全文获取类型
收费全文 | 11408篇 |
免费 | 1110篇 |
国内免费 | 607篇 |
学科分类
工业技术 | 13125篇 |
出版年
2024年 | 60篇 |
2023年 | 191篇 |
2022年 | 428篇 |
2021年 | 535篇 |
2020年 | 406篇 |
2019年 | 327篇 |
2018年 | 365篇 |
2017年 | 441篇 |
2016年 | 422篇 |
2015年 | 504篇 |
2014年 | 627篇 |
2013年 | 670篇 |
2012年 | 815篇 |
2011年 | 776篇 |
2010年 | 726篇 |
2009年 | 727篇 |
2008年 | 648篇 |
2007年 | 637篇 |
2006年 | 536篇 |
2005年 | 443篇 |
2004年 | 398篇 |
2003年 | 359篇 |
2002年 | 448篇 |
2001年 | 389篇 |
2000年 | 269篇 |
1999年 | 224篇 |
1998年 | 142篇 |
1997年 | 102篇 |
1996年 | 115篇 |
1995年 | 92篇 |
1994年 | 87篇 |
1993年 | 50篇 |
1992年 | 26篇 |
1991年 | 26篇 |
1990年 | 21篇 |
1989年 | 20篇 |
1988年 | 12篇 |
1987年 | 10篇 |
1986年 | 10篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 5篇 |
1973年 | 1篇 |
1969年 | 3篇 |
1951年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
系统地研究了用空气——乙炔火焰原子吸收光谱分析法测定高纯石英粉中钙的最佳条件,建立了14%的乙醇作为增感剂,在2%盐酸介质中,0.4% LaCl3溶液作为释放剂,用塞曼火焰原子吸收法测定的可行性方案,探讨了共存元素对钙的干扰及其消除。方法操作简便快速,干扰少,方法相对标准偏差小于3%,适用于日常分析石英粉中的杂质。 相似文献
42.
The cobalt(II) chloride-catalyzed oxidative cleavage of -methylstyrene with oxygen in t-BuOH gives acetophenone and formaldehyde in good yield. The competing reactions between C=C cleavage and formation of polymeric products are strongly affected by the solvent, cobalt catalyst and concentration used, as well as the reaction temperature. A free radical mechanism involving a cyclic peroxide intermediate is proposed to give the cleavage products. Oxidation of various alkenes using CoCl2/t-BuOH/O2 system shows that only activated styrenes can be oxidized effectively. The reactivity of various styrenes and their selectivity towards giving cleavage products or polymers are strongly influenced by the electronic and steric properties of the substrate. 相似文献
43.
介绍了通径为20"(1"=25.4mm)的大口径中压球阀阀体、新型C形金属密封环组件等的结构设计;在阀座与球体之间采用整体碟形弹簧和新型阀座密封填料,以保证高压密封,提高使用寿命;阀芯采用空心球体结构和分段冲压成形加工工艺,有效地保证了球体的加工精度和质量,降低了生产成本;在结构设计中,充分考虑了球阀的密封、防火、启闭传动及制造工艺的要求;对其中结构复杂的球阀阀体和空心球形阀芯进行了强度计算和ANSYS应力、应变模拟分析计算,二者计算结果一致,并认为阀体的厚度由其大开孔处局部应力的整体补强确定。 相似文献
44.
45.
46.
Using TiO2 as carrier, CuO/TiO2 catalysts with different CuO loading were prepared by the impregnation method. The catalytic activities in NO+CO reaction
were examined with a micro-reactor gas chromatography reaction system and the methods of TPR, XPS and NO-TPD. It was found
that the catalytic activities were affected by pretreatment atmosphere, i.e. H2 atmosphere > reduction–reoxidation > 10%CO/He > reaction gas (fresh sample). NO decomposition was better by low-valence Cu
species than by high-valence Cu species, i.e. Cu0>Cu+>Cu2+. The XPS results indicated that Cu species on CuO/TiO2 were Cu0, Cu+, normal Cu2+(Cu2+(I)) and chain-structured Cu2+(Cu2+(II)) as –Cu–O–Ti–O–. The activities of Cu2+(II) were much higher than that of Cu2+(I), but both species were very unstable in the reaction atmosphere and easily reduced by CO, which accounted for the variable
activities of fresh catalysts with increasing reaction temperature. In NO+CO reaction, the redox process was a cycle of Cu+–Cu2+(I) at low reaction temperature but was a cycle of Cu0–Cu+ at high reaction temperature. As shown by NO-TPD, high catalytic activities could be attributed to the following factors,
e.g. oxygen caves on the catalyst’s surface after pretreatment with H2 and reduction–reoxidation, formation of Cu0 after pretreatment with H2, and increment of Cu species dispersion and formation of Cu2+(II) after pretreatment with reduction–reoxidation. 相似文献
47.
摘要:细胞固定化技术具有流程简单、生物相容、操作稳定等优点,可有效保证细胞活性,实现高效的细胞催化生产精细化学品。本文介绍了表面附着、凝胶包埋、聚电解质层层自组装膜等多细胞固定化方法,及其在二元醇、生物乙醇、乳酸、酯、多糖等精细化学品生产中的研究现状和进展,并分析讨论了各种方法存在的问题。同时,总结了近年来新发展的单细胞纳米涂层固定化方法的机理、趋势及应用于精细化学品生产的可能性。最后对细胞固定化催化生产精细化学品面临的技术挑战及研究方向做出展望,以期为精细化学品生产提供一定的技术支持。 相似文献
48.
49.
Water-soluble amino acid derivatives of gadolinium (Gd) endohedral metallofullerenes (AAD-EMFs), Gd@C82Om(OH)n(NHCH2CH2COOH)l (m ≈ 6, n ≈ 16 and l ≈ 8) are synthesized by a direct reaction of the pure endohedral metallofullerene Gd@C82 with an excess of alkaline solution of β-alanine. The structure of the AAD-EMFs is characterized by FTIR, XPS and laser-desorption time-of-flight (LD-TOF) mass spectrometries. Water proton relaxivity analysis indicates that the longitudinal relaxivity R1 (the effect on 1/T1, 9.1 mM−1 s−1) of AAD-EMFs is higher than that of the commercial MRI contrast agent, Magnevist (gadolinium-diethylenetriaminepentaacetic acid, Gd-DTPA, 5.6 mM−1 s−1). The MRI phantom studies are performed to confirm the high efficiency of this sample as MRI contrast agents. 相似文献
50.
Various electrochemical methods with different conditions were used to prepare lead dioxide (PbO2). The observation revealed that the morphology of deposited PbO2 could be controlled by simply changing deposition parameters. Under the condition of oxygen evolution, which dominates the electrode process, uniformly distributed high porous structured PbO2 was formed. The results indicated that large current density or high potential polarization should be one of the most important and necessary factors for forming high surface area PbO2 deposit. Only β-PbO2 was identified by X-ray diffraction measurement for the deposit prepared by present methods and solution. One potential application of this method is to prepare nanoscaled PbO2 parallel lines. 相似文献