Variation of the partial pressure of CO2 in surface water from Kuroshio to Oyashio and the relation between environmental factors and the partial pressure at 144°E off Sanriku, northwestern North Pacific in May, 1997

Partial pressure of CO₂ in surface sea water (pCO₂) was measured continuously off Sanriku in May, 1997 by a new pCO₂ measurement system. We have examined the relation of pCO₂ to physical factors such as temperature, salinity and density, chemical and biological factors such as nutrients and carbonate system and chlorophylla. In the Kuroshio region pCO₂ was not correlated to physical, chemical and biological factors in the range of 260 to 290 μatom. In transition water (Tr1) between Kuroshio and the Oyashio second branch, pCO₂ was weakly correlated to physical factors and strongly correlated to nutrients. In transition water (Tr2) between the Oyashio first and second branches, pCO₂ was highly correlated to temperature (SD: 10.9 μatom) and salinity (SD: 8.6 μatom) and also to nutrients. In transition water (Tr1+Tr2), pCO₂ was highly multivariately correlated to temperature (T), salinity (S), chlorophylla (CH) (or nitrate+nitrite (N)) as follows, pCO₂(μatom)= 10.8×T(°C)+27.7×S+2.57CH(μg/1) −769, R²= 0.86, SD = 20.9, or pCO₂(μatom)= 3.9×T(°C)+25.5×S+16.0NO₃(μM) −686, R²= 0.99, SD = 6.4. Moreover, pCO₂ was predicted by only two factors, one physical (S) and the other chemical/biological (N) as follows: pCO₂ (μatom)=32.8×S+19.4N−908, R²=0.97, SD=8.4. The pH measured at 25°C was well correlated with normalized pCO₂ at a fixed temperature. In the Oyashio region pCO₂ was decreased to 160 μatom, probably because of spring bloom, but was not correlated linearly to chlorophylla. The results obtained showed the possibility of estimating pCO₂ of the Oyashio and transition regions in May by satellite remote sensing of SST, but the problem of estimation of pCO₂ in Kuroshio water remains to be solved.     

Importance of space weathering simulation products in compositional modeling of asteroids: 349 Dembowska and 446 Aeternitas as examples

Abstract— Based on recent progress in simulating space weathering on asteroids using pulse‐laser irradiation onto olivine and orthopyroxene samples, detailed analyses of two of the A and R type asteroid reflectance spectra have been performed using reflectance spectra of laser‐treated samples. The visible‐near‐infrared spectrum of olivine is more altered than that of pyroxene at the same pulse‐laser energy, suggesting that olivine weathers more rapidly than orthopyroxene in space. The same trend can be detected from reflectance spectra of the asteroids, where the more olivine an asteroid has, the redder its 1 μm band continuum can become. Comparison of the 1 μm band continuum slope and the 2/1 μm band area ratio between the asteroids and olivine and pyroxene samples (including the laser‐treated ones) suggests that asteroids may be limited in the degree of space weathering they can exhibit, possibly due to the short life of their surface regolith. Their pyroxenes may also have a limited chemical composition range. Fitting the visible continuum shape and other parts of the spectra (especially the 2μm part) has been impossible with any combination of common rock‐forming minerals such as silicates and metallic irons. However, this study shows, for the first time, excellent fits of reflectance spectra of an A asteroid (Aeternitas) and an R asteroid (Dembowska), including their visible spectral curves, band depths and shapes, and overall continuum shapes. Our results provide estimates that Aeternitas consists of 2% fresh olivine, 93% space‐weathered olivine, 1% space‐weathered orthopyroxene, and 4% chromite, and that Dembowska consists of 1% fresh olivine, 55% space‐weathered olivine, and 44% space‐weathered orthopyroxene. These results suggest that space weathering effects maybe important to the interpretation of asteroid reflectance spectra, even those with deep silicate absorption bands. Modified Gaussian model deconvolutions of the laser‐irradiated olivine samples show that their identity as olivine remained. The most recent submicroscopic mineralogical analyses have revealed that the laser‐irradiated olivine samples contain nanophase iron particles similar to those in space‐weathered lunar samples.     

Kinetics of nitrate and ammonium uptake by the natural populations of marine phytoplankton in the surface water of the Oyashio region during spring and summer

Journal of Oceanography -     

Distribution of nitrous oxide dissolved in water masses in the eastern subtropical North Pacific and its origin inferred from isotopomer analysis

N₂O concentration and its isotopomer ratios were measured over a wide area from San Diego to Honolulu in the eastern subtropical North Pacific (ESNP). Waters in the study area had an N₂O maximum (38.2–50.5 nmol kg^?1) at 600–1000 m depth, which is similar to the profiles obtained previously in other areas in the North Pacific. We separated the seawater into five water masses (two for the surface layer, two for the middle layer, and one for the deep layer) and deduced N₂O production–consumption mechanisms in each water body by use of N₂O isotopomer ratios. The results showed that the mechanisms differ slightly among water masses. In the “coastal” surface layer, N₂O is produced by nitrification (NH₂OH oxidation). In the “open ocean” surface layer, it is produced mainly by nitrifier denitrification and to a lesser extent by nitrification under substrate-limited conditions. In both “upwelling” and “open ocean” middle layers it is produced mainly by denitrification and to a lesser extent by nitrifier denitrification. It is also partly reduced. In the deep layer, it is produced predominantly by denitrification with partial reduction. In this way, isotopomers aid elucidation of production–consumption mechanisms of N₂O in the sea even though the mechanisms cannot always be ascertained.     

Estimating the impact parameters of cosmic dust particles using a piezoelectric lead zirconate titanate detector

A cosmic dust detector for installation on a satellite is currently being developed using piezoelectric lead zirconate titanate (PZT), which can possess both functions of the collector and the transducer. The characteristics of the PZT detector have been studied by bombarding it with hypervelocity particles supplied by a Van de Graaff accelerator. The front surface of the detector used in this study was covered with a white paint to reduce any increase in the temperature due to the solar radiation. There was a linear relationship between the rise time of the signal produced by the detector and the particle's velocities, which were above 10 km/s on impact. This implies that individual particle velocities on impact can be inferred through the empirical formula derived from the data obtained from the PZT detector.     

Modeling interaction of fluid and salt in an aquifer/lagoon system

To simulate the dynamic interaction between a saline lagoon and a ground water system, a numerical model for two-dimensional, variable-density, saturated-unsaturated, and coupled flow and solute transport (saltwater intrusion by finite elements and characteristics [SIFEC]) was modified to allow the volume of water and mass of salt in the lagoon to vary with each time step. The modified SIFEC allows the stage of a lagoon to vary in accordance with a functional relation between the stage and water volume of the lagoon, and also allows the salt concentration of the lagoon to vary in accordance with the salt budget of the lagoon including chemical precipitation and dissolution of salt. The updated stage and salt concentration of the lagoon are in turn used as transient boundary conditions for the coupled flow and solute transport model. The utility of the modified model was demonstrated by applying it to the eastern Mediterranean coastal region of Turkey for assessing impacts of climate change on the subsurface environment under scenarios of sea level rise, increased evaporation, and decreased precipitation.     

Structure and dynamics of water on muscovite mica surfaces

The structure and dynamics of water on muscovite mica (0 0 1) surfaces have been investigated by molecular dynamics simulations. X-ray reflectivity profiles highly reflecting the interfacial structure are directly calculated and compared with those of experiments. The direct comparison has validated the usefulness of MD simulations to understand the real interfacial structure of the mica−water system. We observed five distinguished peaks in the density profile of oxygen present in water, and these peaks are attributable to the water molecules directly adsorbed on mica, hydrated to the K⁺ ions on the mica surface, and ordered due to hydrogen bonds between hydrated K⁺ ions. The hydrated K⁺ ions make an inner-sphere complex and have an explicit first hydration shell with a radius of 3.6 Å and a hydration number of 2.9. The change of the viscosity of water located above 1 nm apart from the mica surface was not observed. This feature is in good agreement with a recent experimental study in which the shear measurement was conducted using a surface forces apparatus. The increase of the viscosity by a factor of ca. 2-3 relative to that of the bulk water was observed at water located within 1 nm from the isolated mica surface.     

A mechanism of Alpine lee cyclogenesis as revealed by a quasigeostrophic variational filter

Summary Mechanisms associated with Alpine lee cyclogenesis during the early phase of their generation are investigated using a variational quasigeostrophic filter technique. It was possible to extract the quasigeostrophic signal from the available analyzed real data set.The results presented here are for the 11–12 March 1982, an example of so-called orographically induced lee cyclogenesis. Non-quasigeostrophic fields, calculated as a difference between observations and the quasigeostrophic fields, show significant magnitudes indicating the possible importance of non-quasigeostrophic processes. A dipole structure in the residual geopotential field was observed, similar to the results of numerical model experiments. Also, a strong upper-level non-quasigeostrophic divergence was found in the Alpine region 24 hours prior to lee cyclogenesis, lasting for 6–12 hours. On the other hand, quasigeostrophic results indicate only a local effect of mountain slopes, suggesting possibly a dominant role of the low-level blocking. A hypothetical scenario of Alpine lee cyclogenesis is proposed, based on results obtained here.With 14 Figures     

Mineralogy and petrography of C asteroid regolith: The Sutter's Mill CM meteorite

Based upon our characterization of three separate stones by electron and X‐ray beam analyses, computed X‐ray microtomography, Raman microspectrometry, and visible‐IR spectrometry, Sutter's Mill is a unique regolith breccia consisting mainly of various CM lithologies. Most samples resemble existing available CM2 chondrites, consisting of chondrules and calcium‐aluminum‐rich inclusion (CAI) set within phyllosilicate‐dominated matrix (mainly serpentine), pyrrhotite, pentlandite, tochilinite, and variable amounts of Ca‐Mg‐Fe carbonates. Some lithologies have witnessed sufficient thermal metamorphism to transform phyllosilicates into fine‐grained olivine, tochilinite into troilite, and destroy carbonates. One finely comminuted lithology contains xenolithic materials (enstatite, Fe‐Cr phosphides) suggesting impact of a reduced asteroid (E or M class) onto the main Sutter's Mill parent asteroid, which was probably a C class asteroid. One can use Sutter's Mill to help predict what will be found on the surfaces of C class asteroids such as Ceres and the target asteroids of the OSIRIS‐REx and Hayabusa 2 sample return missions (which will visit predominantly primitive asteroids). C class asteroid regolith may well contain a mixture of hydrated and thermally dehydrated indigenous materials as well as a significant admixture of exogenous material would be essential to the successful interpretation of mineralogical and bulk compositional data.     

Autumn atmospheric preconditioning for interannual variability of wintertime sea-ice in the Okhotsk Sea

Relations in year-to-year variability between wintertime Sea-Ice Concentrations (SICs) in the Okhotsk Sea and atmospheric anomalies consisting of zonal and meridional 1000-hPa wind speeds and 850-hPa air temperatures are studied using a singular value decomposition analysis. It is revealed that the late autumn (October–November) atmospheric conditions strongly influence sea-ice variability from the same season (late autumn) through late winter (February—March), in which sea-ice extent is at its maximum. The autumn atmospheric conditions for the positive sea-ice anomalies exhibit cold air temperature anomalies over the Okhotsk Sea and wind anomalies blowing into the Okhotsk Sea from Siberia. These atmospheric conditions yield anomalous ocean-to-atmosphere heat fluxes and cold sea surface temperature anomalies in the Okhotsk Sea. Hence, these results suggest that the atmospheric conditions affect the sea-ice through heat anomalies stored in sea-ice and oceanic fields. The late autumn atmosphere conditions are related to large 700-hPa geopotential height anomalies over the Bering Sea and northern Eurasia, which are related to a stationary Rossby wave propagation over the North Pacific and that from the North Atlantic to Eurasia, respectively. In addition, the late autumn atmospheric preconditioning also plays an important role in the decreasing trend in the Okhotsk sea-ice extent observed from 1980 to the mid-1990s. Based on the lagged sea-ice response to the late autumn atmosphere, a simple seasonal prediction scheme is proposed for the February–March sea-ice extent using four-month leading atmospheric conditions. This scheme explains 45% of the variance of the Okhotsk sea-ice extent.