conditions, while the saline waters were diluted by apparently fossil meteoric water originated under wetter climatic conditions. These geochemical and isotopic data, in combination with elevated helium levels, suggest that exogenous fluids are the source of the saline groundwater and originated from remnant seawater prior to dilution by old meteoric water combined with further modification by water‐rock interactions. Samples with elevated methane concentrations (>14 ccSTP/kg) were strongly associated with the sodium‐chloride water located near dolerite intrusions, which likely provide a preferential pathway for vertical migration of deeply sourced hydrocarbon‐rich saline waters to the surface. This pre‐drill evaluation indicates that the natural migration of methane‐ and salt‐rich waters provides a source of geogenic contamination to shallow aquifers prior to shale gas development in the Karoo Basin.     

Heterogeneity influences on stream water–groundwater interactions in a gravel-dominated floodplain

ABSTRACT

Floodplains are composed of complex depositional patterns of ancient and recent stream sediments, and research is needed to address the manner in which coarse floodplain materials affect stream–groundwater exchange patterns. Efforts to understand the heterogeneity of aquifers have utilized numerous techniques typically focused on point-scale measurements; however, in highly heterogeneous settings, the ability to model heterogeneity is dependent on the data density and spatial distribution. The objective of this research was to investigate the correlation between broad-scale methodologies for detecting heterogeneity and the observed spatial variability in stream/groundwater interactions of gravel-dominated alluvial floodplains. More specifically, this study examined the correlation between electrical resistivity (ER) and alluvial groundwater patterns during a flood event at a site on Barren Fork Creek, in the Ozark ecoregion of Oklahoma, USA, where chert gravels were common both as streambed and as floodplain material. Water table elevations from groundwater monitoring wells for a flood event on 1–5 May 2009 were compared to ER maps at various elevations. Areas with high ER matched areas with lower water table slope at the same elevation. This research demonstrated that ER approaches were capable of indicating heterogeneity in surface water–groundwater interactions, and that these heterogeneities were present even in an aquifer matrix characterized as highly conductive. Portions of gravel-dominated floodplain vadose zones characterized by high hydraulic conductivity features can result in heterogeneous flow patterns when the vadose zone of alluvial floodplains activates during storm events.

EDITOR D. Koutsoyiannis; ASSOCIATE EDITOR X. Chen     

Biodiversity in Hudson River shore zones: influence of shoreline type and physical structure

The shore zones of the Hudson River, like those of many developed waterways, are highly varied, containing a mix of seminatural and highly engineered shores. Our goal was to document the biodiversity supported by different kinds of shore zones in the Hudson. We chose six common types of shore zones, three of them ??natural?? (sand, unconsolidated rock, and bedrock), and three of them engineered (riprap, cribbing, and bulkheads). We measured selected physical characteristics (shore zone width, exposure, substrate roughness and grain size, shoreline complexity) of three examples of each of these shore types, and also sampled communities of terrestrial plants, fishes, and aquatic and terrestrial invertebrates. Community composition of most taxa differed across shore types, and frequently differed between wide, sheltered shores and narrow, exposed shores. Alien plant species were especially well represented along engineered shores. Nevertheless, a great deal of variation in biological communities was not explained by our six-class categorization of shore zones or the physical variables that we measured. No single shore type supported the highest values of all kinds of biodiversity, but engineered shore zones (especially cribbing and bulkheads) tended to have less desirable biodiversity characteristics than ??natural?? shore zones.     

Cytochrome P4501A biomarker indication of the timeline of chronic exposure of Barrow's goldeneyes to residual Exxon Valdez oil

We examined hepatic EROD activity, as an indicator of CYP1A induction, in Barrow’s goldeneyes captured in areas oiled during the 1989 Exxon Valdez spill and those from nearby unoiled areas. We found that average EROD activity differed between areas during 2005, although the magnitude of the difference was reduced relative to a previous study from 1996/1997, and we found that areas did not differ by 2009. Similarly, we found that the proportion of individuals captured from oiled areas with elevated EROD activity (?2 times unoiled average) declined from 41% in winter 1996/1997 to 10% in 2005 and 15% in 2009. This work adds to a body of literature describing the timelines over which vertebrates were exposed to residual Exxon Valdez oil and indicates that, for Barrow’s goldeneyes in Prince William Sound, exposure persisted for many years with evidence of substantially reduced exposure by 2 decades after the spill.     

Evaluating a process‐based model for use in streambank stabilization: insights on the Bank Stability and Toe Erosion Model (BSTEM)

Streambank retreat is a complex cyclical process involving subaerial processes, fluvial erosion, seepage erosion, and geotechnical failures and is driven by several soil properties that themselves are temporally and spatially variable. Therefore, it can be extremely challenging to predict and model the erosion and consequent retreat of streambanks. However, modeling streambank retreat has many important applications, including the design and assessment of mitigation strategies for stream revitalization and stabilization. In order to highlight the current complexities of modeling streambank retreat and to suggest future research areas, this paper reviewed one of the most comprehensive streambank retreat models available, the Bank Stability and Toe Erosion Model (BSTEM), which has recently been integrated with several popular hydrodynamic and sediment transport models including the Hydrologic Engineering Center's River Analysis System (HEC‐RAS). The objectives of this paper were to: (i) comprehensively review studies that have utilized BSTEM and report their findings, (ii) address the limitations of the model so that it can be applied appropriately in its current form, and (iii) suggest directions of research that will help make the model a more useful tool in future applications. The paper includes an extensive overview of peer reviewed studies to guide future users of BSTEM. The review demonstrated that the model needs further testing and evaluation outside of the central United States. Also, further development is needed in terms of accounting for spatial and temporal variability in geotechnical and fluvial erodibility parameters, incorporating subaerial processes, and accounting for the influence of riparian vegetation on streambank pore‐water pressure dynamics, applied shear stress, and erodibility parameters. Copyright © 2016 John Wiley & Sons, Ltd.     

Seismic fragility of traction elevators

Second‐generation performance‐based earthquake engineering (PBEE‐2) requires a library of component fragility functions to estimate probabilistic damage to a wide variety of building components. The present work draws on a large body of (mostly) post‐earthquake reconnaissance and (some) post‐earthquake survey observations of traction elevators to create fragility functions useful in PBEE‐2. Two surveys provide detailed observations of 115 representative elevators at 12 hospitals shaken in the 1989 Loma Prieta and 1994 Northridge earthquakes and selected without regard to or foreknowledge of damage. Of these, 55 failed and 60 did not. Approximately half were installed after an important code change of 1972, so one can distinguish the performance of pre‐1973 and post‐1973 elevator construction. They experienced a range of strong motion: 22 with peak ground acceleration (PGA) < 0.25 g, 93 with 0.25 g < PGA < 0.85 g. The hospitals had elevator failure rates as low as 0% and as high as 100%. A third survey describes damage qualitatively for six sites with PGA ≤ 0.25 and per‐site failure rates of 0% to perhaps 30%. Fragility functions are offered where the damage state is the loss of functionality of the elevator. The elevators in these surveys exhibit a median capacity of PGA ≈ 0.35 g with a logarithmic standard deviation of 0.40. Capacity is modestly sensitive to whether the elevator was installed before or after 1973. Using building‐specific intensity measures such as S_a(T₁) does not improve the fragility functions. Copyright © 2015 John Wiley & Sons, Ltd.     

Field testing of modular borehole monitoring with simultaneous distributed acoustic sensing and geophone vertical seismic profiles at Citronelle,Alabama

A modular borehole monitoring concept has been implemented to provide a suite of well‐based monitoring tools that can be deployed cost effectively in a flexible and robust package. The initial modular borehole monitoring system was deployed as part of a CO₂ injection test operated by the Southeast Regional Carbon Sequestration Partnership near Citronelle, Alabama. The Citronelle modular monitoring system transmits electrical power and signals, fibre‐optic light pulses, and fluids between the surface and a reservoir. Additionally, a separate multi‐conductor tubing‐encapsulated line was used for borehole geophones, including a specialized clamp for casing clamping with tubing deployment. The deployment of geophones and fibre‐optic cables allowed comparison testing of distributed acoustic sensing. We designed a large source effort (>64 sweeps per source point) to test fibre‐optic vertical seismic profile and acquired data in 2013. The native measurement in the specific distributed acoustic sensing unit used (an iDAS from Silixa Ltd) is described as a localized strain rate. Following a processing flow of adaptive noise reduction and rebalancing the signal to dimensionless strain, improvement from repeated stacking of the source was observed. Conversion of the rebalanced strain signal to equivalent velocity units, via a scaling by local apparent velocity, allows quantitative comparison of distributed acoustic sensing and geophone data in units of velocity. We see a very good match of uncorrelated time series in both amplitude and phase, demonstrating that velocity‐converted distributed acoustic sensing data can be analyzed equivalent to vertical geophones. We show that distributed acoustic sensing data, when averaged over an interval comparable to typical geophone spacing, can obtain signal‐to‐noise ratios of 18 dB to 24 dB below clamped geophones, a result that is variable with noise spectral amplitude because the noise characteristics are not identical. With vertical seismic profile processing, we demonstrate the effectiveness of downgoing deconvolution from the large spatial sampling of distributed acoustic sensing data, along with improved upgoing reflection quality. We conclude that the extra source effort currently needed for tubing‐deployed distributed acoustic sensing vertical seismic profile, as part of a modular monitoring system, is well compensated by the extra spatial sampling and lower deployment cost as compared with conventional borehole geophones.     

Spectrophotometric pH measurement in estuaries using thymol blue and m-cresol purple

The conditional acid dissociation constants (pK_a′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pK_a′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln⁻¹):

The estimated accuracy of pH measurements using these calculated pK_a′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities.     

Assessing the Measurement Consistency Between the Jason-2/AMR and SARAL/AltiKa/DFMR Microwave Radiometers Using Simultaneous Nadir Observations

SARAL/AltiKa has a Dual Frequency Microwave Radiometer (DFMR), and Jason-2 has an Advanced Microwave Radiometer (AMR). Both microwave radiometer sensors include a 23.8 GHz primary water sensing channel. The measurement consistencies between DFMR and AMR are important for establishing a consistent altimetry data set between SARAL/AltiKa and Jason-2 in order to accurately assess sea level rise in a long-term time series. This study investigates the measurement consistency in the 23.8 GHz channel between DFMR and AMR at the Simultaneous Nadir Overpasses (SNO's) between the two satellites and also at coldest ocean brightness temperature locations. Preliminary results show that while both instruments show no significant trends over the one year since the launch of SARAL, a consistent relative bias of 2.88 K (DFMR higher than AMR) with a standard deviation of 0.98 K is observed. The relative bias at the lowest brightness temperature from the SNO method (-3.82 K) is consistent with that calculated from coldest ocean method (-3.74 K). The relative bias exhibits strong latitude (and scene temperature) dependency, changing from -3.82 K at high latitudes to -0.92 K near the equator. There also exists an asymmetry between the northern and southern hemisphere. The relative bias increases toward the lower end of brightness temperature.     

Emerging coral diseases: a temperature‐driven process?

In the last few decades there has been a surge in research focusing on coral disease. While climate change, specifically rising sea surface temperature, has been proposed as a major and growing driver of the emergence of marine diseases, to date a solid connection between disease epizootics and elevated sea surface temperature has not been established. However, a wealth of data now exists, compiled from many different perspectives, that may support such a connection. In this work we provide a comprehensive review targeting one coral disease, black band disease, that spans the infection process, pathobiology, and epizootiology, and links specific mechanisms of the disease process to increasing temperatures. This temperature‐driven pattern of infection can be expanded to include similar processes associated with other temperature‐related coral diseases. The conclusions presented here are based upon the results of many studies using a diverse suite of approaches that have been synthesized to argue that the emergence and continuing spread of black band disease is linked to warming sea surface temperatures. In summary, as global ocean temperatures increase seasonally and over decades, the environment shifts to become more favorable for the growth of potentially pathogenic microorganisms endemic to the immediate environment of the reef. The increase in the relative number of potential pathogens in the microbial community produces microenvironments conducive to the growth of other potential pathogens, leading to infection by a polymicrobial consortium. This consortium is easily perturbed by a (seasonal) temperature decrease, but remains associated with the coral host and can be reactivated with a subsequent seasonal increase in temperature, resulting in a cycle of temperature‐dependent disease emergence.